• Title/Summary/Keyword: coating area

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Removal of arsenic from aqueous phase using magnetized activated carbon and magnetic separation

  • Kwon, H.W.;Shin, T.C.;Kim, J.J.;Ha, D.W.;Kim, Min Gyu;Kim, Young-Hun
    • Progress in Superconductivity and Cryogenics
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    • v.20 no.2
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    • pp.1-5
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    • 2018
  • Arsenic (As) is one of the elements having most harmful impact on the human health. Arsenic is a known carcinogen and arsenic contamination of drinking water is affecting on humans in many regions of the world. Adsorption has been proved most preferable technique for the removal of arsenic. Many researchers have studied various types of solid materials as arsenic adsorbent, and iron oxide and its modified forms are considered as the most effective adsorbent in terms of adsorption capacity, recovery, and economics. However, most of all iron oxides have small surface area in comparing with common adsorbents in environmental application such as activated carbon but the activated carbon has weak sorption affinity for arsenic. We have used an activated carbon as base adsorbent and iron oxide coating on the activated carbon as high affinity sorption sites and giving magnetic attraction ability. In this study, adsorption properties of arsenic and magnetic separation efficiency of the magnetized activated carbon (MAC) were evaluated with variable iron oxide content. As the iron oxide content of the MAC increased, adsorption capacity has also gradually increased up to a point where clogging by iron oxide in the pore of activated carbon compensate the increased sorption capacity. The increase of iron oxide content of the MAC also affected magnetic properties, which resulted in greater magnetic separation efficiency. Current results show that magnetically modified common adsorbent can be an efficiency improved adsorbent and a feasible environmental process if it is combined with the magnetic separation.

The Effect of Surface Protective Material on the Impact Resistance in Filament Wound Composite Pressure Vessel (필라멘트 와인딩 복합재 압력용기의 충격저항성에 미치는 표면 고무 보호재료의 영향)

  • Kang, Ki-Weon;Kim, Young-Soo;Lee, Mee-Hae;Choi, Rin
    • Journal of the Korean Society of Safety
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    • v.20 no.4 s.72
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    • pp.14-19
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    • 2005
  • One area in which composites have been used rather extensively is for fabricating pressure vessel. These structures can be readily manufactured by filament winding, which is, as far as composite fabrication techniques are concerned, a relatively inexpensive method for producing composite structures. Unfortunately, the higher strength material and fabrication costs are not the only disadvantages of fiber-reinforced polymer composites when they are compared to metals. Additionally, these materials tend to exhibit brittle behavior. This is of particular concern when they are subjected to a low-velocity impact during routine handling a significant amount of structural damage can be introduced into the composites. The goals of this paper are to understand the impact damage behavior and identify the effect of surface coating materials on impact resistance in filament wound composite pressure vessels. For these, a series of low velocity impact tests was performed on specimens cutting from the full scale pressure vessel by the instrumented impact testing machine. The specimens are classified into two types with and without surface protective material. The visualization for impact damage is made by metallurgical microscope. Based on the impact force history and damage, the resistance parameters were employed and its validity in identifying the damage resistance of pressure vessel was reviewed. As the results, the impact resistance of the filament wound composites and its dependency on the protective material were evaluated quantitatively.

Preparation and Characterization of High-performance Photocatalyst for Photoelectrocatalytic System (PECS) (광전자촉매시스템(PECS) 적용을 위한 고효율 광촉매의 제조와 특성)

  • Park, Seong-Ae;Yu, Dong-Sik;Lee, Ji-Ho;Do, Young-Woong;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.6
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    • pp.1302-1307
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    • 2006
  • This study describes the preparation of high-performance photocatalyst and its environmental applications. We prepared visible-light response nano-particle photocatalyst exhibiting the similar photocatalytic activity with $TiO_2$, dispersed $TiO_2$ on $SiO_2$ with an active rutile type titanium oxide prepared at low temperature. The binder and stable photocatalytic $TiO_2$ sol for photocatalytic system were also prepared. Such products were evaluated by UV/Vis spectrometer, X-ray diffraction analysis, SEM, measurement of photocatalytic activities and surface area, mechanical properties of $TiO_2$-coated surfaces. The results obtained can be applied in efficient photocatalytic systems using POF and metal plate for the purification of air.

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Highly Photocatalytic Performance of flexible 3 Dimensional (3D) ZnO nanocomposite

  • Lee, Hyun Uk;Seo, Jung Hye;Son, Byoungchul;Kim, Hyeran;Yun, Hyung Joong;Jeon, Cheolho;Lee, Jouhahn
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.270.1-270.1
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    • 2013
  • Zinc oxide (ZnO) is one of the most powerful materials for purifying organic pollutants using photocatalytic activity. In this study, we have introduced a novel method to design highly photoreactive flexible 3 dimensional (3D) ZnO nanocomposite [F-ZnO-m (m: reaction time, min)] by electrospinning and simple-step ZnO growth processing (one-step ZnO seed coating/growth processing). Significantly, the F-ZnO-m could be a new platform (or candidate) as a photocatalytic technology for both morphology control and largearea production. The highest photocatalytic degradation rate ([k]) was observed for F-ZnO-m at 2.552 h-1, which was 8.1 times higher than that of ZnO nanoparticles (NPs; [k] = 0.316 h-1). The enhanced photocatalytic activity of F-ZnO-m may be attributed to factors such as large surface area. The F-ZnO-m is highly recyclable and retained 98.6% of the initial decolorization rate after fifteen cycles. Interestingly, the F-ZnO-m samples show very strong antibacterial properties against both Gram-negative Escherichia coli (E. coli) and Gram-positive Staphylococcus aureus (S. aureus) after exposure to UV-light for 30 min. The antibacterial properties of F-ZnO-m samples are more effective than those of ZnO NPs. More than 96.6% of the E. coli is sterilized after ten cycles. These results indicate that F-ZnO-m samples might have utility in several promising applications such as highly efficient water/air treatment and inactivation of pathogenic microorganisms.

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A Study on the E-textiles Dip-Coated with Electrically Conductive Hybrid Nano-Structures

  • Lee, Euna;Kim, Jongjun
    • Journal of Fashion Business
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    • v.21 no.6
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    • pp.16-30
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    • 2017
  • Currently, e-textile market is rapidly expanding and the emerging area of e-textiles requires electrically conductive threads for diverse applications, including wearable innovative e-textiles that can transmit/receive and display data with a variety of functions. This study introduces hybrid nano-structures which may help increase the conductivity of the textile threads for use in wearable and flexible smart apparels. For this aim, Ag was selected as a conductive material, and yarn treatment was implemented where silver nanowire (AgNW) and graphene flake (GF) hybrid structures overcome the limitations of the AgNW alone. The yarn treatment includes several treatment conditions, e.g., annealing temperature, annealing time, binder material such as polyurethane (PU), coating time, in order to search for the optimum method to form stable conductive nano-scale composite materials as thin film on the surface of textile yarns. Treatedyarns showed improved electrical resistance readings. The functionality of the spandex yarn as a stretchable conductive thread was also demonstrated. When the yarn specimens were treated with colloid of AgNW/GF, relatively good electrical conductivity value was obtained. During the extension and recovery cycles of the treated yarns, the initial resistance values did not deteriorate significantly, since the network of nanowire structure with the support of GF and polyurethane stayed flexible and stable. Through this research, it was found that when one-dimensional structure of AgNW and two-dimensional structure of GF were mixed as colloids and treated on the surface of textile yarns, flexible and stretchable electrical conductor could be formed.

Analysis of Multi-layered Thin Film Using ATR FT-IR and pyro-GC/MS (ATR FT-IR과 pyro-GC/MS를 이용한 다층박막필름의 분석)

  • Park, Sung Il;Lee, Jung-Hyun;Lee, Myung Cheon
    • Journal of Adhesion and Interface
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    • v.20 no.3
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    • pp.102-109
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    • 2019
  • The material constitution of multi-layered thin film coated on the PET base film was analyzed using ATR FT-IR and pyro GC/MS combination. The cross section of the film was acquired by cracking the film after dipping in liquid nitrogen and was observed using optical microscope. Total thickness of the coated film was $70{\mu}m$ and three layers were observed. Since each layers were too thin to analyze directly except the surface layer, analyzable area of each layers were exposed by using a proper solvent and were investigated using ATR FT-IR and pyro GC/MS. Results shows that three layers were commonly consisted of urethane-acrylate copolymers. Also, inorganic and/or metal inclusions detected by XPS and SEM-EDAX were exhibited by nano size $SiO_2$ particles in layer(1) and aluminum flakes in layer(2).

Swimming Suitability and Management of Sea Water for Artificial created Swimming in the Southwestern Sea of Korea (한국 서남해역 인공해수욕장의 적합성 판정과 수질관리 방안)

  • Kim, Do-Hee;Chang, Jin-Ho
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.20 no.6
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    • pp.640-645
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    • 2014
  • This study aimed to determine the swimming suitability of sea and to suggest methods to address the problems on sea water color and green plants growing on sediment in the artificial created swimming in the beach of southwestern Korea. Sea water samples were collected from January to December of 2010 and analysis for SS, COD, $NH_4{^+}-N$, TP, MPN, sediment IL, ORP and plants on sediment. The results showed that the sea water under the swimming suitability "level of management" based on the relating high levels of SS and TP, but still suitable for swimming on the basis of MPN. Improving exchange seawater flow, dredging, coating and chemical treatment of polluted sediments in addition to removal of point sources and restriction of non point sources in the study area could improve the sea water quality and swimming suitability of the sea.

Thermal Performance Assessment of Insulated door by experiment. (실측 실험을 통한 단열문의 열성능 평가)

  • Jang, Cheol-Yong;Kim, Chi-Hoon;Ahn, Byung-Lip;Hong, Won-Hwa
    • Journal of the Korean Solar Energy Society
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    • v.31 no.2
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    • pp.47-52
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    • 2011
  • Currently, Exterior wall's U-value about building envelope is 0.36 W/$m^2K$(Central Region), but window's one is 2.1 W/$m^2K$ according to air gap of glazing, filling gas, coating and type of windows. The door"s one is 1.6~5.5 W/$m^2{\cdot}K$ depending on material and configuration of door. As such, energy loss per unit of door is considerably larger like windows. The door for the recognition was relatively low because energy loss through the door is relatively small compared to window area. In this paper, thermal performance was analyzed through simulation targeting the door which has thermal break that can improve the insulation performance and doesn't have one. As a results of simulations, case1 was calculated as the average of 1.63 w/m2k and case 2 was calculated as the average of 4.14 w/m2k. The thermal performance of door depends on the type and condition of insulations. As a results of final simulations, Case1 was calculated as 1.06 w/m2k and Case2 was calculated as 1.27 w/m2k. As a results of the experiments, thermal performance of case 1 was measured as 1.28 w/m2k. Error between experiments and simulations is considered problems encountered when creating the samples. The effect of door frame on the overall thermal performance is slight because it's a small proportion of the door frame.

Effects of Surface Color and Morphology on the Mar Behaviors of Urethane-Acrylate Coatings (우레탄 아크릴 코팅 소재의 표면 색상 및 모폴로지가 긁힘 거동에 미치는 영향)

  • Jung, Won-Young;Weon, Jong-Il
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.1-8
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    • 2014
  • The effects of surface color and morphology on the mar behaviors of urethane-acrylate coated surfaces were examined. The superiority of mar resistance was observed in the order of white, red and black-colored samples. This can be explained by a contrast effect. In other words, in case of black colored sample, it takes place the defuse reflection of the incident light on the damaged region where mar damage exerts, leading to whitening phenomenon. Therefore, the damaged region is easily recognized by contrasting the black background. On the other hand, it is difficult for the white-colored sample to perceive the mar-damaged area by the white background acting as protecting coloration. As the gloss of urethane-acrylate coated surface increases, it is observed that there is an increase in the number of carbonyl (-C=O) function group, amount of ethylene and silica. The enhancements of surface rigidity by adding the silica particles and formation of carbonyl function groups by the surface oxidation lead to the increase in mar resistance, while the increase of polyethylene wax is responsible for the improved gloss and smooth-faced surface. Based on the above findings, technical approaches leading the improvement of mar resistance of the urethane-acrylate coated surface are discussed.

Microstructure and Strength Characteristic of Hydropobic Cement Mortar with Silan Admixture (실란계 혼화제가 혼입된 소수성 시멘트 모르타르의 미세구조 및 강도특성)

  • Kim, Younghwan;Oh, Hongseob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.2
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    • pp.127-134
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    • 2021
  • A hydrophobic emulsion consisting of PMHS and PVA was mixed into a cement mortar to observe changes in cement hydrate and microstructure, and to experimentally evaluate compressive strength and flexural strength. The hydrophobic emulsion was added with metakaolin and PVA fibers, and the stirring speed and sequence were adjusted to prepare a shell-concept hydrophobic emulsion. It was then mixed when mixing mortar to enhance filling of the internal pores and change of the hydrates. It was observed that the mortar mixed with a hydrophobic emulsion was filled with micropores and a coating film was formed on the surface of the hydrates by the emulsion. It was analyzed that the total pore area and porosity of the mortar mixed with the emulsion decreased from 30% to 60% compared to OPC, excluding the 50MK variable, which was extremely reduced and the median pore diameter decreased in some variables. It was also found that the compressive strength of the mortar mixed with emulsion 1% was increased up to 20%, but the strength of the mortar specimen mixed with 2% decreased to 50%.