• Toxicological Research
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• v.29 no.2
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• pp.107-114
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• 2013

Mass spectrometry (MS) is a very powerful instrument that can be used to analyze a wide range of materials such as proteins, peptides, DNA, drugs, and polymers. The process typically involves either chemical or electron (impact) ionization of the analyte. The resulting charged species or fragment is subsequently identified by the detector. Usually, single mass uses source-induced dissociation (SID), whereas mass/mass uses collision-induced dissociation (CID) to analyze the chemical fragmentations Each technique has its own advantages and disadvantages. While CID is most effective for the analysis of pure substances, multiple-step MS is a powerful technique to get structural data. Analysis of veterinary drugs ampicillin, chloramphenicol, ciprofloxacin, and oxytetracycline serves to highlight the slight differences between SID and CID. For example, minor differences were observed between ciprofloxacin and oxytetracycline via SID or CID. However, distinct fragmentation patterns were observed for ampicllin depending on the analysis method. Both SID and CID showed similar fragmentation spectra but different signal intensities for chloramphenicol. There are several factors that can influence the fragmentation spectra, such as the collision energy, major precursor ion, electrospray mode (positive or negative), and sample homogeneity. Therefore, one must select a fragmentation method on an empirical and case-by-case basis.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.17 no.3
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• pp.107-114
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• 2017

In beacon-enabled mode, beacon collision is a significant problem for the scalability of cluster-tree wireless sensor networks. In this paper, multi-channel time division scheduling (MCTS) is proposed to prevent beacon collisions and provide scalability. A coordinator broadcasts a beacon frame, including information on allocated channels and time-slots, and a new node determines its own channel and time-slot. The performance of the proposed method is evaluated by comparing the proposed approach with a typical ZigBee. MCTS prevents beacon collisions in cluster-tree wireless sensor networks. It enables large-scale wireless sensor networks based on a cluster tree to be scalable and effectively constructed.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.14 no.2
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• pp.321-328
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• 2010

This paper presents a coordinator-based TDMA reader protocol that can avoid the reader collision in a passive RFID system. In the proposed protocol, the coordinator can not only minimize the number of empty slots by efficiently allocating slots to readers incoming in Poisson distribution, but reduce latency time through the limited frame size. The proposed protocol can be implemented in either mobile or fixed mode through the slot structure to be described in the context. The simulation results show it works as suggested and the frame size limitation as well as the statistical distribution of incoming readers has a great impact on the overall slots and the average latency time.

• Environmental Engineering Research
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• v.23 no.3
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• pp.309-315
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• 2018

Chlortetracycline (CTC) is one of the most important compounds in antibiotic production, and its distribution has been widely investigated due to health and ecological concerns. This study presents systematic approach to optimize the high-performance liquid chromatography-tandem mass spectrometry for analyzing CTC in a multiple reaction monitoring mode ($479{\rightarrow}462m/z$). One-factor-at-a-time (OFAT) test with response surface analysis (RSA) was used as optimization strategy. In OFAT tests, the fragmentor voltage, collision energy, and ratio of acetonitrile in the mobile phase were selected as major factors for RSA. The experimental conditions were determined using a composite in cube design (CCD) to maximize the peak area. As a result, the partial cubic model precisely predicted the peak area response with high statistical significance. In the model, the (solvent composition) and (collision $energy^2$) terms were statistically significant at the 0.1 ${\alpha}$-level, while the two-way interactions of the independent variables were negligible. By analyzing the model equation, the optimum conditions were derived as 114.9 V, 15.7 eV, and 70.9% for the fragmentor voltage, collision energy, and solvent composition, respectively. The RSA, coupled with the CCD, offered a comprehensive understanding of the peak area that responds to changes in experimental conditions.

• Nuclear Engineering and Technology
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• v.54 no.12
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• pp.4560-4570
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• 2022

Dynamic fault tree (DFT) and its related research methods have received extensive attention in safety analysis and reliability engineering. DFT can perform reliability modelling for systems with sequential correlation, resource sharing, and cold and hot spare parts. A technical modelling method of DFT is proposed for modelling ship collision accidents and loss-of-coolant accidents (LOCAs). Qualitative and quantitative analyses of DFT were carried out using the cutting sequence (CS)/extended cutting sequence (ECS) method. The results show nine types of dynamic fault failure modes in ship collision accidents, describing the fault propagation process of a dynamic system and reflect the dynamic changes of the entire accident system. The probability of a ship collision accident is 2.378 × 10^-9 by using CS. This failure mode cannot be expressed by a combination of basic events within the same event frame after an LOCA occurs in a marine nuclear reactor because the system contains warm spare parts. Therefore, the probability of losing reactor control was calculated as 8.125 × 10^-6 using the ECS. Compared with CS, ECS is more efficient considering expression and processing capabilities, and has a significant advantage considering cost.

• Journal of the Korean Society of Marine Environment & Safety
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• v.28 no.4
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• pp.601-609
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• 2022

Jack-up drilling rigs are mobile offshore platforms widely used in the offshore oil and gas exploration industry. These are independent, three-legged, self-elevating units with a cantilevered drilling facility for drilling and production. A typical jack-up rig includes a triangular hull, a tower derrick, a cantilever, a jackcase, living quarters and legs which comprise three-chord, open-truss, X-braced structure with a spudcan. Generally, jack-up rigs can only operate in water depths ranging from 130m to 170m. Recently, there has been an increasing demand for jack-up rigs for operating at deeper water levels and harsher environmental conditions such as waves, currents and wind loads. All static and dynamic loads are supported through legs in the jack-up mode. The most important issue by society is to secure the safety of the leg structure against collision that causes large instantaneous impact energy. In this study, nonlinear FE -analysis and verification of the requirement against collision for 35MJ recommended by DNV was performed using LS-Dyna software. The colliding ship used a 7,500ton of shore supply vessel, and five scenarios of collisions were selected. From the results, all conditions do not satisfy the class requirement of 35MJ. The loading conditions associated with chord collision are reasonable collision energy of 15M and brace collisions are 6MJ. Therefore, it can be confirmed that the identical collision criteria by DNV need to be modified based on collision scenarios and colliding members.

• Journal of Mechanical Science and Technology
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• v.17 no.10
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• pp.1399-1410
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• 2003

In this paper, we develop a joystick manual driving algorithm for an electric vehicle called Cycab. Cycab is developed as a public transportation vehicle, which can be driven either by a manual joystick or an automated driving mode. The vehicle uses six motors for driving four wheels, and front/rear steerings. Cycab utilizes one industrial PC with a real time Linux kernel and four Motorola MPC555 micro controllers, and a CAN network for the communication among the five processors. The developed algorithm consists of two automatic vehicle speed control algorithms for normal and emergency situations that override the driver's joystick command and an open loop torque distribution algorithm for the traction motors. In this study, the algorithm is developed using SynDEx, which is a system level CAD software dedicated to rapid prototyping and optimizing the implementation of real-time embedded applications on distributed architectures. The experimental results verify the usefulness of the two automatic vehicle control algorithms.

• Journal of Navigation and Port Research
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• v.34 no.9
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• pp.693-698
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• 2010

In port and its approach channel, traffic accidents such as collision, aground, minor collision have reached about 77% of total marine casualty in the area. In this paper, an attempt to enhance the safe navigation was proposed by offering marine traffic supporting system which helps VTS operator assist vessel effectively with the quantitative assessment on difficulty of each vessel. The system collects navigation data from onboard AIS, assesses the data in assessment mode to analyze the navigation difficulties of each vessel and displays the degree of danger of each vessel on the ECDIS in real-time to decide the intervention time or order of priority for VTS operator. The effectiveness of the system was verified by the VTS operators in Korea.

• 제어로봇시스템학회:학술대회논문집
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• 2001.10a
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• pp.44.3-44
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• 2001

This articles describes a novel design elastic joint manipulator for a mobile robot, which works in an office environment with humans. The primary goal of this manipulator design is safeness on collision and contact. To achieve this, each joint is made of an elastic element and this is driver with a high ratio gear tram. The performance was verified, however, it has a serious drawback. It produce vibration, due to the elastic joints and high ratio gear train. We found that a sliding mode controller has an excellent performance for reducing such vibration. Results of computer simulation and experiments are shown.

• Journal of the Korea Society for Simulation
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• v.12 no.2
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• pp.75-89
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• 2003

This paper describe numerical experiments with solitary beams in a self focusing Kerr medium with fast response. Through formal analogies, it compare this results on the phase sensitivity of beam collision with known predictions about one dimensional soliton interaction. For incoherent oblique beam interaction, there occurs a non-periodic coupled-mode type transfer of energy, resulting in complete transmission each beam through the other one.