• 한국재료학회지
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• 제26권11호
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• pp.662-669
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• 2016

In order to identify changes in the nature of the particles due to changes in the inflow rate of the raw material solution, the present study was intended to prepare nano-sized cobalt oxide ($Co_3O_4$) powder with an average particle size of 50 nm or less by spray pyrolysis reaction using raw cobalt chloride solution. As the inflow rate of the raw material solution increased, droplets formed by the pyrolysis reaction showed more divided form and the particle size distribution was more uneven. As the inflow rate of the solution increased from 2 to 10 ml/min, the average particle size of the formed particles increased from about 25 nm to 40 nm, while the average particle size did not show significant changes when the inflow rate increased from 10 to 50 ml/min. XRD analysis showed that the intensity of the XRD peaks increased remarkably when the inflow rate of the solution increased from 2 to 10 ml/min. On the other hand, the peak intensity stayed almost constant when the inflow rate increased from 10 to 50 ml/min. With the increase in the inflow rate from 2 to 10 ml/min, the specific surface area of the particles decreased by approximately 20 %. On the contrary, the specific surface area stayed constant when the inflow rate increased from 10 to 50 ml/min.

• 한국분말재료학회지
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• 제10권4호
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• pp.228-234
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• 2003

In the present study, the focus is on the synthesis of titanium carbide/cobalt composite powder by the spray thermal conversion process using metallic salt solution as the raw materials. Two types of oxide powders of Ti-Co-O system were prepared by the spray drying of two types of metallic salt solutions : titanium chloride-cobalt nitrate and $TiO_2$ powder-cobalt nitrate solutions. These oxide powders were mixed with carbon black, and then these mixtures were carbothermal reduced under a flowing argon atmosphere. The changes in the phase structure and thermal gravity of the mixtures during carbothermal reduction were analysed using XRD and TG-DTA. In the case of using the titanium chloride-cobalt nitrate solution, it could not be obtained TiC/Co composite powder due to contamination of the impurities during the spray drying of the solution. However, in tile case of using the $TiO_2$ powder-cobalt nitrate scullion, TiC-15 wt. %Co composite powder could be synthesized by the spray thermal conversion process. The synthesized TiC-15 wt. %Co composite powder at 120$0^{\circ}C$ for 2 hours has average particle size of 150 nm.

• Korean Chemical Engineering Research
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• 제52권4호
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• pp.436-442
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• 2014

염화코발트 용액을 사용하여 전자기파와 진동에 영향을 받지 않는 원거리 실시간 광섬유 온도 감지 센서를 개발하였다. 염화코발트 용액을 제조하기 위하여, 물과 에탄올은 부피 비율로 10%와 90%로 고정하고, 용해되는 염화코발트의 양을 다양하게 변화시켰다. 제조된 염화코발트 용액은 자외-가시선 분광 광도계를 사용하여, 온도 변화에 따른 655 nm 파장의 투과도를 측정하였다. 또한 제조된 30.8 mM 염화코발트 수화물 용액에 polyvinyl butyral을 용해시켜 겔화한 후, 온도 변화에 따른 655 nm 파장의 투과도 측정 및 센서 적용 후 광 파워 분석을 실시하였다. 투과도와 광 파워 측정 결과, $25^{\circ}C$에서 66.8%와 149.5 nW, $70^{\circ}C$에서는 7.1%와 48 nW로 각각 나타나, 온도가 증가함에 따라 투과도와 광 파워 모두 감소하는 경향을 보였다. 본 실험에서 제조된 겔화 염화코발트/polyvinyl butyral은 온도 변화에 따라 655 nm 파장에 대한 광 투과도와 광 파워가 변하는 점을 이용하여 온도 변화를 감지하기 위한 광섬유 센서로 사용 가능함을 확인하였다.

• 대한화학회지
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• 제31권3호
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• pp.231-235
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• 1987

니켈중 미량의 코발트를 분리하는데 액상음이온교환수지인 Amberlite LA-2를 이용하였다. 10M 염소이온 (4M HCl + 6M LiCl) 용액중에서 코발트는 ${CoCl_3}^-$를 형성하여 Amberlite LA-2 1ml에 2.175meq 추출되었다. 그러나 같은 조건의 염소이온용액에서 니켈은 착음이온을 형성하지 않으므로 전연 추출되지 않았다. 수지층에 추출된 코발트는 0.4M 질산용액에 의해 정량적으로 용리되었다. 코발트 50mg과 니켈 500mg을 녹인 합성시료용액중에 본 분리 방법을 적용시킨 결과 99.6%의 코발트를 분리회수 하였다.

• 한국재료학회지
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• 제24권1호
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• pp.25-32
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• 2014

In this study, nano-sized cobalt oxide powder with an average particle size below 50 nm was prepared from a cobalt chloride solution by the spray pyrolysis process. The influences of reaction temperature on the properties of the generated powder were examined. The average particle size of the particles formed based on the spray pyrolysis process at a reaction temperature of $700^{\circ}C$ is roughly 20 nm. Moreover, most of these particles cannot appear with an independent type, thereby coexisting in a droplet type. When the reaction temperature increases to $800^{\circ}C$, the average particle size not only increases to roughly 40 nm but also shows a more dense structure while the ratio of particles which shows a polygonal form significantly increases. As the reaction temperature increases to $900^{\circ}C$, the distribution of the particles is from roughly 70 nm to 100 nm, while most of the particle surface is more intricately close and forms a polygonal shape. When the reaction temperature increases to $1000^{\circ}C$, the particle size distribution of the powder shows an existing form from 80 nm to at least 150 nm in an uneven form. As the reaction temperature increases, the XRD peak intensity gradually increases, yet the specific surface area gradually decreases.

• 대한화학회지
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• 제40권5호
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• pp.302-307
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• 1996

디에탄올아민 디티오카바메이트는 염화디스클로로비스에틸렌디아민)코발트(III)와 반응하여 [$Co(dtc)_3$](dtc=디에탄올아민 디티오카바메이트)를 생성한다. 이때 두 황원자는 코발트에 배위된다. 이 착물은 아세톤에 어느 정도 녹으나 이황산산소와 같은 비극성 용매에는 거의 녹지 않았다. 디에탄올아민 디티오카바메이트와 염화디스클로로비스에틸렌디아민)코발트(III)의 반응속도를 측정하고 이들 결과에서 얻어진 활성화 파라미터에서부터 가능한 메카니즘을 제시하고자 한다.

• 한국재료학회지
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• 제24권6호
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• pp.277-284
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• 2014

Using the spray pyrolysis process, nano-sized cobalt oxide powder with average particle size below 50 nm was prepared from cobalt chloride solution. The influences of the raw material solution on the properties of the powder formed examined. When the concentration of Co was low(20 g/L), the average particle size of the powder formed was roughly 20 nm, and the cohesion between these particles was significantly strong. When the concentration of Co increased to 100 g/L, the droplets nearly failed to exist in circular form and reflected a severely divided form. Furthermore, the average size of the particles formed was roughly 40 nm, and the particles reflected a polygonal form. When the solution was increased to nearly saturation level (Co at 200 g/L), the particle size distribution reflected significant unevenness due to severe droplet division while the surface also reflected significant unevenness. Furthermore, the average size of the particles formed increased significantly to 70 nm. The results of XRD analysis showed that the strength of the peaks reflected very little change when the concentration of Co was increased from 20 g/L to 50 g/L. Alternatively, when the concentration was increased to 100 g/L, the strength of the peaks increased compared to when the concentration was 50 g/L. However, when the concentration was increased to 200 g/L, the strength of the peaks failed to reflect significant change compared to when the concentration was 100 g/L. The specific surface area dramatically decreased by 30 % when the concentration of Co was increased from 20 g/L to 50 g/L. Alternatively, when the concentration of Co the solution increased to 100 g/L, the specific surface area decreased by roughly 15 %. Furthermore, when the concentration of Co was increased to nearly saturation level(200 g/L), the specific surface area decreased by roughly 35%.

• 한국분말재료학회지
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• 제21권2호
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• pp.93-96
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• 2014

Cobalt coated tungsten carbide-cobalt composite powder has been prepared through wet chemical reduction method. The cobalt sulfate solution was converted to the cobalt chloride then the cobalt hydroxide. The tungsten carbide powders were added in to the cobalt hydroxide, the cobalt hydroxide was reduced and coated over tungsten carbide powder using hypo-phosphorous acid. Both the cobalt and the tungsten carbide phase peaks were evident in the tungsten carbide-cobalt composite powder by X-ray diffraction. The average particle size measured via scanning electron microscope, particle size analysis was around 380 nm and the thickness of coated cobalt was determined to be 30~40 nm by transmission electron microscopy.

• Current Optics and Photonics
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• 제5권3호
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• pp.238-242
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• 2021

In this paper, we present an in line plastic-optical-fiber (POF) temperature sensor based on intensity modulation. The in line POF temperature sensor is composed of a POF, including an in-fiber micro hole filled with reversible thermochromic material, the transmittance of which depends on temperature. The reversible thermochromic material was cobalt chloride/polyvinyl butyral gel. A cobalt chloride solution of concentration 30.8 mM was formulated using 10% water/90% ethanol (v/v) solution, and gelled by dissolving polyvinyl butyral in this solution. Four types of in line POF sensors, with in line micro holes of four different diameters, were fabricated to measure temperature in the range of 25 to 75 ℃. The output optical power of all of these in line POF temperature sensors was inversely proportional to the temperature; the relation between output power and temperature was approximately linear, and the sensitivity was proportional to the diameter of the in-fiber micro hole. The experimental results indicate that an in line POF sensor can be used effectively for measuring moderate temperatures.

• 대한화학회지
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• 제51권6호
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• pp.479-486
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• 2007

Bicarbonate 완충용액에서 Co-RDE를 이용하여 RDE 회전속도와 완충용액 속의 염화이온이 Co의 부식과 부동화에 미치는 영향을 연구하였다. Co-RDE의 회전속도가 부식에 미치는 영향은 Levich 식과 일치하였으며 부동화 막을 파괴하는데 염화이온의 효과가 큼을 알 수 있었다. 혼합 전위 이론을 사용하여 대류확산 조건에서 회전속도의 증가에 따라 부식전위가 양의 방향으로 증가하는 모형을 발견하였다. Tafel 영역에서 Co의 용해반응과 수소가 발생하는 환원반응은 전하이동과 물질이동을 이용하여 설명할 수 있었다.