• Title/Summary/Keyword: colloidal suspension

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Study on Mechanism of Mechanical Damping System Based on The Colloidal Suspension of Nano-Porous Particles (나노 다공성 입자의 콜로이드 서스펜션을 이용한 기계적 감쇠기구에 대한 연구)

  • W.J, Song;Kim, J.;B.Y. Moon;B.S. Kang
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.10a
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    • pp.359-362
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    • 2003
  • Damping systems have been widely used to various industrial structures and are mainly hydraulic and pneumatic devices nowadays. In this work, a novel damping system based on the colloidal suspension in the field of nanotechnology is investigated. The colloidal suspension consists of Iyophobic working fluid and hydrophobic-coated porous particle. The mechanism of mechanical energy dissipation in damping system based on the colloidal suspension with nano-porous particles is different from that of the existing hydraulic damping system. The absorbed energy of the damping system using colloidal suspension can be calculated through the mechanical equilibrium condition by the superficial tensions of liquid-gas Interface in the hydrophobic surface in nano-porous particles. The results from an analytic approach have a reasonable agreement with experimental results.

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Reorientation of Colloidal Crystalline Domains by a Thinning Meniscus

  • Im, Sang-Hyuk;Park, O-Ok
    • Macromolecular Research
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    • v.12 no.2
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    • pp.189-194
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    • 2004
  • When water is evaporated quickly from a water-based colloidal suspension, colloidal particles protrude from the water surface, distorting it and generating lateral capillary forces between the colloidal particles. The protruded colloidal particles are then assembled into ordered colloidal crystalline domains that float on the water surface on account of their having a lower effective density than water. These colloidal crystal domains then assemble together by lateral capillary force and convective flow; the generated colloidal crystal has grain boundaries. The single domain size of the colloidal crystal could be controlled, to some extent, by changing the rate of water evaporation, but it seems very difficult to fabricate a single crystal over a large area of the water's surface without reorienting each colloidal crystal domain. To reorient such colloidal crystal domains, a glass plate was dipped into the colloidal suspension at a tilted angle because the meniscus (airwaterglass plate interface) is pinned and thinned by further water evaporation. The thinning meniscus generated a shear force and reoriented the colloidal crystalline domains into a single domain.

Multiple-Layered Colloidal Assemblies via Dipping Method with an External Electric Field

  • Im, Sang-Hyuk;Park, O-Ok;Kwon, Moo-Hyun
    • Macromolecular Research
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    • v.11 no.2
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    • pp.110-114
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    • 2003
  • When using the dipping method for crystal formation, mono-layered colloidal crystal structures depend upon the lift-up rate of a glass substrate. The mono-layered colloidal crystals showed the highest quality when the glass substrate was raised at a rate of 3 mm/min at 25 $^{\circ}C$ in a 1 wt% polystyrene colloidal suspension (ethanol medium). In addition, in order to obtain multiple-layered colloidal crystals, an external electric Held was introduced. Multiple-layered colloidal crystals were successfully obtained via this method. The colloidal particles were well ordered over large areas and assembled into a homogeneous structure.

Collodial Properties and Acid Consuming Capacity of Hydrous Aluminum Oxide Suspension (제산제 알루미나수화물의 콜로이드성과 제산능)

  • 이계주;이기명
    • YAKHAK HOEJI
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    • v.35 no.4
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    • pp.277-282
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    • 1991
  • Rheological, colloidal and micromeritical properties were followed to investigate aging mechanisms of hydrous aluminum oxide suspension using Zeta-meter systems, BET adsorption apparatus, Master sizer and electronmicroscope. The results indicate that hydrous aluminum oxide suspension revealed plastic flow with thixotropy. The viscosity, thixotropy and yield value were increased with increasing concentration. During aging process, the viscosity and thixotropic index were increased by an addition of glycerin, however, sorbitol stabilized aging process of the suspension being accompanied with growth of particle size and reduction in specific surface area, pore area and pore volume, and consistency. Diminution of adsorptive power of the particles was also protected by addition of sorbitol to hydrous aluminum oxide suspension. From these results, one of aging mechanism of hydrous aluminum oxide suspension assumed growth and/or crystallization of colloidal particles in aqueous suspension.

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Experimental study on impact and spreading of SiO2 nanoparticle colloidal suspension droplets (SiO2 나노입자 현탁액의 충돌 및 퍼짐에 관한 실험적 연구)

  • Huh, H.K.;Lee, S.J.
    • Journal of the Korean Society of Visualization
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    • v.11 no.3
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    • pp.12-16
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    • 2013
  • The impact and spreading behaviors of silicon dioxide nanoparticle colloidal suspension droplets were quantitatively visualized using a high-speed imaging system. Millimeter-scale droplets were generated by a syringe pump and a needle. Droplets of different velocity were impacted on a non-porous solid surface. Images were consecutively recorded using a CMOS high-speed camera at 5000 fps (frames per second) for millimeter-scale droplets. Temporal variations of droplet diameter, velocity and maximum spreading diameters were evaluated from the sequential images captured for each experimental condition. Effects of Reynolds number, Weber number, and particle concentration were investigated experimentally.

Synthesis of stable colloidal zirconia sol by adsorption of polyvinyl alcohol (PVA 흡착에 의한 안정한 콜로이드 지르코니아 졸의 합성)

  • Lee, Jong-Kook;Moon, Gi-Dong;Kim, Hwan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.2
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    • pp.165-174
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    • 1995
  • A stable suspension with a colloidal $ZrO_2$ particle was prepared by an adsorption of PV A and investigated to the effects of PV A on the dispersion and particle growth within suspension. With a suspension added the optimum concentration of PYA (about 500 ppm in this study), it was shown the property of a stable sol due to the formation of adsorbed PV A layer on surface and the reduction of an agglomeration among the particles. Most of nucleation in colloidal $ZrO_2$ were occured in the early stage of hydrolysis reaction and the plate-like monoclinic $ZrO_2$ particle were grown with an aging time. The rate of particle growth and yield for a reaction were decreased with an addition of PV A. The compact prepared from well- dispersed suspension by an addition of PV A was contained the homogeneous particle arrangement and pore distribution.

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Application of Scaling Theories to Estimate Particle Aggregation in a Colloidal Suspension

  • Park, Soongwan;Koo, Sangkyun
    • Korean Chemical Engineering Research
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    • v.60 no.2
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    • pp.260-266
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    • 2022
  • Average aggregate size in particulate suspensions is estimated with scaling theories based on fractal concept and elasticity of colloidal gel. The scaling theories are used to determine structure parameters of the aggregates, i.e., fractal dimension and power-law exponent for aggregate size reduction with shear stress using scaling behavior of elastic modulus and shear yield stress as a function of particle concentration. The structure parameters are utilized to predict aggregate size which varies with shear stress through rheological modeling. Experimentally rheological measurement is conducted for aqueous suspension of zinc oxide particles with average diameter of 110 nm. The predicted aggregate size is about 1135 nm at 1 s-1 and 739 nm at 1000 s-1 on the average over the particle concentrations. It has been found that the predicted aggregate size near 0.1 s-1 agrees with that the measured one by a dynamic light scattering analyzer operated un-sheared.

Effects of Carbon Fiber on Mechanical Behaviour of Al2O3 Porous Ceramics

  • Basnet, Bijay;Lim, Hyung Mi;Lee, Kee Sung;Kim, Ik Jin
    • Journal of the Korean Ceramic Society
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    • v.56 no.5
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    • pp.513-520
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    • 2019
  • This study reports the improvement of mechanical properties of Al2O3 porous ceramics from colloidal suspension with the addition of carbon fiber by direct foaming. The initial colloidal suspension of Al2O3 was partially hydrophobized by surfactant to stabilize wet foam with the addition of carbon fiber from 2 to 8 wt% as stabilizer. The influence of carbon fiber on the air content, bubble size, pore size and pore distribution in terms of wet foam stability and physical properties of porous ceramics were discussed. The viscosity of the colloidal suspension was increased giving solid like properties with the increased in carbon fiber content. The mechanical properties of the sintered porous samples were investigated by Hertzian indentation test. The results show the wet foam stability of more than 90% corresponds to compressive loading of 156.48 N and elastic modulus of 57.44 MPa of sintered sample with 8 wt% of carbon fiber content.

Process Development of Self-Assembled Monolayers(SAMs) of Colloidal Particles (콜로이드 입자의 자기 배열성을 이용한 Monolayer 형성에 관한 연구)

  • Ko, Hwa-Young;Lee, Hae-Weon;Kim, Joo-Sun;Moon, Joo-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.981-987
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    • 2002
  • Monodispersed colloidal silica was prepared by Stober process. We have synthesized monodispersed colloidal silica of carious sizes (100 nm, 200 nm, 300 nm) by controlling volume ratios of TEOS(Tetraethylorthosilicate), $NH_4OH$, Ethanol and D. I. water. Shape and monodispersity of the synthesized colloidal particles were observed by Scanning Electron Microscopy(SEM) and laser light scattering particle analyzer. Self-assembled monolayer of monodispersed colloids was achieved by dipping Si substrate into a well-dispersed silica suspension. It was determined that uniformity and spatial extent of the self-assemble monolayer of monodispersed colloids are significantly influenced by the experimental parameters such as concentration, pH and surface tension of the colloidal suspension. We have observed a hexagonally well-ordered packing colloidal monolayer in a relatively large area (1.5 mm ${\times}$ 1.5 mm) as confirmed by SEM.