• Title/Summary/Keyword: column leaching

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Leaching of Soil Cations by Simulated Acid Rains of Different Compositions (구성성분이 다른 인공산성비에 의한 토양의 양이온 용탈에 관한 연구)

  • Ryu, Kwan-Shig;Min, Tai-Gi
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.4
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    • pp.407-413
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    • 1998
  • The influence of the anion composition of simulated acid rain on cation leaching of two soils with different surface charge properties was examined. Four mixtures of mole ratio of $SO_4:NO_3$(1:0, 2:1, 1:1, 0:1) with pH 2.0 simulated acid rain were applied to an Inceptisols(Gyuam series) and Andisols(Pyeongdae series). The Andisols had higher $SO_4{^{2-}}$ adsorption capacity than the Inceptisols because of its higher point of zero charge(PZC, pH 6.5) than Inceptisols(PZC pH 3.1). Cation leaching in Andisols varied directly with the $NO_3$ content of the leaching input due to higher mobility of $NO_3$ compared with $SO_4$ that was absorbed. The pH of the Andisols was higher with the addition of $Na_2SO_4$ than the addition of $NaNO_3$ indicating that this soil behaves as a base and has a high $SO_4$ adsorption capacity. The relative $NO_3{^-}/SO_4{^{2-}}$ content input had no effect on cation leaching of the Inceptisols. Amounts of leaching on the Andisols by simulated acid rain were higher than Inceptisols. This experiment explained that anion composition of acid rain plays a significant role in the cation leaching of soils which are able to adsorb $SO_4$.

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Characterization of Leaching of Heavy Metal and Formation of Acid Mine Drainage from Coal Mine Tailings (석탄폐석(石炭廢石)으로부터 산성광산배수(酸性鑛山排水)의 생성과 중금속(重金屬)의 용출(溶出) 특성(特性))

  • Lee, Gye-Seung;Song, Young-Jun
    • Resources Recycling
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    • v.19 no.2
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    • pp.54-62
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    • 2010
  • In order to obtain the basic data for recycling of coal mine tailings, the characteristics of coal mine tailings, the formation of AMD from the tailings and the leaching of heavy metal from the tailings were studied. The samples were characterized in terms of chemical composition, mineral composition and content of heavy metal of the tailings were investigated. The effects of time, temperature, content of pyrite, sulfide minerals on the formation of AMD were also investigated. For the leaching tests, the KS method, TCLP method and column test were used. From the investigated data, we can see that the coal mine tailings can be used as aggregate for filling used gallery. We can also see that the formation of AMD from coal mine tailings can be prevented by mixing 4% or more limestone with it.

Behaviors of Chloronicotinyl Insecticide Acetamiprid in Soil (Chloronicotinyl계 살충제 Acetamiprid의 토양 환경중 동태)

  • Hong, Min-Kee;Park, Jong-Woo;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.20 no.3
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    • pp.162-168
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    • 2001
  • This study was conducted to evaluate the degradation, adsorption and desorption and leaching of acetamiprid in soils. The half-life of acetamiprid in field condition was $1.7{\sim}3.3$ days in Bokhyun soil and, in case of laboratory condition, 15.5 days. Adsorption of acetamiprid was equilibrated in 12 hours incubation. In adsorption experiment using modified soils, such as oxidized soil, oxidized soil added humic acid, fulvic acid, kaolinite or montmorillinite, adsorption rate of acetamiprid was the highest in the oxidized soil added fulvic acid. The desorption rate was the lowest in the oxidized soil added fulvic acid. The adsorption and desorption results should be suggested that acetamiprid could be strongly adsorbed with soil humic materials, especially fulvic acid. When the mobility of acetamiprid in soil was calculated according to GUS (Groundwater Ubiquity Score) equation, it was prove to non-leacher, and it was confirmed in the leaching experiment with soil column. Most of acetamiprid was remained in the upper 30 cm of the soil column after eluting with water and it was not even detected in leachate.

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Heavy matal removal in leaching water from the region buried tungsten tailing (중석광 폐재광미의 매립지에서 나오는 침출수 중의 중금속 제거)

  • Lee, Dong-Hoon;Oh, Sae-Gang;Choi, Choong-Lyeal;Park, Man;Choi, Jyung
    • Korean Journal of Environmental Agriculture
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    • v.19 no.3
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    • pp.218-222
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    • 2000
  • Wasted${\cdot}$rested mine areas give lots of effect on around-environmental changes after mining development. Leaching water at reclaimed land has been eluted from the solid components through physical, chemical, biological procedures by waters percolated through reclaimed site. The element analysis of waste tungsten ore tailing, leaching water analysis and removal of heavy metal by zeolite were performed to investigate the influent of acid rain on the released contents of H. M. The heavy metal contents in leaching water were determined to be As $1.21\;{\sim}\;1.54\;ppm$, Pb $0.11\;{\sim}\;0.15\;ppm$ and $SO_4\;^{2-}$ was $302\;{\sim}\;378ppm$. As deionized water and simulated acid rain (pH 3,4) were percolated through columns packed tungsten ore tailing, the amount of Mn, Na, Ca which were dissolved by pH4 solution was higher than those by distilled water. However, W and Mo were eluted easily by high pH solution. The change of heavy metal concentration by column experiment packed zeolite was effective a little because heavy metals were adsorved much more by zeolite.

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Adsorption-Desorption, Leaching, and Degradation Pattern of Fungicide Fluazinam in the Soil Environment (살균제 Fluazinam의 토양환경 중 흡.탈착, 용탈 및 분해양상)

  • Hu, Won;Lee, Seog-June;Kim, Jang-Eok
    • Applied Biological Chemistry
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    • v.40 no.2
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    • pp.128-133
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    • 1997
  • This study was conducted to evaluate the adsorption, desorption, leaching and degradation pattern of fungicide fluazinam in the soil environment under the laboratory conditions. The mode of isothermal adsorption of fluazinam in soil was coincident with the Freundlich equation. The adsorption amount of fluazinam was much higher on soils containing organic matter than on soils oxidized with hydrogen peroxide. The presence of organic matter, humic acid or fulvic acid, increased the adsorption amount of fluazinam on soils. The Freundlich constant K was much higher in soil added with humic acid than in soil added with fulvic acid. The desorption ratio of fluazinam adsorbed to soil was increased by removal of organic matter. In leaching experiment using soil column, the fluazinam applied on the soil surface was not moved down to the bottom of soil and was not detected in leachate water. The degradation of fluazinam was faster in Soil I with rich organic matter than Soil II with poor organic matter, in non-sterilized soil than sterilized soil, and in flooded soil than unflooded soil.

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폐석회 혼합토사의 환경영향 저감방안 연구

  • Hong, Seung-Seo;Jeong, Ha-Ik;Yoo, Jun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.95-98
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    • 2003
  • Waste lime is produced as by-products in chemical industry, Reuse of waste lime mixed with soil for banking and backfill material in civil works was analysed in this study. For this purpose, environmental effect of waste lime admixtures was tested. Thus, this study presents the leaching characterization of waste lime in laboratory batch and column tests. Countermeasure for reduction of environmental effects was suggested from the test results.

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경작조건별 농경지 비료성분의 거동특성에 관한 칼럼 연구

  • 최태범;이기철;장윤영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.279-281
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    • 2003
  • This study is intended to give information on agricultural nonpoint source pollution and transport related to fertilizer application and irrigation practice. Field-simulated soil columns were set up and leaching studies on fertilizer components such as nitrogen and phosphorus were performed. Nitrogen and phosphorus in the leachate showed different trends in each column and nonpoint source pollution in agricultural areas may be expected to depend on planted crops, soil conditions, and climate as well as irrigation and fertilizing management.

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Analytical Studies on Leaching of Plasticizers from Medical Grade Polyvinyl Chloride Containers (폴리염화비닐 의료용기의 가소제의 정량 및 용출에 관한 연구)

  • Lee, Min-Hwa
    • Journal of Pharmaceutical Investigation
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    • v.16 no.3
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    • pp.106-109
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    • 1986
  • The elution of di(2-ethylhexyl) phthalate (DEHP) from flexible bags into human blood or transfusion was studied. The conditions of determination of DEHP using high performance liquid chromatography (HPLC) was established as follows: Condition I-column, ${\mu}-Bondapak^{TM}\;C_{18}$; mobile phase, methanol: water=91 : 9 ; flow rate, 1.2ml/min; wavelength, 254nm; injection volume, $10{\mu}l$. Condition II-column, Lichorsorb RP-18$(10{\mu}m)$; mobile phase, methanol: water=94 : 6 ; flow rate, 1.1ml/min; wavelength, 254nm; injection volume, $10{\mu}l$. DEHP was found to be migrating from PVC blood and total parentral nutrient bags into methanol, but not into anti, coagulant drug solution.

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Effective Reservoir Management Methods using Nutrients Leaching Characteristic Analysis: Case Study of the Hongdong Reservoir (홍동저수지 퇴적토의 유기물 용출 특성 분석을 통한 효율적인 저수지 관리 방안 연구)

  • Lee, Young-Shin;Shin, Sang-Hee
    • The Journal of Engineering Geology
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    • v.23 no.2
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    • pp.95-104
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    • 2013
  • This study proposes an efficient management plan for improving the water quality of agricultural reservoirs. Hongdong reservoir is located in an area that includes farmland, forest, residential housing, and livestock farms. The levels of pollutants in Hongdong reservoir were investigated with the aim of improving the water quality in the reservoir. The potential concentrations of total nitrogen (T-N) and total phosphorus (T-P) in Hongdong reservoir were 1.06-3.67 and 0.52-1.12 $g/m^2-d$, respectively. An analysis of leaching characteristics was performed under anaerobic conditions for 72 hours at $20^{\circ}C$. The concentrations of T-P and $PO_4$-P were measured by general leaching for a set period. In the case of T-P, the leaching was measured by irregular leaching due to denitrification of nitrite nitrogen ($NO_2$-N) and nitrate nitrogen ($NO_3$-N). A very small amount of $NH_3$-N on nitrogen ($N_2$) was measured due to the low pH in the column, as a consequence of the anaerobic conditions.

Recycling Water Treatment of Aquaculture by Using DynaSand Filter II. Effect of Coating on Removal of Bacteria and Virus in Sand Columns (상향류식 연속 역세 여과를 이용한 양어장 순환수 재리용 II. 여과사의 표면처리에 의한 세균 및 바이러스 처리율 검토)

  • 박종호;조규석;황규덕;김이오
    • Journal of Aquaculture
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    • v.16 no.2
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    • pp.76-83
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    • 2003
  • To improve the efficiency of removal of bacteria and virus with DynaSand Filters used for treatment of recycling wastewater from aquaculture, effect of biofilm formation on bacterial transport through coated sand was estimated. At the neutral pH (pH 7.0), the coated sand was positive of zeta potential (surface charge). Column experiments were also carried out to test the effect of uncoated sand as well as coated sand with Al and Fe. The coated sand influenced more significantly the surface properties, adsorption and transport than the uncoated sand. The leaching batch system investigated for synthetic water showed concentrations of 7.47, 4.80, 20.89 and 7.23 mg/L for the uncoated sand, coated sand with Al, Fe and Al+Fe, respectively. Hence there are significant differences among the tested coatings with reference to bacterial transport and surface properties.