• Title/Summary/Keyword: colloid stability

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Measurement of Normal Gastric Emptying Rate Using Chicken Liver Labeled with $^{99m}Tc-Colloid$ (정상인의 Gastric Emptying Rate 측정)

  • Lee, Cheorl-Woo;Kim, Chahng-Guhn;Kim, Byung-Chan;Won, Jong-Jin;Nah, Yong-Ho
    • The Korean Journal of Nuclear Medicine
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    • v.22 no.2
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    • pp.193-197
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    • 1988
  • Measurement of gastric emptying rate has been performed by a variety of techniques. Nuclear medicine method is a major advance in the quantitative evaluation of gastric function and also of pharmacologic intervention. Normal gastric emptying rate was measured in 48 healthy volunteers using live chicken liver labeled with $^{99m}Tc-Tin$ Colloid as a solid phase marker. In vitro studies were performed to evaluate the labeling efficiency and stability in hydrochloric acid and in human gastric juice of intracellularly labeled chicken liver. Anterior image counts only were compared with the geometric mean of anterior and posterior counts in 12 healthy volunteers who were studied by both anterior count and posterior count. The results were as follows: 1) The labeling efficiency in gastric juice and hydrochloric acid were $95.5{\pm}1.23%,\;95.7{\pm}1.15%$, respectively. 2) Half gastric emptying time by anterior count only was $126{\pm}21$ minutes 3) Although standard deviation of geometric mean method was smaller than anterior count method, gastric emptying curves from both method were similar. In daily practice, anterior count method may be useful alternative to geometric mean method in evaluation of gastric emptying rate.

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Changes in Mechanical Properties of Sanitary Nonwoven Fabrics by Chitosan/Nanosilver Mixed Solution Treatment (위생용 부직포의 키토산/은나노 혼합용액 처리에 의한 역학적 특성 변화)

  • Bae, Hyun-Sook
    • Textile Coloration and Finishing
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    • v.22 no.2
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    • pp.163-172
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    • 2010
  • In order to investigate the changes in mechanical properties of sanitary nonwoven fabrics actually used as a top sheet, the fabric was treated with a mixture of chitosan and nanosilver colloidal solution in accordance with the prescribed ratio. The former is a natural polymer with excellent biocompatibility and the latter can give an additional performance while compensating the weaknesses of chitosan of deteriorating adherence efficiency. It was shown that the bending and shearing characteristics of the chitosan/nanosilver treated fabrics decreased, which helped to make it softer, smoother and more flexible. The shape stability and drapability of the treated fabrics improved. As KES-FB system evaluation showed that Koshi was deduced, and both Numeri and Fukurami were increased. Thereby, the chitosan/nanosilver treated fabrics were smoother to provide elasticity. In the change of hand value compared to chitosan only treatment, a better THV was shown in the fabrics treated with chitosan/nanosilver mixed solution than the fabric treated with chitosan alone.

Factors Affecting the Characteristics of Melamine Resin Microcapsules Containing Fragrant Oils

  • Hwang, Jun-Seok;Kim, Jin-Nam;Wee, Young-Jung;Jang, Hong-Gi;Kim, Sun-Ho;Ryu, Hwa-Won
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.11 no.5
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    • pp.391-395
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    • 2006
  • Microcapsules containing fragrant oils as a core material were prepared by in situ polymerization, using melamine-formaldehyde prepolymer as the wall material. The several parameters, such as stirring times, stirring rates, emulsifier types, emulsifier concentrations, and the viscosity of the core materials, affect the characteristics of the microcapsules. These parameters were investigated by the analyses of microcapsule size, particle size distribution, and morphology. The average microcapsule size decreased with an increase in stirring time, stirring rate, emulsifier concentration, and viscosity of the core material. It was also found that poly(vinyl alcohol) as a protective colloid could enhance the stability of the melamine-formaldehyde microcapsules.

Effects of the Surface Chemical Properties of Silica Sols on the Retention and Drainage of Microparticles Systems

  • Min, Choon-Ki
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.1
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    • pp.26-32
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    • 2000
  • The impact of major surface chemical properties of silica sols on the retention and drainage performance of the silica based micrparticle system, Compozil was investigated using four different silica sols. And the effect of silica properties on the interactions with cationic starch and cationic plyacrylamide has also been identified. The surface charge density and the stability over pH of silica sols were increased by introducing aluminosilicate anions at surface. It was found that the charge density of silica sols determined the addition level necessary to attain the maximum retention and drainage. When silica sols were combined with cationic starch, the change density of the product was the critical properties and the degree of microagregation was of minor importance. In the cationic polyacrylamide system the degree of colloid structure appeared to be a more critcial property than the charge density of silica sols.

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Effects of Protective Colloids on the Formation of Polyurea Microcapsules

  • Lee, Eung-Min;Kim, Hea-In;Park, Soo-Min
    • Textile Coloration and Finishing
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    • v.19 no.5
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    • pp.30-36
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    • 2007
  • Cypermethrin-containing polyurea microcapsules were prepared by interfacial polymerization using aromatic 2,4-toluene diisocyanate(TDI) and Ethylene diamine(EDA) as wall forming materials. The effects of the protective colloids of polyvinylalcohol(PVA) and gelatin were investigated through experimentation. The mean size of the polyurea microcapsules was smaller and the surface morphology of the PVA was much smoother than gelatin. In addition the release behavior was much more controlled and better sustained. As the concentration of protective colloid increased, the wall membrane of the polyurea microcapsules became more stable, the thermal stability of the wall membrane increased, the mean particle size became smaller, and the particle distribution was more uniform. The release behavior of the core material changed according to the concentration. As the gelatin concentration was increased, a more controlled and sustained release behavior was observed. However, in the case of PVA, the increase of PVA concentration lead to a more rapid release rate.

Colloidally stable organic-inorganic hybrid nanoparticles prepared using alkoxysilane-functionalized amphiphilic polymer precursors and mechanical properties of their cured coating film

  • Kim, Nahae;Li, Xinlin;Kim, Se Hyun;Kim, Juyoung
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.209-219
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    • 2018
  • Colloidally stable organic-inorganic (O-I) hybrid nanoparticles could be prepared using an alkoxysilanefunctionalized amphiphilic polymer (AFAP) precursor. O-I hybrid sols could maintain colloidal stability for six months even at 45% solid content and be coated onto glass as well as PET film to form transparent O-I hybrid films. The formation of O-I hybrid nanoparticles dispersed in cured coating films could be confirmed using scanning electron microscopy. The cured coating film showed 3H and 5H pencil hardness on PET and glass, respectively. Nanoindentation measurements also showed that their modulus and hardness was varied with the type of AFAP used in its preparation.

Emulsion Polymerization of Vinyl acetate-Butyl acrylate Copolymer (유화 중합에 의한 비닐 아세테이트-부틸 아크릴레이트 공중합체의 합성 연구)

  • 설수덕;임종민
    • Polymer(Korea)
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    • v.28 no.2
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    • pp.135-142
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    • 2004
  • Poly(vinyl acetate) (PVAc) prepared by emulsion polymerization has broad applications for additives such as paint binder, adhesive for wood and paper due to its low glass transition temperature which help to plasticize substrate resins. Since emulsion polymerization has a disadvantage that surfactant and ionic initiator degrade properties of the product polymer, poly(vinyl acetate-co-butyl acrylate) (VVc-BA) was synthesized using potassium persulfate as catalyst and poly(vinyl alcohol) (PVA) as protective colloid to prevent the degradation. The copolymer latex product was internally plasticized and has enhanced colloid stability, adhesion, tensile strength and elongation. During VAc-BA emulsion polymerization, no coagulation and complete conversion occur with the reactant mixture of 0.7wt% potassium persulfate, 15wt% poly(vinyl alcohol) (PVA-217), and the balanced monomer that the weight ratio of vinyl acetate to butyl acrylate is 19. As the concentrations of PVA increase, the copolymerization becomes faster and polymer particles are more stable, resulting in enhanced mechanical stability of the VAc-BA copolymer. However, the size of the polymer particles decreases with increasing PVA contents. Properties of the VAc-BA copolymer, such as minimum film formation temperature, glass transition temperature, surface morphology, molecular weight and molecular weight distribution, tensile strength and elongation, were characterized using differential scanning calorimeter, transmission electron microscope and other instruments.

Novel Encapsulation with New Glyceryl Ester Vesicle Enhances Stability of Nanoemulsion Containing Astaxanthin (아스타잔틴을 포함하는 나노에멀젼의 안정성 향상을 위한 신규 Glyceryl Ester 이용 캡슐화)

  • Kim, Dong Myung;Hong, Weon Ki;Kong, Soo Sung;Lee, Un Yep
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.39 no.3
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    • pp.225-231
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    • 2013
  • Oil in water nanoemulsion of astaxanthin was prepared by high pressure homogenization. The emulsifying conditions including emulsifier type, concentration and astaxanthin concentration were optimized. Stability of nanoemulsion was measured using zetasizer, freeze-fracture scanning electron microscope (FF-SEM), particle analyzer and colorimeter. The mean diameter of the dispersed particles containing astaxanthin ranged from 160 to 190 nm. Size distribution was unimodal and extended from 40 to 200 nm. The nanoemulsion prepared by glyceryl citrate/lactate/linoleate/oleate had smaller particle size and narrow size distribution. Stable incorporation of astaxanthin in nanoemulsion was performed and checked using high performance liquid chromatography (HPLC), freeze-fracture scanning electron microscope (FF-SEM). Physical stability of nanoemulsion was not significantly changed during storage at both light and thermal condition for a month with zeta potential value of -41 mV meaning stable colloid.

A Note on Preparation of Acid Milk Drink Containing Natural Grape Juice (포도과즙(葡萄果汁) 우유(牛乳) 혼합음료(混合飮料)의 시제(試製))

  • Hah, Duk-Mo
    • Korean Journal of Food Science and Technology
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    • v.7 no.4
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    • pp.250-253
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    • 1975
  • The acid milk containing grape juice was prepared from natural grape juice, acid milk and sugar as raw materials, and the stability of the drink was studied. The following results were obtained. 1. The milk mixed with natural grape juice formed coagulated precipitate by coupling of the colloidal materials in the juice with the milk protein and the formation of precipitate was accelerated by pasteurization. 2. The pectin in natural grape juice was affected on the stability of the product, and the stability increased with decrease in the content of pectin. When the content of pectin in natural grape juice was lower than 2.5mg%, the precipitate was not formed in the drink containing 10 to 20% of the juice. 3. The acid milk drink containing the natural grape juice treated with pectinase, not formed precipitate by pasteurization at $85^{\circ}C$, for 20 minutes and can be preserved for long term.

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Improvement in the Dispersion Stability of Iron Oxide (Magnetite, Fe3O4) Particles with Polymer Dispersant Inject (고분자 분산제 주입을 통한 철산화물(Magnetite, Fe3O4) 입자의 분산 안정성 향상)

  • Song, Geun Dong;Kim, Mun Hwan;Lee, Yong Taek;Maeng, Wan Young
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.656-662
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    • 2013
  • The iron oxide ($Fe_3O_4$) particles in the coolant of the secondary system of a nuclear power plant reduce the heat transfer performance or induce corrosion on the surface of the heat transfer tube. To prevent these problems, we conducted a study to improve the dispersion stability of iron oxide using polymeric dispersant injection in simulated secondary system water. The three kinds of anionic polymers containing carboxyl groups were selected. The dispersion characteristics of the iron oxide particles with the polymeric dispersants were evaluated by performing a settling test and measuring the transmission, the zeta potential, and the hydrodynamic particle size of the colloid solutions. Polymeric dispersants had a significant impact on the iron oxide dispersion stability in an aqueous solution. While the dispersant injection tended to improve the dispersion stability, the dispersion stability of iron oxide did not increase linearly with an increase in the dispersant concentration. This non-linearity is due to the agglomerations between the iron oxide particles above a critical dispersant concentration. The effect of the dispersant on the dispersion stability improvement was significant when the dispersant concentration ratio (ppm, dispersant/magnetite) was in the range of 0.1 to 0.01. This suggests that the optimization of dispersant concentration is required to maximize the iron oxide removal effect with the dispersant injection considering the applied environments, the iron oxide concentration and the concentration ratio of dispersant to iron oxide.