• 제목/요약/키워드: complex geometry

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저탄소 화물운송체계 구현을 위한 3차원 도로망도 모델에 관한 연구 (The Research about Map Model of 3D Road Network for Low-carbon Freight Transportation)

  • 이상훈
    • Spatial Information Research
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    • 제20권4호
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    • pp.29-36
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    • 2012
  • 최근 도시와 도시간의 물류량 증가로 인하여 교통혼잡비용이 증가하고, 기후변화협약에 따른 이산화탄소 감축이 의무화됨에 따라 저탄소 화물운송체계 개념이 소개되었다. 연료소비량 및 탄소배출량을 고려한 화물운송계획을 수립하기 위해서는 현실의 도로 기하정보를 표현하는 3차원 도로망도가 필수적이다. 본 연구는 화물운송의 주요대상인 도시와 도시간의 간선도로를 중심으로 지형 및 도로구조물을 고려하기 위하여 기존 2차원 교통주제도와 수치표고모델을 이용하여 도로의 실제 기하정보를 반영하는 3차원 도로망도 모델을 제안한다. 제안 모델은 실험 도로구간(평택항-의왕IC)을 대상으로 구축하고 GPS/INS 측량을 통해 구축한 3차원 도로망도가 도로의 기하정보를 잘 표현함을 검증하였다(RMSE=0.87m). 또한, 연료소모량 시뮬레이션을 통해 기존의 2차원 도로망도에 비해 제안모델이 현실도로의 연료소모량을 효과적으로 반영함을 알 수 있었다. 본 연구를 통해 복잡한 도로의 3차원 기하정보를 반영하여 에너지 및 환경문제를 효과적으로 고려할 수 있는 Green-ITS기반의 화물 경로계획 및 네비게이션 시스템 개발이 가능할 것이다.

생태학적 ${\cdot}$ 육수학적 현상들에 대한 프랙탈의 적용 (Fractal Approaches to Ecological and Limnological Phenomena)

  • 장현정;강신규;이도원
    • 생태와환경
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    • 제33권2호통권90호
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    • pp.69-79
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    • 2000
  • Fractal geometry has become one of prospective research approaches as the complex structure of natural entities is not easily characterized by traditional Euclidean geometry. With the fractal geometry, we can better decipher the complex structure and identify natural and anthropogenic agents of landscape patterns occurring at different spatial scales. The usefulness of fractal, however, has not been fully appreciated among Korean academic societies, especially in ecological and limnological fields. We attempt to address three points in this study. First, we introduce the concept and dimension of fractal and review relevant research approaches, especially with respect to ecological and limnological phenomena. Second, we explore possible applications of fractal to some aspects of geography and land use characteristics in South Korea. For the analyses of fractal dimensions, we used data published in other studies previously and collected for this study. Data were analyzed by a perimeter/area method of fractal dimension for the spatial distribution of global solar radiation and leaf area index, and the movement of wild boars in forested landscapes of mid-eastern Korea. The same approach was also applied to the water channel of a hypothetical river and the shape of reservoirs in Yongin, Kyunggi Province. Finally, we discuss the results and key issues to consider when a fractal approach is employed in ecology and limnology.

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Structural Analysis of the Cu-binding Site in the [Cu·dCMP·dCMP-H]1- Complex

  • Jung, Sang-Mi;Kim, Ho-Tae
    • Mass Spectrometry Letters
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    • 제4권4호
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    • pp.67-70
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    • 2013
  • The Cu-binding site in the $[Cu{\cdot}dCMP{\cdot}dCMP-H]^{1-}$ complex was investigated. The tandem mass (MS/MS) spectra of the [$[Cu{\cdot}dCMP{\cdot}dCMP-H]^{1-}$ parent ion showed $[dCMP{\cdot}Cu{\cdot}H_2PO_4+CONH]^{1-}$ fragment ions. Therefore, we propose that the Cu cation is simultaneously coordinated to the phosphate site and cytosine moiety in the stable geometry of the $[Cu{\cdot}dCMP{\cdot}dCMP-H]^{1-}$ complex. Three geometries for the complex were considered in an attempt to optimize the structure of the $[Cu{\cdot}dCMP{\cdot}dCMP-H]^{1-}$ complex. The ab initio calculations were performed at the $B3LYP/6-311G^{**}$ level.

Synthesis and Characterization of Nickel(II) Tetraaza Macrocyclic Complex with 1,1-Cyclohexanediacetate Ligand

  • Lim, In-Taek;Kim, Chong-Hyeak;Choi, Ki-Young
    • 대한화학회지
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    • 제62권6호
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    • pp.427-432
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    • 2018
  • The reaction of [$[Ni(L)]Cl_2{\cdot}2H_2O$ (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[$14,4,0^{1.18},0^{7.12}$]docosane) with 1,1-cyclohexanediacetic acid ($H_2cda$) yields mononuclear nickel(II) complex, [$Ni(L)(Hcda^-)_2$] (1). This complex has been characterized by X-ray crystallography, electronic absorption, cyclic voltammetry and thermogravimetric analyzer. The crystal structure of 1 exhibits a distorted octahedral geometry with four nitrogen atoms of the macrocycle and two 1,1-cyclohexanediacetate ligands. It crystallizes in the triclinic system P-1 with a = 11.3918(7), b = 12.6196(8), $c=12.8700(8){\AA}$, $V=1579.9(2){\AA}^3$, Z = 2. Electronic spectrum of 1 also reveals a high-spin octahedral environment. Cyclic voltammetry of 1 undergoes one wave of a one-electron transfer corresponding to $Ni^{II}/Ni^{III}$ process. TGA curve for 1 shows three-step weight loss. The electronic spectra, electrochemical and TGA behavior of the complex are significantly affected by the nature of the axial $Hcda^-$ ligand.

Binding Geometry of Inclusion Complex as a Determinant Factor for Aqueous Solubility of the Flavonoid/β-Cyclodextrin Complexes Based on Molecular Dynamics Simulations

  • Choi, Young-Jin;Lee, Jong-Hyun;Cho, Kum-Won;Hwang, Sun-Tae;Jeong, Karp-Joo;Jung, Seun-Ho
    • Bulletin of the Korean Chemical Society
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    • 제26권8호
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    • pp.1203-1208
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    • 2005
  • A computational study based on molecular dynamics (MD) simulations was performed in order to explain the difference in aqueous solubilities of two flavonoid/$\beta$-cyclodextrin ($\beta$-CD) complexes, hesperetin/$\beta$-CD and naringenin/$\beta$-CD. The aqueous solubility of each flavonoid/$\beta$-CD complex could be characterized by complexwater interaction not by flavonoid-CD interaction. The radial distribution of water around each inclusion complex elucidated the difference of an experimentally observed solubility of each flavonoid/$\beta$-CD complex. The analyzed results suggested that a bulky hydrophobic moiety (-$OCH_3$) of B-ring of hesperetin nearby primary rim of $\beta$-CD was responsible for lower aqueous solubility of the hesperetin/$\beta$-CD complex.

Halide (Cl-, Br-, I-) Influence on the Electronic Properties of Macrocyclic Nickel(II) Complexes: Ab-initio DFT Study

  • Zarei, Seyed Amir;Akhtari, Keivan;Hassanzadeh, Keyumars;Piltan, Mohammad;Saaidpour, Saadi;Abedi, Marjan
    • 대한화학회지
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    • 제57권3호
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    • pp.311-315
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    • 2013
  • The geometry structures of hexa-coordinated [NiLX]X complexes ($X=Cl^-,\;Br^-,\;I^-$) {L = 8,9,18,19-tetrahydro-7H,17H-dibenzo[f,o] [1,5,9,13]dioxadiaza cyclohexadecine-8,18-diol} are optimized by density functional theory (DFT) using B3LYP/LANL2DZ. The calculated geometric parameters are in good agreement with the corresponding experimental values. Calculation results about these complexes show that dipole moment decreases, and the energy levels of HOMOs descend from iodo-complex to chloro-complex. The energy levels of HOMOs descend gently from iodo-complex to chloro-complex, while the energy levels of LUMOs in the present complexes are almost similar; therefore the energy gapes between HOMOs and LUMOs increased from iodo-complex to chloro-complex.

A Novel Iron(III) Complex with a Tridentate Ligand as a Functional Model for Catechol Dioxygenases: Properties and Reactivity of [Fe(BBA)DBC]$ClO_4$

  • 윤성호;이호진;이강봉
    • Bulletin of the Korean Chemical Society
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    • 제21권9호
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    • pp.923-928
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    • 2000
  • [FeIII(BBA)DBC]ClO4 as a new functional model for catechol dioxygenases has been synthesized, where BBA is a bis(benzimidazolyl-2-methyl)amine and DBC is a 3,5-di-tert-butylcatecholate dianion.The BBA complex has a structuralfeature that iron cent er has a five-coordinate geometry similar to that of catechol dioxygenase-substrate complex.The BBA complex exhibits strong absorptionbands at 560 and 820 nm in CH3CN which are assigned to catecholate to Fe(III) charge transfer transitions. It also exhibits EPR signals at g = 9.3 and 4.3 which are typical values for the high-spin FeIII (S = 5/2) complex with rhombicsymmetry. Interestingly, the BBA complex reacts with O2 within an hour to afford intradiol cleavage (35%) and extradiol cleavage (60%) products. Surprisingly, a green color intermediate is observed during the oxygenation process of the BBA com-plex in CH3CN. This green intermediate shows a broad isotropic EPR signal at g = 2.0. Based on the variable temperature EPR study, this isotropic signalmight be originated from the [Fe(III)-peroxo-catecholate] species havinglow-spin FeIII center, not from the simple organic radical. Consequently,it allows O2 to bind to iron cen-ter forming the Fe(III)-superoxide species that converts to the Fe(III)-peroxide intermediate. These present data can lead us tosuggest that the oxygen activation mechanism take place for the oxidative cleavingcatechols of the five-coordinate model systems for catechol dioxygenases.

스테인리스 강 STS305의 디프 드로잉 가공에 관한 실험적 연구 (Experimental study on the severe deep drawing for complex cylindrical housing of STS 305 stainless steel)

  • 김두환
    • 소성∙가공
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    • 제7권5호
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    • pp.439-444
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    • 1998
  • Recently many automotive parts have been made with stainless steels by deep drawing processes, But there are various problems occurred in deep drawing works of stainless steels compared with low carbon steels. For the severe deep drawing of complex cylindrical housing optimum process planning is required to eliminate intermediate annealing improve shape accuracy and maintain surface integrity without drawing defects such as tears wrinkles and scratches or galling. Therefore in this study a sample process planning of the severe of the severe deep drawing process is applied to a complex cylindrical housing needed for a 6 multi-stepped deep drawing of type STS 305 . A series of experiments are performed to investigate optimum process variables such as drawing rate radius and clearance. Through experiments the variations of the thickness strain distribution and hardness distribution in each drawing step are observed. Also the effects of other factors on formability such as drawing oil, blank holding force and die geometry are examined and discussed.

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간결하고 효율적인 폴리곤 메쉬의 표현 구조 (A Compact and Efficient Polygonal Mesh Representation)

  • 박상근;이상헌
    • 한국CDE학회논문집
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    • 제9권4호
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    • pp.294-305
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    • 2004
  • Highly detailed geometric models are rapidly becoming commonplace in computer graphics and other applications. These complex models, which is often represented as complex1 triangle meshes, mainly suffer from the vast memory requirement for real-time manipulation of arbitrary geometric shapes without loss of data. Various techniques have been devised to challenge these problems in views of geometric processing, not a representation scheme. This paper proposes the new mesh structure for the compact representation and the efficient handling of the highly complex models. To verify the compactness and the efficiency, the memory requirement of our representation is first investigated and compared with other existing representations. And then we analyze the time complexity of our data structure by the most critical operation, that is, the enumeration of the so-called one-ring neighborhood of a vertex. Finally, we evaluate some elementary modeling functions such as mesh smoothing, simplification, and subdivision, which is to demonstrate the effectiveness and robustness of our mesh structure in the context of the geometric modeling and processing.

비선형 최적화 기법을 이용한 압전 세라믹의 복소 재료 정수 규명 (An Identification Method for Complex-Valued Material Properties of Piezoelectric Ceramics Using Nonlinear Optimization Technique)

  • 조치영;서희선;김대환
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 1996년도 춘계학술대회논문집; 부산수산대학교, 10 May 1996
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    • pp.298-305
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    • 1996
  • The common practice for the identification of piezoelectric properties is based on the use of immittance behavior of a resonator with a certain geometry and poling direction. In this paper, a new method is suggested to identify the complex-valued piezoelectric material constants. This method is based on the minimization of differences between the analytical immittance and the experimental measurement of resonator. Non-linear minimization problems are formulated to find out the unknown properties relevant to the resonators. The immittance data used for identification are measured at a number of frequencies which cover the vicinity of resonance frequency and the low frequency region. To illustrate the proposed technique, the complex-valued coefficients are identified for a typical PZT4 ceramic composition.

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