• Korean Journal of Fisheries and Aquatic Sciences
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• v.11 no.4
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• pp.243-247
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• 1978

COD and sulphide contents in the superficial mud in three oyster farms, one near Gajo-do in Chinhae Bay, the second near Eup-do in Koseong Bay and the third near Eogu in Keoje Bay, around the Chungmu area have been monthly determined for seven months from May through November in 1978. Bottom water was also checked for chlorophyll-a, dissolved oxygen, COD and sulphide. In general, large amounts of COD and sulphide in the superficial mud were found in the summer season, COD was 38.1 mg/g dry mud in the farm near Gajo-do, 32.3 mg/g near Eup-do and 25.1 mg/g in Eogu farm and sulphide was 0.313 mg/g dry mud, 0.517 mg/g and 0.132 mg/g respectively. COD and sulphide contents in the farms near Gajo-do and Eup-do were a little over the upper level of the eutrophic range, that is, 30 mg/g dry mud in COD and 0.3 mg/g dry mud in sulphide. It shows that the above two oyster farms were already eutrophicated. However, among three oyster farms no clear difference in bottom water was found.

• Journal of the Korea Organic Resources Recycling Association
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• v.3 no.2
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• pp.37-45
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• 1995

The performance and the operational problems of UASB(Upflow Anaerobic Sludge Blanket) reactor for treatment of dairy wastewaters were investigated. Synthetic milk wastewater was successfully treated up to the loading rate of 3.9kg $COD/m^3.day$, with a specific gas production rate of 1. 23 I/I. day and a COD removal efficiency of over 90%. However, the sludge rising was observed at the loading rate of 2.1kg $COD/m^3.day$, due probably to the formation of scum layer at the surface of settling compartment. The BMP(biochemical methane potential) of raw milk wastewater and ice cream wastewater, measured by using SBT(serum bottle test), were 0.135 and 0.66ml $CH_4/mg\;COD_{added}$, respectively. The sludge activity increased more than 8 times from 0.159g $COD-CH_4/g$ VSS. d during 90 days of operation.

• Journal of Environmental Impact Assessment
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• v.8 no.1
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• pp.81-92
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• 1999

This study discussed the appropriateness of organic matter indexes such as biochemical oxygen demand(BOD) and chemical oxygen demand with potassium permanganate($COD_{Mn}$) in water quality environmental standard of streams and lakes and the applicability of the items to water quality environmental standard to add or substitute COD with potassium dichromate ($COD_{Cr}$) and total organic carbon(TOC) being used as index of organic matter. And indexes of organic matter content and organic carbon concentration were distinguished between dissolved and particulate component in water sample to estimate their effect on pollutants loading in lake and stream. The ratio of $COD_{Cr}$/BOD was 5.1 under BOD concentration 3mg/L in river water quality environmental standard II, and 2.67 above it. This ratio was diminished to 2.04 when BOD concentration was more than 8mg/L, in river quality environmental standard IV. Also the ratio of $COD_{Mn}$/BOD showed 2.16 under 3mg/L(BOD), and 1.1 above it. This ratio is also diminished to 0.84 over 8mg/L(BOD). Accordingly, we should apply this ratio depending on the concentration level to add and change organic matter index of water quality environmental standard newly. The ratio $COD_{Cr}/COD_{Mn}$ both in lake and stream shows 2.37(r=0.986, p<0.001). But the ratios showed range of 2.34~2.50, which is no much difference of this ratio according to $COD_{Mn}$ concentration.

• Journal of Environmental Science International
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• v.28 no.6
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• pp.571-579
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• 2019

In this study, monthly average values of BOD, COD, and TOC observed for 10 years (2008-2017) in the Nam River were estimated, and monthly variations of BOD, COD, and TOC were analyzed. Monthly average COD was always higher than monthly average BOD; monthly average TOC was high from June to September when rainfall was high. Monthly correlation coefficients between BOD and COD ranged from 0.57 to 0.94, those between BOD and TOC from 0.45 to 0.93, and those between COD and TOC from 0.75 to 0.93. The correlation coefficients were high from November to February when rainfall was low. Regression analyses for monthly average water quality data of the Nam River classified into dry season (October to April) and wet season (May to September) were conducted. Correlation coefficients were higher in the dry season than those in the wet season, and the determination coefficients of linear regression functions for BOD and COD with TOC were also higher in the dry season than those in the wet season. From this study, it can be concluded that it is appropriate to use monthly data to analyze the correlations among BOD, COD, and TOC in the stream. To analyze the relationship between TOC flowing into the stream and BOD/COD, it was found that seasonal characteristics should be considered.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.26 no.4
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• pp.207-216
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• 2014

Total organic carbon (TOC) is an important indicator used as an direct biological index in the research field of the marine carbon cycle. It is possible to produce the sufficient TOC estimation data by using the Chemical Oxygen Demand(COD) data because the available TOC data is relatively poor than the COD data. The outlier detection and treatment (removal) should be carried out reasonably and objectively because the equation for a COD-TOC conversion is directly affected the TOC estimation. In this study, it aims to suggest the optimal regression model using the available salinity, COD, and TOC data observed in the Korean coastal zone. The optimal regression model is selected by the comparison and analysis on the changes of data numbers before and after removal, variation coefficients and root mean square (RMS) error of the diverse detection methods of the outlier and influential observations. According to research result, it is shown that a diagnostic case combining SIQR (Semi - Inter-Quartile Range) boxplot and Cook's distance method is most suitable for the outlier detection. The optimal regression function is estimated as the TOC(mg/L) = $0.44{\cdot}COD(mg/L)+1.53$, then determination coefficient is showed a value of 0.47 and RMS error is 0.85 mg/L. The RMS error and the variation coefficients of the leverage values are greatly reduced to the 31% and 80% of the value before the outlier removal condition. The method suggested in this study can provide more appropriate regression curve because the excessive impacts of the outlier frequently included in the COD and TOC monitoring data is removed.

• Journal of Korean Society on Water Environment
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• v.31 no.1
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• pp.29-34
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• 2015

The aim of this study is to understand the limitation of organic pollutant indexes ($BOD_5$, $COD_{Mn}$, $COD_{Cr}$) and estimate to set the TOC standard by comparing oxidation rates of $BOD_5$, $COD_{Mn}$, $COD_{Cr}$ and TOC based on the 487 organic compounds and 11 effluents from industrial wastewater containing various and unknown organic compounds. The range of ratio of theoretical oxygen demand (ThOD) to theoretical organic carbon (TOCt) was 0.00~5.33 and average ratio of classes of organic compounds was 2.68~3.70. According to classes of organic compounds, the average ratio of $O_2/C$ was 1.2 (range : 1.02~1.39). The order of oxidation rate for 15 organic compounds was TOC (90.7%) > $COD_{Cr}$ (88.8%) > $BOD_5$ (54.4%) > $COD_{Mn}$ (30.8%) indicating the lower oxidation rate of $BOD_5$ and COD compared with TOC. The ranking for average oxidation rate was $COD_{Cr}$ > $COD_{Mn}$ > $BOD_5$ indicating that $BOD_5$, $COD_{Mn}$ could be underestimated comparing with ThOD of organic compounds in case of industrial wastewater containing high concentration of refractory organic compounds. Most of the relationships between organic pollutant indexes and TOC were higher than 0.9. The ratio of TOC to organic compound indexes decreased in the order : $COD_{Cr}$ (3.4) > $COD_{Mn}$ > (1.9) > $BOD_5$ (0.7).

• Journal of the Korean Society for Marine Environment & Energy
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• v.15 no.1
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• pp.38-46
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• 2012

This study carried out current status, characteristics, and problems of coastal environment management on semi-enclosed Masan Bay in Korea and suggests cost-effective and eco-friendly water quality management policy. The pollutants from terrestrial sources into the Bay have apparently environmental pollution problems, such as eutrophication, red tide, and hypoxia. The carrying capacity of the Bay is estimated by hydrodynamic model and ecosystem model, material circulation including bivalve in ecosystem is analyzed by the growth model of bivalve. The resulting reduction in the input load was found to be 50~90%, which is unrealistic. When the efficiency of water quality improvement through bivalve farming was assessed based on the autochthonous COD, 30.7% of the total COD was allochthonous COD and 69.3% was autochthonous COD. The overall autochthonous COD reduction rate by bivalve aquaculture farm was found to be about 6.7%. This study indicate that bivalve farming is about 31% less expensive than advanced treatment facilities that remove both nitrogen and phosphorous.

• Journal of Korean Society on Water Environment
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• v.25 no.4
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• pp.589-596
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• 2009

The spectroscopic characteristics and chemical oxygen demand (COD) oxidation efficiencies were investigated for dissolved organic matters (DOM) from diverse sources, which may indirectly affect the concentrations and the quality of DOM found in watersheds. The DOM investigated for this study showed a wide range of the percent distributions of refractory organic matter (R-OM) from 8 to 100%. Relatively high R-OM distributions were observed for the DOM with the source of head water, sediments, paddy soils, field soils, and treated sewage whereas the DOM from livestock waste, reed, weeds, algae, and attached algae exhibited lower R-OM percent distributions. The percent distribution of R-OM had positive correlations with specific UV absorbance (SUVA) and humidification indices (HIX) of DOM. The investigated DOM was classified into four different source groups (i.e., biota, vegetables, soils, sediments) by comparing the synchronous fluorescence spectra. The DOM group from biota source was characterized by a prominent presence of protein-like fluorescence (PLF) whereas fulvic-like fluorescence (FLF) was additionally observed for vegetable-source DOM. FLF became significant for the DOM from both soils and sediments although no PLF was found for soil-derived DOM. A range of COD oxidation efficiency was observed for the various DOM, ranging from 36 to 94% and from 65 to 125% for $COD_{Mn}$ and $COD_{Cr}$, respectively. The results indicate that $COD_{Cr}$ reflects the higher OM concentration than $COD_{Mn}$. However, 95% confidence intervals of the COD oxidation efficiencies were similar for the two types of COD, suggesting that $COD_{Cr}$ may not be the superior OM index to $COD_{Mn}$ in terms of the variability of the oxidation efficiency. No significant correlations were obtained between COD oxidation efficiencies and the spectroscopic characteristics of DOM for this study.

• Journal of Wetlands Research
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• v.20 no.2
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• pp.173-180
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• 2018

The utilization of TOC(Total organic carbon), a new environmental standard, was evaluated for 30 lakes in the Nakdong River Basin, which is used for drinking and agricultural usage. The active use of water resources begins with securing satisfactory water quality. Since this allows people and nature to maintain stability of quality, water quality standards are being tightened to ensure good water quality. In order to improve the pollution level of organic matter in lakes in the living environment, it is important to use the appropriate organic substance index. The relationship between the newly introduced TOC and the existing COD(Chemical oxygen demand) in the targeted lake was positively correlated with the possibility of replacing the TOC with COD. However, the environmental grade standard using TOC is better than the environmental grade standard using COD, so it has the same effect as that of the grade of water quality using TOC as an organic substance factor. This indicates the limitation of TOC to directly replace existing COD when trying to determine or improve the quality level using organic indicators of lakes. Therefore, in order to secure the qualitative safety of the lake, it is required to strengthen environmental standards of TOC in terms of water quality grade. In addition, the correlation between TOC and COD shows a great difference depending on the utilization characteristics of the lake. This requires clear scientific identification, and it requires continuous monitoring of COD that has been used to accumulate indicators of lake organic matter.

• The Journal of Engineering Geology
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• v.16 no.4 s.50
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• pp.373-379
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• 2006

We investigated the relationship of the organic pollutant index in wastewater where the high percentages of an organic load to a water body was found. Measuring of TOC was to identify the relationship with COD and BOD which were used already. The correlation coefficient (r) of TOC/COD, BOD/COD and TOC/BOD were effected by the types of industry such as paper, textile, chemical, food and metal industries. In food industry it was found that the highest correlation coefficient (r) of TOC/COD, BOD/COD and TOC/BOD as 0.967, 0.969 and 0.990, respectively. There is low correlation coefficient in many cases. Hence it was impossible that the use of TOC for the water standard or monitoring instead of COD and BOD directly. However it can be used as alternative index to management a water process in the case of waste water where there was found high correlation coefficient of TOC/ COD, BOD/COD and TOC/BOD. It was sure that the water quality of river body can be protected if we use these the relationship among organic index.