• Title/Summary/Keyword: combustion reaction mechanism

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A Steady-State Combustion Modelling of Composite Solid Propellants

  • Hur, Byung-Ki;Kim, Chong-Bo
    • Journal of Mechanical Science and Technology
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    • v.15 no.4
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    • pp.473-481
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    • 2001
  • By depicting the transfer of heat and combustion reaction to take place within thin gas layers close to the propellant surface burning in a steady-state fashion, a mathematical equation has been deduced to describe the burning rate of solid propellant as a function of initial grain temperature and chamber pressure. It has been also assumed that chemical reaction could take place in premixing-diffusing zone but were carried out mainly in the reaction-flame zone. All these phenomena taken place in each zone of combustion have been assumed to be steady-state. In the present investigation, the equation, γ=$\kappa$$.$(1/R(T(sub)i+C))(sup)n$.$exp(-E(sub)a/R(T(sub)i+C))(P/z) is being presented and it is compared with experimental data. The proposed model has been tested and evaluated vis-a-vis strand burner data for three different propellants based on CTPB, and it has been found that the deviation of the computed burning rates from the measured rates ranged up to 2%.

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Numerical analysis of nonequilibrium plasma assisted combustion using OpenFOAM (OpenFOAM을 이용한 비평형 플라즈마 연소 수치해석)

  • Park, Yeongdo;Huh, Kang Y.
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.181-182
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    • 2015
  • The nonequilibrium plasmas in which electrons have much higher energy compared to heavy species that cannot be represented with single temperature can enhance combustion reaction significantly. Therefore the nonequilibrium plasmas provide new effective mechanism to control combustion to overcome difficulties advanced combustion devices exploiting extreme operating parameters for high efficiency, lower emission.

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Laminar Burning Velocities of Propane and Iso-Octane Fuels for Stratified Charged Combustion Modeling (성층화 혼합기 연소 모델링을 위한 프로판 및 이소옥탄 연료의 층류 화염 속도)

  • Pae, Sang-Soo;Kim, Yong-Tae;Lim, Jae-Man;Min, Kyoung-Doug
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.704-709
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    • 2000
  • Laminar burning velocities of propane- and iso-octane-air mixtures have been numerically modelled over a wide range of equivalence ratio, pressure and temperature. These correlations are applicable to the modelling of stratified charged combustion like that of lean bum and GDI engine combustion. The numerical models are based on the results calculated by PREMIX code with Sloane's detailed chemical reaction mechanism for propane and FlameMaster code with Peters' for iso-octane. Laminar burning velocity for two fuels showed a pressure and temperature dependence in the following form, in the range of $0.1{\sim}4MPa$, and $300{\sim}1000K$, respectively. $S_L={\alpha}\;{\exp}[-\xi({\phi}-{\phi}_m)^2-{\exp}\{-{\xi}({\phi}-{\phi}_m)\}-{\xi}({\phi}-{\phi}_m)]$ where ${\phi}_m=1.07$, and both of ${\alpha}$ and ${\xi}$ are functions of pressure and temperature. Compared with the results of the existing models, those of the present one showed the good agreement of the recent experiment data, especially in the range of lean and rich sides. Judging from the calculated results of the stratified charged combustion by using STAR-CD, the above modelling prove to be more suitable than the other ones.

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Development of a Multi-zone Combustion Model for the Analysis of CAI Engines (CAI 엔진 해석을 위한 multi-zone 연소 모델의 개발)

  • Lee, Kyeong-Hyeon;Lim, Jae-Man;Kim, Young-Rae;Min, Kyoung-Doug
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.6
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    • pp.74-80
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    • 2008
  • A combustion of CAI engine is purely dominated by fuel chemical reactions. In order to simulate the combustion of CAI engine, it should be considered the effect of fuel components and chemical kinetics. So it needs enormous computational power. To overcome this problem reduced problem of needing massive computational power, chemical kinetic mechanism and multi-zone method is proposed here in this paper. A reduced chemical kinetic mechanism for a gasoline surrogate was used in this study for a CAI combustion. This gasoline surrogate was modeled as a blend of iso-octane, n-heptane, and toluene. For the analysis of CAI combustion, a multi-zone method as combustion model for a CAI engine was developed and incorporated into the computational fluid dynamics code, STAR-CD, for computing efficiency. This coupled multi-zone model can calculate 3 dimensional computational fluid dynamics and multi-zoned chemical reaction simultaneously in one time step. In other words, every computational cell interacts with the adjacent cells during the chemical reaction process. It can enhance the reality of multi-zone model. A greatly time-saving and yet still relatively accurate CAI combustion simulation model based on the above mentioned two efficient methodologies, is thus proposed.

Computer Simulation of Liquid-Fuelled Combustor in Hot Vitiated-Air Stream (고온.저산소 농도영역중의 분무연소해석)

  • 김태한;최병륜
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.12
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    • pp.3187-3195
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    • 1993
  • Combustion of liquid-fuelled combustion in a high-temperature vitiated-air stream was studied. The mathematical formulation comprise the application of Eulerian conservation equation to the gas phase and Lagrangian equation of droplet motion. The latter is coupled with a droplet-tracking technique (PSI-CELL Model) which regard the droplet phase as a source of mass, momentum, and energy to the gaseous phase. Reaction rate is determined by taking into account the Arrhenius reaction rate based on a single-step reaction mechanism. The calculated profiles show somewhat uncertainess at the upstream, but bases data for designing the combustor followed by 2-phase flow were obtained.

Skeletal Chemical Mechanisms for a Diesel Fuel Surrogate by the Directed Relation Graph(DRG) (직접 관계 그래프(DRG)를 이용한 디젤 연료의 상세 화학 반응 기구 축소화)

  • Lee, Young-J.;Huh, Kang-Y.
    • Journal of the Korean Society of Combustion
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    • v.16 no.2
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    • pp.16-22
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    • 2011
  • It is a challenging task to apply large detailed chemical mechanisms of fuel oxidation in simulation of complex combustion phenomena. There exist a few systematic methodologies to reduce detailed chemical mechanisms to smaller sizes involving less computational load. This research work concerns generation of a skeletal chemical mechanism by a directed relation graph with specified accuracy requirement. Two sequential stages for mechanism reduction are followed in a perfectly stirred reactor(PSR) for high temperature chemistry and to consider the autoignition delay time for low and high temperature chemistry. Reduction was performed for the detailed chemical mechanism of n-heptane consisting of 561 species and 2539 elementary reaction steps. Validation results show acceptable agreement for the autoignition delay time and the PSR calculation in wide parametric ranges of pressure, temperature and equivalence ratio.

Numerical analysis on performances and emission characteristics of HCCI engine fueled with hydrogen added biogas (반응 메커니즘 기반의 수소 첨가 바이오가스 HCCI 엔진 성능 및 배출가스에 대한 수치 해석적 연구)

  • Park, Jungsoo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.12
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    • pp.41-46
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    • 2018
  • In this research, numerical analysis was performed to determine the effects of hydrogen on biogas combustion for homogeneous charged compression ignition (HCCI) engines. The target engine specifications were a 2300cc displacement volume, 13:1 compression ratio, 15kW of electricity, and 1.2 bar boost pressure. The engine speed was fixed to 1800rpm. By varying the excess air ratio and hydrogen contents, the cylinder pressure, nitric oxide, and carbon dioxide were measured as a function of the hydrogen contents. According to preliminary studies related to the reaction mechanism for methane combustion and oxidation, a GRI 3.0 mechanism as the base mechanism was selected for HCCI combustion calculations describing the detailed reaction mechanism. By adding hydrogen, NO was increased while $CO_2$ was decreased. The cylinder pressure was also increased, having advanced timing for the maximum cylinder pressure and pressure rise region. Furthermore, lean operation limits were extended by adding hydrogen to the HCCI engine.

A study on the development of liquefied natural gas-fired combustor (액화천연가스 연소기개발에 관한 연구)

  • 최병륜;오상헌;김덕줄
    • Journal of Advanced Marine Engineering and Technology
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    • v.10 no.3
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    • pp.107-118
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    • 1986
  • The presenet research attempts to examine the combustion characteristics and the structure of the flame in turbulent premixed flames and thus enhance the combustion performance that leads to the design of the effective combustion system (untilizing LNG). Following experimental investigations for several stabilized premixed flames were attempted to identify the interactive mechanism between flame structures and flow fields; Visualization by Schlieren method, measurement of flow velocity by LDV, detection of ion current by ion probe, measurement of fluctuating temperature by thermocouple having compensation circuit, average values with respect to time of fluctuating amount for flow velocity, temperature, ion current, etc., variable RMS values, PDFs, autocorrelation, crosscorrelation, spatial macroscale, power spectra, and velocity scale. Continuing the authors published studies whose flame dominated by coherent structures and the characteristics of combustion reaction for irregular three dimensional flame and stabilized flame by step were investigated with obtained experimental quantities. Results of this research are following : The most turbulent flames support the structure of a Wrinkled laminar flame or laminar flamelets. It also observed that combustion reaction is related to small tubulence microscales of the turbulent flow fields closly.

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The Influence of Strain Rates on the $CH_4/C_2HCl_3/Air$ Counterflow Nonpremixed Flames ($CH_4/C_2HCl_3/Air$ 대향류 비예혼합 화염에서 스트레인율의 영향)

  • Lee, Ki-Yong
    • Journal of the Korean Society of Combustion
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    • v.5 no.1
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    • pp.7-18
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    • 2000
  • Numerical simulations of counterflow non-premixed $CH_4/C_2HCl_3/Air$ flames added 8%(by volume) C2HCl3 on the fuel side are conducted at atmospheric pressure using a detailed chemical reaction mechanism in order to understand the effect of strain rates. A detailed sensitivity analysis is also performed in order to assess the relative influence of each reaction on the flame established at a strain rate of 200s-1. The structure of flames (i.e., temperature, velocity, and concentration of species) established at both a strain rate of 150s-1 and 300s-1 are investigated. As the strain rate increases, the "flame zone" is restricted to a narrower range and the position of maximum temperature is shifted to the fuel side. The concentrations of major species, H2O, CO, H2, HCl, Cl2, and Cl are decreased with increased strain rate. The reaction involving chlorine, CH4 + Cl $\rightarrow$ CH3 + HCl, instead of the reaction, CH4 + H $\rightarrow$ CH3 + H2 influences the consumption of methane. C2HCl3 + OH $\rightarrow$ CHCl2 + CHOCl and HCl + OH $\rightarrow$ H2O + Cl, are major reactions, through which OH radicals are consumed.

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A Computational Study about Effects of Operating parameters and EGR compositions on Autoignition Reactivity for DME HCCI Combustion

  • Jamsran, Narankhuu;Lim, Ocktaeck
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.305-307
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    • 2012
  • This study was computationally explored how the fuel autoignition reactivity was affected by operating parameters such as fuel, pressure, intake temperatures, engine speed and EGR compositions for HCCI combustion. This is done for DME and CHEMKIN-PRO was used as a solver. At first, influence of the operating parameters and EGR compositions were showed. And then, in order to clarify the mechanism of them on autoignition reactivity, data-sets of kinetic were analyzed to investigate the elementary reaction path for heat release at transient tempeatures by using contribution matrix.

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