• Bulletin of the Korean Chemical Society
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• 제8권2호
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• pp.88-96
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• 1987

The effects of initial vibrational energy on VV energy transfer in the collinear collision of two diatomic molecules, either homonuclear or heteronuclear, has been studied over a range of collision energies in classical mechanics. When initial vibrational energy is very large, only a small fraction of vibrational energy in the excited molecule is transferred to the colliding partner. In this case, the VV step is found to be strongly coupled with VT during the collision. At low collision energies, energy transfer in the homonuclear case of $O_2$+ $O_2$ with small initial vibrational energy is found to be very inefficient. In the heteronuclear case of CH + HC with the initial energy equivalent to one vibrational quantum, VV energy exchange is found to be very efficient at such energies. Between 0.3 and 0.5 ev, nearly all of vibrational energy of the excited molecule with one to about three vibrational quanta in CH + HC is efficiently transferred to the colliding partner through pure VV process in a sequence of down steps during the collision. The occurrence of multiple impacts during the collision of two heteronuclear molecules and the collisional bond dissociation of homonuclear molecules are also discussed.

• Bulletin of the Korean Chemical Society
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• 제34권11호
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• pp.3350-3356
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• 2013

Quasi-classical trajectory calculations have been carried out for the reaction H+HS by using the newest triplet 3A" potential energy surface (PES). The effects of the collision energy and reagent initial rotational excitation are studied. The cross sections and thermal rate constants for the title reaction are calculated. The results indicate that the integral cross sections (ICSs) are sensitive to the collision energy and almost independent to the initial rotational states. The ro-vibrational distributions for the product $H_2$ at different collision energies are presented. The investigations on the vector correlations are also performed. It is found that the collision energies play a postive role on the forward scatter of the product molecules. There is a negative influence on both the alignment and orientation of the product angular momentum for low collision energy at low energy region. Whereas the influence of collision energy is not obvious at high energy region.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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• pp.416-419
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• 2004

The kinetic energy during ship collision with bridge piers is released as the permanent deformations of structure and friction between the impact surfaces. So the ship collision energy is estimated from the equations of motions for ship-pier collisions which include the influence of the surrounding water, different impact angles and impact locations. The normal impact energy and tangent impact energy at a collision location and angle can be transformed into the normal impact force and friction force acting on the structure. Also the kinetic energy after collisions is calculated from the linear and angular impulse of ship collisions. The collision energy absorption system such as the protective structures for bridges is designed by evaluating the damage portions of ship and structure during the ship-structure collisions varying from the soft impact to hard impact and then the estimation of it will be suited for the design of protective measures.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회A
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• pp.1788-1793
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• 2008

Classical molecular dynamics simulations (MDS) were conducted to simulate nano-sized cluster collisions with a weakly attractive static surface. Energy exchanges associated with the cluster collision and the adhesion probability are discussed. Routes of the energy exchanges and the kinetic energy loss are vastly altered in their mode according to the cluster incident velocity. In the elastic collision regime ($V_0$<0.1), most incident kinetic energy is recovered into the rebounding kinetic energy, but a little loss in the incident kinetic energy causes the cluster adhesion. Dissipated kinetic energy is converted into the rotational energy. In the weakly plastic collision regime (0.1<$V_0$<0.3), the transition from elastic to plastic collision occurs, and a large part of the released potential energy is converted into rebounding translational energy. For strongly plastic collisions ($V_0$>0.3), permanent cluster deformation occurs with extensive collapse of the lattice structure inducing a solid-to-solid phase transition; moreover, most of the cluster kinetic energy is converted into cluster potential and thermal energy.

• 한국해양공학회지
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• 제15권3호
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• pp.120-127
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• 2001

The potential pollution problems resulting from tanker collision necessitate the requirement for an effective structural design and the development of relevant safety regulations. During a few decades, the great effort has been made by the international Maritime Organization and the Administration, etc, to reduce oil spillage from collision accidents. However there is still a need for investigation in the light of structural evaluation method for the experiments and rational analysis, and design development for an operational purpose of ships. This study aims for investigating a complicated structural response of bow structures of simplified models and oil carriers for assessing the energy dissipation and crushing mechanics of the striking vessels through a methodology of the numerical analysis for the various models and its design changes. Through these study an optimal bow construction absorbing great portion of kinetic energy at the least penetration depth prior to reach to the cargo area and an effective location of collision bulkhead are investigated. In order to obtain a rational results in this study, three stages of collision simulation procedures have been performed step by step as follows; 1) 16 simplified ship models are used to investigate the structural response against bow collision with variation of primary and secondary members. Mass and speed are also varied in four conditions. 2) 21 models consisted of 5 sizes of the full scaled oil carriers are used to perform the collision simulation with the various sizes and deadweight delivered in a recent which are complied with SOLAS and MARPOL. 3) 36 models of 100l oil carrier are used to investigate the structural response and its influence to the collision bulkhead against bow collision in variation with location of collision bulkhead, primary members, framing system and colliding conditions, etc. By the first study using simplified models the response of the bow collision is synthetically evaluated for the parameters influencing to the absorbed energy, penetration depth and impact force, etc.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2005년도 춘계 학술발표회 논문집
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• pp.696-703
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• 2005

Recently, the collision problems between a bridge and a navigating ship are frequently issued at the stage of structure design. Even the many study results about vessel to vessel collision are presented, but the collision studies between vessel and bridge structure have been hardly presented. In this study, nonlinear dynamic analysis of vessel and fender system carry out using ABAQUS/Explicit commercial program with consideration of some parameters, such as bow structure we composed to shell element also ship's hull is modeling to beam element. Also, buoyancy effect is considered as spring element. The two types of fender systems was comparable with both collision analysis about steel materials fender system and rubber fender system On the purpose of study is analyzed the plasticity dissipated energy of vessel and fender system. We blow characteristic that kinetic energy is disappeared by plastic large deformation in case of collision. Also, We considered dissipated kinetic energy considering friction effect.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2004년도 춘계학술대회 논문집
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• pp.71-76
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• 2004

선박의 충돌 또는 좌초 사고에 대응하기 위하여 위험 화물을 운반하는 선박의 경우 이중 선체를 채용하고 있으나 이중선체의 충돌 에너지 흡수 정도와 내판의 파단 여부를 효과적으로 판단하는 기준은 아직 연구 대상으로 남아 있다. 본 연구에서는 실제선박의 충돌강도 해석을 하기 위해서 상용해석코드인 LS-DYNA3D를 사용하고 다양한 시나리오에 따라 동적 해석을 수행하였다. 본 연구를 위하여 46K의 Chemical／Product Carrier를 해석 대상 선박으로 정하여 하중 조건과 충돌 속도를 달리하여도 Energy-Indentation, Force-Indentation에 관한 연구를 수행하였다. 본 연구를 통해 얻어진 결과 및 정의는 충돌 사고에서의 매커니즘과 충돌 강도 평가에 유익한 정보를 제공하게 될 것이라 판단된다.

• Mass Spectrometry Letters
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• 제12권4호
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• pp.131-136
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• 2021

Collision-induced dissociation of peptides involves a series of proton-transfer reactions in the activated peptide. To describe the kinetics of energy-variable dissociation, we considered the heat capacity of the peptide and the Marcus-theory-type proton-transfer rate. The peptide ion was activated to the high internal energy states by collision with a target gas in the collision cell. The mobile proton in the activated peptide then migrated from the most stable site to the amide oxygen and subsequently to the amide nitrogen (N-protonated) of the peptide bond to be broken. The N-protonated intermediate proceeded to the product-like complex that dissociated to products. Previous studies have suggested that the proton-transfer equilibria in the activated peptide affect the dissociation kinetics. To take the extent of collisional activation into account, we assumed a soft-sphere collision model, where the relative collision energy was fully available to the internal excitation of a collision complex. In addition, we employed a Marcus-theory-type rate equation to account for the proton-transfer equilibria. Herein, we present results from the integrated thermochemical approach using a tryptic peptide of ubiquitin.

• 한국전산구조공학회논문집
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• 제30권6호
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• pp.485-493
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• 2017

본 연구에서는 LNG 저장시설의 외조를 구성하는 SCP(sandwich concrete panel)에 대한 충돌해석을 수행하고 그 거동을 분석하였다. 설계기준 중 하나인 BS7777에서 제시하는 충돌에너지와 동일한 값을 갖도록 두 종류의 충돌체와 다양한 충돌속도를 이용하여 충돌조건을 구성하고 이에 대한 비선형동적 해석모델을 구성하여 설정된 충돌조건에 대하여 수치해석을 수행하였다. 또한 1차 충돌 후에 동일한 지점에 같은 충돌에너지를 가진 2차 충돌이 일어나는 것을 가정하여 충돌거동을 분석하였다. 해석결과 동일한 충돌에너지를 갖는 충돌에서 충돌체의 크기가 작고, 충돌속도가 작을수록 큰 변형이 발생하는 것으로 나타났다. 충돌에너지는 외측강판과 내부 충진콘트리트가 6:4정도의 비율로 소산시키는 것으로 나타났다. 중복충돌해석에서는 2차 충돌체의 크기에 따라 최종충돌변형이 지배되는 것으로 나타났고 2차 충돌에 의한 변형량은 1차 충돌에 비하여 적은 값을 나타냈는데 이는 강판의 막거동 때문인 것으로 분석되었다. 이격된 중복충돌에서는 이격위치와 관계없이 2차 충돌점에서 가장 큰 변형이 발생하는 것으로 나타났다.

• 천문학논총
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• 제12권1호
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• pp.149-157
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• 1997

The collision model of the disk, based on collisions between the particles in the disk, is summarized. The dependence of disk stability on the collision of the particles is demonstrated. The energy spectrum produced in the disk is numerically calculated. We concluded that the results are not largely different from those of the standard disk model. It implies that the collision of the particles inside the disk may be considered here.