• 한국세라믹학회지
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• 제53권2호
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• pp.227-233
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• 2016

In order to make a highly ordered three-dimensional porous structure of titania ceramics, porogen beads of PS [Polystyrene] and PMMA [poly(methylmetacrylate)] were prepared by emulsion polymerization using styrene monomer and methyl methacrylate monomer, respectively. The uniform beads of PS or PMMA latex were closely packed by centrifugation as a porogen template for the infiltration of titanium butoxide solution. The mixed compound of PS or PMMA with titanium butoxide was dried and the dry compacts were calcined at $450^{\circ}C-750^{\circ}C$ according to the firing schedule to prepare micro- and meso- structures of polycrystalline titania with monodispersed porosity. Inorganic frameworks composed of $TiO_2$ were formed and showed a three Dimensionally Ordered Microstructure [3DOM] of $TiO_2$ ceramics. The pulverized particles of the $TiO_2$ ceramic skeleton were characterized using XRD analysis. A monodispersed crystalline micro-structure with micro/meso porosity was observed by FE-SEM with EDX analysis. The 3DOM $TiO_2$ skeleton showed opalescent color tuning according to the direction of light.

• Current Optics and Photonics
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• 제3권1호
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• pp.27-32
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• 2019

We present an autofocus tracking system implemented by the digital refocusing of digital holographic microscopy (DHM) and the tunability of an electrically tunable lens (ETL). Once the defocusing distance of an image is calculated with the DHM, then the focal plane of the imaging system is optically tuned so that it always gives a well-focused image regardless of the object location. The accuracy of the focus is evaluated by calculating the contrast of refocused images. The DHM is performed in an off-axis holographic configuration, and the ETL performs the focal plane tuning. With this proposed system, we can easily track down the object drifting along the depth direction without using any physical scanning. In addition, the proposed system can simultaneously obtain the digital hologram and the optical image by using the RGB channels of a color camera. In our experiment, the digital hologram is obtained by using the red channel and the optical image is obtained by the blue channel of the same camera at the same time. This technique is expected to find a good application in the long-term imaging of various floating cells.

• 생명과학회지
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• 제27권4호
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• pp.423-429
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• 2017

모발의 색은 melanin의 종류와 양에 의해 결정 된다. Melanocyte는 주로 자외선 자극에 의하여 L-tyrosine으로부터 멜라닌을 합성한다. 활성산소종은 백발의 진행과정에 중요한 역할을 하고 있다. 적하수오는 백발화되는 노화과정을 억제한다고 보고되고 있다. 본 연구의 목적은 흑모발생과 연관된 melanin 합성에 대한 적하수오 에탄올 추출물(PMEE)의 효능을 조사한 것이다. 항산화 실험에서 PMEE는 DPPH radical을 감소시켰고 환원력을 증가시켜 PMEE는 백발과정에 관여하는 활성산소종을 소거할 수 있다고 볼 수 있다. PMEE는 농도 의존적으로 세포생존능을 감소시켰다. 더욱이 melanin의 생성에 대한 PMEE의 효과는 DOPA assay와 tyrosinase 활성측정에 의하여 결정되었다. PMEE는 tyrosinase 활성을 증가시켰으며 melanin 합성을 촉진시켰다. 뿐만 아니라 Western blot 분석을 이용하여 tyrosinase, TRP-1, TRP-2 및 MITF 뿐만 아니라 SOD-3와 catalase와 같은 항산화 효소의 단백질 발현을 조사하였다. PMEE의 항산화 활성의 증가로 인하여 SOD-3와 catalase의 발현 수준은 감소된 것으로 나타났다. 특히, PMEE는 tyrosinase와 TRP-2의 발현 수준은 증가시켰다. 이러한 결과들은 PMEE가 백발화 된 모발에서 흑발로 변하는 것과 관련된 melanin 합성을 촉진할 수 있다는 것을 암시하고 있다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.76.1-76.1
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• 2015

Optical resonances of metallic or dielectric nanoantennas enable to effectively convert free-propagating electromagnetic waves to localized electromagnetic fields and vice versa. Plasmonic resonances of metal nanoantennas extremely modify the local density of optical states beyond the optical diffraction limit and thus facilitate highly-efficient light-emitting, nonlinear signal conversion, photovoltaics, and optical trapping. The leaky-mode resonances, or termed Mie resonances, allow dielectric nanoantennas to have a compact size even less than the wavelength scale. The dielectric nanoantennas exhibiting low optical losses and supporting both electric and magnetic resonances provide an alternative to their metallic counterparts. To extend the utility of metal and dielectric nanoantennas in further applications, e.g. metasurfaces and metamaterials, it is required to understand and engineer their scattering characteristics. At first, we characterize resonant plasmonic antenna radiations of a single-crystalline Ag nanowire over a wide spectral range from visible to near infrared regions. Dark-field optical microscope and direct far-field scanning measurements successfully identify the FP resonances and mode matching conditions of the antenna radiation, and reveal the mutual relation between the SPP dispersion and the far-field antenna radiation. Secondly, we perform a systematical study on resonant scattering properties of high-refractive-index dielectric nanoantennas. In this research, we examined Si nanoblock and electron-beam induced deposition (EBID) carbonaceous nanorod structures. Scattering spectra of the transverse-electric (TE) and transverse-magnetic (TM) leaky-mode resonances are measured by dark-field microscope spectroscopy. The leaky-mode resonances result a large scattering cross section approaching the theoretical single-channel scattering limit, and their wide tuning ranges enable vivid structural color generation over the full visible spectrum range from blue to green, yellow, and red. In particular, the lowest-order TM01 mode overcomes the diffraction limit. The finite-difference time-domain method and modal dispersion model successfully reproduce the experimental results.

• 한국세라믹학회지
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• 제41권5호
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• pp.381-387
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• 2004

현재 상용화되어 있는 PDP용 형광체의 물성에 있어서 청색 형광체는 열화, 색도변화, 휘도, 그리고 녹색 형광체는 잔광시간과 색순도, 적색 형광체의 경우에는 색순도에 대한 개선이 필요한 것으로 알려져 있다. 그 중 녹색 형광체로 Willemite 구조의 ZnSiO:Mn 형광체의 경우 발광효율은 우수하나 반면에 잔광시간이 길고 색순도(color purity)가 좋지 않다는 단점을 가지고 있다. 따라서 본 연구에서는 미세조정 조합화학기법을 이용하여 PDP에 적합한 새로운 고효율 형광체를 개발하였다. 화학적으로 정량인 가돌리늄 인산염(gadolinium phosphorous) 대신 인산을 과잉으로 첨가하여 탐색한 다음 과잉인산(excess phosphorous) 첨가 조성을 유지한 채로 가돌리늄(gadolinium)의 일정분율을 이트륨(yttrium)으로 치환하였다. 그 결과 최적 형광체 조성은 (G $d_{0.74}$ $Y_{0.11}$T $b_{0.15}$) $P_{1.15}$ $O_{{\delta}}$이였으며, 현재 상용화된 Z $n_2$ $SiO_4$:Mn 형광체에 비해 상대적으로 높은 발광효율을 나타내었으며, 잔광시간도 줄일 수 있게 되었다.

• 패션비즈니스
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• 제17권6호
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• pp.28-43
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• 2013

Recent trends toward the collaborations among various sectors of academia and research areas have brought interests and significances in new activities especially in the fashion and textile areas. One of the collaboration examples is the recent research projects on 3D virtual clothing systems based on the 3D CAD software. The 3D virtual clothing systems provide simulated apparels with high degrees of fidelity in terms of color, texture, and structural details. However, since real fabrics exhibit strong nonlinearity, anisotropy, viscoelasticity, and hysteresis, the 3D virtual clothing systems need fine tuning parameters for the simulation process. In this study, characteristics of silk fabrics, which are woven by using degummed silk and raw silk yarns, are being analyzed and compared. Anisotropic properties may be measured as warp and filling direction properties separately in woven fabrics, such as warp tensile stress or filling bending rigidity. Hysteretic properties may be measured as bending hysteresis or shear hysteresis by using KES measurements. These data provide deformation-force relationships of the fabric specimen. Three-dimensional effects obtained when using these characteristic fabrics are also analyzed. The methods to control the three-dimensional appearance of the sewn fabric specimens when utilizing a programmable microprocessor-based motor device, as prepared in this study, are presented. Based on the physical and mechanical properties measured when using the KES equipment, the property parameters are being into a 3-dimensional virtual digital clothing system, in order to generate a virtual clothing product based on the measured silk fabric properties.

• Bulletin of the Korean Chemical Society
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• 제30권11호
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• pp.2754-2758
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• 2009

Three novel phosphorescent 2-phenylpyridine-based iridium(III) complexes, $[(ppy)_2Ir(P\^{}N)]PF6\;(1),\;[(dfppy)_2Ir(P\^{}N)]PF_6$ (2), and $[(dfmppy)_2 Ir(P\^{}N)]PF6$ (3), where $P\^{}N$ = 2-[(diphenylphosphino)methyl]pyridine (dppmp), were synthesized and characterized. The absorption, photoluminescence, cyclic voltammetry and thermal stability of the complexes were investigated. The complexes showed bright blue luminescences at wavelengths of 448 $\sim$ 500 nm at room temperature in $CHCl_3$ and revealed that the $\pi$-acceptor ability of the phosphorous atom in the ancillary dppmp ligand plays an important role in tuning emission color resulting in a blue-shift emission. The single crystal structure of $[(dfmppy))_2Ir(P\^N)]PF_6$ was determined using X-ray crystallography. The iridium metal center adopts a distorted octahedral structure coordinated to two dfmppy and one dppmp ligand, showing cis C-C and trans N-N chelate dispositions. There is a $\pi-\pi$ overlap between π electrons delocalized in the difluorophenyl rings.

• Bulletin of the Korean Chemical Society
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• 제34권1호
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• pp.167-173
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• 2013

A series of highly efficient red phosphorescent heteroleptic iridium(III) complexes 1-6 containing two cyclometalating 2-(2,4-substitued phenyl)quinoxaline ligands and one chromophoric ancillary ligand were synthesized: (pqx)$_2Ir$(mprz) (1), (dmpqx)$_2Ir$(mprz) (2), (dfpqx)$_2Ir$(mprz) (3), (pqx)$_2Ir$(prz) (4), (dmpqx)$_2Ir$(prz) (5), (dfpqx)$_2Ir$(prz) (6), where pqx = 2-phenylquinoxaline, dfpqx = 2-(2,4-diflourophenyl)quinoxaline, dmpqx = 2-(2,4-dimethoxyphenyl)quinoxaline, prz = 2-pyrazinecarboxylate and mprz = 5-methyl-2-pyrazinecarboxylate. The absorption, emission, electrochemical and thermal properties of the complexes were evaluated for potential applications to organic light-emitting diodes (OLEDs). The structure of complex 2 was also determined by single-crystal X-ray diffraction analysis. Complex 2 exhibited distorted octahedral geometry around the iridium metal ion, for which 2-(2,4-dimethoxyphenyl)quinoxaline N atoms and C atoms of orthometalated phenyl groups are located at the mutual trans and cis-positions, respectively. The emission spectra of the complexes are governed largely by the nature of the cyclometalating ligand, and the phosphorescent peak wavelengths can be tuned from 588 to 630 nm with high quantum efficiencies of 0.64 to 0.86. Cyclic voltammetry revealed irreversible metal-centered oxidation with potentials in the range of 1.16 to 1.89 V as well as two quasi-reversible reduction waves with potentials ranging from -0.94 to -1.54 V due to the sequential addition of two electrons to the more electron-accepting heterocyclic portion of two distinctive cyclometalated C^N ligands.

• 한국컴퓨터정보학회논문지
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• 제24권11호
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• pp.29-39
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• 2019

실생활에서의 모바일 로봇 응용이 증가하면서 저비용의 자율 주행 기능이 요구되고 있다. 본 논문은 모바일 로봇의 실내 주행 여건을 고려한 제한된 트랙을 가정하고, 제한된 트랙에서 모바일 로봇의 자율 주행을 지원하는 비젼 기반 실시간 차선 검출 및 추적 시스템을 제안한다. 다양한 형태의 차선 처리와 동작 파리미터의 사전 조정 등을 고려하여 다중 동작 모드를 가진 시스템 구조와 상태 기계를 설계하였으며, 파라미터 조정 모드에서 차선 두께의 기하학적 특성을 바탕으로 컬러 필터의 임계값을 동적으로 조정하고, 곡선 트랙의 불안정 입력 모드와 직선 트랙의 안정 입력 모드에서 차선의 기하학적 그리고 시간적 특성을 바탕으로 차선 특징 픽셀을 적응적으로 추출하고 최소제곱법으로 차선 모형을 추정한다. 추정된 차선 모형으로 트랙 중앙선을 산출하고 움직임 모형을 단순화시켜 선형 칼만 필터를 통해 추적한다. 주행 실험에서 저성능의 로봇 구성에서도 실시간 처리를 통해 제한된 트랙에서 정상적으로 자율 주행이 이루어짐을 확인하였다.

• 한국정보전자통신기술학회논문지
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• 제15권5호
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• pp.380-386
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• 2022

본 논문은 적대적 생성 신경망 기법의 하나인 Pix2Pix를 활용하여 컬러색상을 입히는 경우 학습된 이미지의 빛 반사 정도에 따라 예측결과가 손상되어 나오는 부분에 집중하여 Pix2Pix 모델 적용 전 이미지 전처리 프로세스 및 모델 최적화를 위한 파라미터 테이블을 구성한다. 기존 논문에 나온 Pix2Pix 모델을 활용하여 실생활에 적용하기 위해서는 해상도에 대한 확장성을 고려해야한다. 학습 및 예측결과 이미지 해상도를 키우기 위해서는 동시에 모델의 커널 사이즈 등을 같이 맞춰주는 부분을 수정해줘야 하는데 이부분은 파라미터로 튜닝 가능하도록 설계했다. 또한 본 논문에서는 예측결과가 빛 반사에 의해 손상된 부분만 별도 처리하는 로직을 같이 구성하여 예측결과를 왜곡시키지 않는 전처리 로직을 구성하였다. 따라서 활용성을 개선하기 위하여 Pix2Pix 모델의 학습이미지에 공통적인 빛반사 튜닝 필터를 적용하는 부분과 파라미터 구성부분을 추가하여 모델 정확도를 개선하였다.