• Journal of the Korean Chemical Society
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• v.39 no.8
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• pp.611-616
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• 1995

Oxovanadium(IV) complexes with salicylaldoxime, o-vanilline oxime, 2-hydroxy-4-methoxybenzaldoxime, 2-hydroxy-5-methoxybenzaldoxime and 2-hydroxy-5-nitrobenzaldoxime were synthesized. The complexes have been characterized by elemental analysis, electric conductivity measurement, infrared spectrometry, electronic spectrometry, mass spectrometry, and thermal analysis. The results of elemental analysis were well coincided with the theoretical values. The values of molar conductance of the complexes in DMF implicated that the complexes were non-electrolyte. The characteristic stretching frequency of V=O appeared strong band in the range of $980{\pm}20\;cm^{-1}.$ All the complexes showed two d-d transition in visible spectra and two charge transfer transitions in ultraviolet spectra. Results of mass spectrometry of $VO(sal)_2\;and\;VO(van)_2$ indicated two peaks corresponding to vanadium containing ion(I) of 1 : 2(metal to ligand) chelate and a fragment ion(II) of 1 : 1 chelate due to loss of ligand radical from ion(I). The thermal analysis showed the endothermic peak due to the thermal decomposition.

• Journal of the Korean Chemical Society
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• v.28 no.2
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• pp.95-101
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• 1984

Aquation reaction kinetics of $[Cr(en)_2Cl_2]^+$complex was carried by the electric conductivity method. Its temperature range was $15^{\circ}C$ to $30^{\circ}C$ and pressure was varied up to 2,000 bars. The reaction rate was increased with increasing temperature, but was reversed to increasing pressure. The activation volume(${\Delta}V^{\neq}$) was increased with increasing temperature and decreased with increasing pressure. At $25^{\circ}C$ and 1 bar it was fairly small positive value, $1.82cm^2/mole$. Activation entropy change(${\Delta}S^{\neq}$) $was calculated as small negative value,-9.019 eu, at $25^{\circ}C$ and 1bar. Referring to the thermodynamic parameters, it was estimated that aquation reaction was proceeded by the interchange-dissociation(Id) mechanism.

• Journal of the Korean Geotechnical Society
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• v.21 no.3
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• pp.119-131
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• 2005

Seepage analysis through unsaturated zone based on the theory of unsaturated flow is commonly performed to evaluate dam safety. However, the concepts of unsaturated soil behavior have not been transferred into the hands of practicing geotechnical engineers since the problems involving unsaturated soils often have the appearances of being extremely complex. The behavior of dam such as seepage rate and the pore water pressure distribution is different according to the unsaturated hydraulic properties, but nevertheless simply assumed properties have been used due to insufficient data from domestic soils. In this paper, the effect of unsaturated hydraulic properties on the behavior of dam was studied through a series of numerical analyses, and then the results were discussed. It is observed that water table moves at a (aster rate, as the values of unsaturated soil parameter a and n increase. The value of m showed opposite trend. The sensitivity calculated using the approximation form showed maximum values near the water table. And the value of n that is related to the slope of soil water characteristic curve gives greatest influence on the change of sensitivity with time.

• Proceedings of the Korea Water Resources Association Conference
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• 2009.05a
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• pp.529-534
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• 2009

Climate models, both global and regional, have increased in sophistication and are being run at increasingly higher resolutions. The Land Surface Models (LSMs) coupled to these climate models have evolved from simple bucket models to sophisticated Soil-Vegetation-Atmosphere Transfer (SVAT) schemes needed to support complex linkages and processes. However, some underpinnings of terrestrial hydrologic parameterizations so crucial in the predictions of surface water and energy fluxes cause model errors that often manifest as non-linear drifts in the dynamic response of land surface processes. This requires the improved parameterizations of key processes for the terrestrial hydrologic scheme to improve the model predictability in surface water and energy fluxes. The Common Land Model (CLM), one of state-of-the-art LSMs, is the land component of the Community Climate System Model (CCSM). However, CLM also has energy and water biases resulting from deficiencies in some parameterizations related to hydrological processes. This research presents the implementation of a selected set of parameterizations and their effects on the runoff prediction. The modifications consist of new parameterizations for soil hydraulic conductivity, water table depth, frozen soil, soil water availability, and topographically controlled baseflow. The results from a set of offline simulations are compared with observed data to assess the performance of the new model. It is expected that the advanced terrestrial hydrologic scheme coupled to the current CLM can improve model predictability for better prediction of runoff that has a large impact on the surface water and energy balance crucial to climate variability and change studies.

• Geophysics and Geophysical Exploration
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• v.2 no.1
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• pp.43-53
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• 1999

Numerical modeling and inversion for electromagnetic exploration methods are essential to understand behaviour of electromagnetic fields in complex subsurface. In this study, a finite element method was adopted as a numerical scheme for the 2.5-dimensional forward problem. And a finite element equation considering linear conductivity variation was proposed, when 2.5-dimensional differential equation to couple eletric and magnetic field was implemented. Model parameters were investigated for near-field with large source effects and far-field with responses dominantly by homogeneous half-space. Numerical responses by this study were compared with analytic solutions in homogeneous half-space. Blocky inversion model was modified to be applied to the forward calculation in this study and it was also adopted in the inversion algorithm. Resolution for isolated bodies were investigated to confirm possibility and limitation of inversion for electromagnetic exploration data.

• Tunnel and Underground Space
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• v.21 no.4
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• pp.297-306
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• 2011

In this paper, we performed thermodynamic energy balance analysis of the underground lined rock cavern for compressed air energy storage (CAES) using the results of multi-phase heat flow analysis to simulate complex groundwater-compressed air flow around the cavern as well as heat transfer to concrete linings and surrounding rock mass. Our energy balance analysis demonstrated that the energy loss for a daily compression and decompression cycle predominantly depends on the energy loss by heat conduction to the concrete linings and surrounding rock mass for a sufficiently air-tight system with low permeability of the concrete linings. Overall energy efficiency of the underground lined rock caverns for CAES was sensitive to air injection temperature, and the energy loss by heat conduction can be minimized by keeping the air injection temperature closer to the ambient temperature of the surroundings. In such a case, almost all the heat loss during compression phase was gained back in a subsequent decompression phase. Meanwhile, the influence of heat conductivity of the concrete linings to energy efficiency was negligible.

• Bulletin of the Korean Chemical Society
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• v.26 no.9
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• pp.1395-1402
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• 2005

The reaction of cis-[Cr([14]-decane)$(OH)_2]^+$ ([14]-decane = rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-teraazacyclotetradecane) with auxiliary ligands {$L_a$ = acetylacetonate (acac), oxalate (ox) or malonate (mal)} leads to a new cis-[Cr([14]-decane)(acac)]$(ClO_4)_2{\cdot}(1/2)H_2O\;(1),\;cis-[Cr([14]-decane)(ox)]ClO_4{\cdot}(1/2)H_2O\;(2)\;or\;cis-[Cr([14]-decane)(mal)]ClO_4{\cdot}(1/4)H_2O\;(3)$. These complexes have been characterized by a combination of elemental analysis, conductivity, IR and Vis spectroscopy, mass spectrometry, and X-ray crystallography. Analysis of the crystal structure of cis-[Cr([14]-decane)(acac)]$(ClO_4)_2{\cdot}(1/2)H_2O$ reveals that central chromium(III) has a distorted octahedral coordination environment and two acetylacetonate-oxygen atoms are bonded to the chromium(III) ion in the cis positions. The angle $N_{axial}-Cr-N_{axial}$ deviates by $11^{\circ}$ from the ideal value of $180^{\circ}$ for a perfect octahedron. The bond angle O-Cr-O between the chromium(III) ion and the two acetylacetonate-oxygen atoms is close to $90^{\circ}$. The bond lengths of Cr-O between the chromium and the acetylacetonate-oxygen atoms are 1.950(3) and 1.954(2) $\AA$. They are shorter than those between chromium and nitrogen atoms of the macrocycle. The IR spectra of 1, 2 and 3 display bands at 1560 {ν (C=O)}, 1710 {${\nu}_{as}$(OCO)} and 1660 $cm^{-1}$ {${\nu}_{as}$(OCO)} attributed to the acac, ox and mal auxiliary ligands stretching vibrations, respectively.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.5
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• pp.1-9
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• 2017

The cryogenic nitrogen spray of a swirl injector has been numerically investigated using three dimensional LES turbulence model to analyze the dynamic characteristics under supercritical condition. To predict the precise nitrogen properties under supercritical condition, SRK equation of state, Chung's method for viscosity and thermal conductivity and Takahashi's correlation based on Fuller's theory for diffusion coefficient are implemented. The complex flow structures due to interaction between flow field and acoustic field are observed inside and outside the injector under supercritical condition. FFT, POD, and DMD techniques are employed to understand the coherent structures. By implementing the FFT, the dominant frequencies are identified inside and outside the injector. The coherent flow structures related to the dominant frequencies are visualized using the POD and DMD techniques. In addition, the DMD provides the damping coefficient which is related with the instability prediction.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1998.11a
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• pp.119-122
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• 1998

Chemical analysis, measurement of pumping rates of 60 production wells and depth to water tables of 57 monitoring wells were carried to protect depletion of water resources and deterioration of water quality for the commercial portable ground-water. Borehole depth of production well averages 149m(31 boreholes), casing depth is 28m(29 boreholes), production rate is 70 $m^3$/day and depth to water table of monitoring well is 23.26m, respectively. The geology of 60 wells can be divided into Daebo granite(20), Okchun metarmorphic complex(18), Precambrian granitic gneiss(15), Bulguksa granite(4), Cheju volcanics(2), Cretaceous sedimentary rock(1). Average electrical conductivity and pH are 152$\mu$S/cm, and 7.35, respectively. The contents of major cation and anion predominantly $Ca^{2+}$>N $a^{+}$>M $g^{2+}$> $K^{+}$ and HC $O_{3}$$^{－}$ >S $O_{4}$$^{2-}$>Cl￣>F￣. Water type is predominantly $Ca^{2+}$-HC $O_{3}$$^{－}$(81.7%). It's possible that water chemistry of some wells were affected not only by the geology of boreholes penetrated but by inflows of surface water or shallow ground-water. Therefore, it is strongly necessary to steadily monitor the water quality and hydrogeologic conditins of production wells.ells.ls.ells.

• Journal of Advanced Navigation Technology
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• v.22 no.3
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• pp.205-212
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• 2018

Spontaneous ignition is not only severe economic damage but also a typical plant damage caused by harmful gases generated during the fire. Because coal is porous, it causes oxygen to be absorbed in the amount of oxygen per unit weight of oxygen, resulting in low humidity and low thermal conductivity. The cause and effect of spontaneous ignition are very complex, so it is difficult to prevent it beforehand and once it is difficult to digest it, it is difficult to digest it. This study examines structural safety by conducting a structural analysis of the cooling ball system to prevent spontaneous combustion of coal stockpile plants and external pressures.