• 대한금속재료학회지
• /
• 제47권5호
• /
• pp.290-296
• /
• 2009

We report on the effects of mixing of powders with various particle sizes on fracture toughness and wear resistance of thermally sprayed WC-10Co-4Cr coating layers fabricated by HVOF (high-velocity oxygen fuel) process. The size and the mixing ratio of powders were changed in order to get high fracture toughness and wear resistance. The mixing of small amount of coarse powders with fine powders resulted in the highest fracture toughness and wear resistance due to the lowest porosity in coating layers.

• 한국표면공학회지
• /
• 제53권4호
• /
• pp.182-189
• /
• 2020

Indium tin oxide (ITO) used a transparent electrode of a photoelectric device has a low sheet resistance and a high transmittance. However, ITO is disadvantageous in that the process cost is expensive, and the process time is long. Silver nanowires (AgNWs) transparent electrodes are based on a low cost solution process. In addition, it has attracted attention as a next-generation transparent electrode material that replaces ITO because it has similar electrical and optical characteristic to ITO, it is noted as a. AgNW thin films are mainly produced by spin-coating. However, the spin-coating process has a disadvantage of high material loss. In this study, the material loss was reduced by using about 2~10 ㎕ of AgNW solution on a (25 × 25) ㎟ substrate using the shear-coating method. It was also possible to align AgNWs in the drag direction by dragging the meniscus of the solution. The electro-optical properties of the AgNW thin film were adjusted by changing the experimental parameters that the amount of AgNWs suspension, the gap between the substrate and the blade, and the coating speed. As a result, AgNW thin films with a transmittance of 90.7 % at a wavelength of 550 nm and a sheet resistance of 15 Ω/□ was deposited and exhibited similar properties to similar AgNW transparent electrodes studied by other researchers.

• Korean Chemical Engineering Research
• /
• 제50권3호
• /
• pp.427-434
• /
• 2012

Poly (carbonate diol)과 isophrone diisocyanate 그리고 dimethylol propionic acid로 부터 NCO/OH 몰 비를 0.8, 1.1, 1.3으로 각각 조절하여 수분산 폴리우레탄(waterborne polyurethane dispersion, PUD)을 합성하였다. 이 용액에 알카리 금속염인 $LiClO_4$, $NaClO_4$, $KClO_4$를 첨가하여 대전방지용 수분산 폴리우레탄 코팅 용액을 제조하였다. 이 과정에서 첨가되는 알카리 금속염의 첨가량과 종류가 코팅 도막의 표면저항에 미치는 영향을 살펴보았다. 알카리 금속염의 첨가량이 증가될수록 코팅 도막의 표면저항은 감소하였다. 그러나 PUD에 같은 양의 알카리 금속염이 첨가될 경우에는 $LiClO_4$ > $NaClO_4$ > $KClO_4$의 순서로 코팅 도막의 이온 전도도가 우수함을 알 수 있었다. 또한 PUD 내의 NCO/OH 몰 비가 증가함에 따라 코팅 도막의 표면저항이 증가하여 이온 전도도가 감소하였다.

• 한국산학기술학회논문지
• /
• 제17권1호
• /
• pp.629-637
• /
• 2016

본 연구는 구강관리행태와의 연관성과 설태지수, 치석, 스케일링 전후의 구강환경에 따른 구취변화를 알아보고자 대전광역시에 위치한 K대학교 치위생학과에 스케일링 실습을 위해 내방한 참여자 130명을 대상으로 설태지수와 구취를 조사하여 조사하였다. 모든 조사대상자에 대하여 설문조사, 설태지수와 치면세균막과 치석정도를 측정한 구강검사, 구취측정 등을 하였다. 그 결과 설태가 구취에 가장 큰 영향을 준다는 것을 확인할 수 있었고, 이러한 설태지수는 흡연과 혀 닦기와 관련이 높았다. 또한 구취는 잇솔질 횟수가 많을수록 낮은 수치를 보였고 비외과적 치료인 스케일링을 통해 구취감소의 효과가 나타났으며, 나이와 설태지수가 관련요인임을 확인하였다. 이에 적절한 구강관리를 실천하여 치태과 설태의 양을 줄이고 정기적인 스케일링을 받음으로써 구강건강증진은 물론 구취감소의 효과를 얻어야 할 것이다.

• 반도체디스플레이기술학회지
• /
• 제21권2호
• /
• pp.25-31
• /
• 2022

By an aid of needle coating, we have fabricated a spherical microlens array using poly(methyl methacrylate) for potential applications in light extraction of organic light-emitting diodes. With an attempt to achieve high-density and high-aspect-ratio microlens arrays, we have investigated the coating behaviors by varying the material parameters such as the solute concentration and wettability of the poly(methyl methacrylate) solution and process parameters such as the dwell time of needle near the substrate, retract distance of needle from the substrate, and coating gap between the needle and substrate. Under the optimized coating conditions, it is demonstrated that high-aspect-ratio microlens arrays can be obtained using a coating solution with high solute concentration and a small amount of a hydrophobic solvent. It is found that the diameter and height of microlens array are decreased with increasing poly(methyl methacrylate) concentration, yet the overall aspect ratio is rather enhanced. By the addition of 5 wt% hexylamine in 35 wt% poly(methyl methacrylate) solution, we have achieved a spherical microlens with the height of 7.7 ㎛ and the width of 94.24 ㎛ (the aspect ratio of 0.082). To estimate the capability of light extraction by the microlens array, we have performed ray tracing simulations and demonstrated that the light extraction efficiency of organic light-emitting diode is expected to be enhanced up to 24%.

• Korean Chemical Engineering Research
• /
• 제59권2호
• /
• pp.174-179
• /
• 2021

Recently, hybrid coal research is underway to upgrade low-grade coal. The hybrid coal is made by mixing low-grade coal with bioliquids such as molasses, sugar cane, and lignin. In the case of lignin used here, a large amount of lignin is included in the wastewater of the papermaking process, and thus, research on hybrid coal production using the same is attracting attention. However, since a large amount of metal ions are contained in the lignin wastewater from the papermaking process, substances that corrode the generator are generated during combustion, and the amount of fly ash is increased. To solve this problem, it is essential to remove metal ions in the lignin wastewater. In this study, metal ions were removed by ion exchange with a alumina hollow fiber membrane coated with K-Phillipsite (K-PHI) zeolite. The alumina hollow fiber membrane used as the support was prepared by the nonsolvent induced phase separation (NIPS) method, and K-PHI seeds were prepared by hydrothermal synthesis. The prepared K-PHI seed was seeded on the surface of the support and coated by secondary growth hydrothermal synthesis. The characteristic of prepared coating membrane was analyzed by Scanning Electron Microscope (SEM), X-Ray Diffraction (XRD), Energy Dispersive Spectroscopy (EDX), and the concentration of metal ions before and after ion exchange was measured by Inductively Coupled Plasma Optical Emission Spectrometer (ICP-OES). The extraction amount of K+ is 86 mg/kg, and the extraction amount of Na+ is 54.9 mg/kg. Therefore, K-PHI zeolite membrane has the potential to remove potassium and sodium ions from the solution and can be used in acidic lignin wastewater.

• 펄프종이기술
• /
• 제41권2호
• /
• pp.64-69
• /
• 2009

Cultural heritages represent the histories and intellectual level of a country. The Annals of Joseon Dynasty are regarded as the most valuable resources containing the record of Korean history. In some periods, wax-treated paper was used as the material of the Annals of Joseon Dynasty. Many previous studies have focused on the development of paper used as the material of the Annals of Joseon Dynasty, but the manufacture method of wax-treated volumes and the degradation mechanism of wax have been not fully understood yet. The purposes of the present study are to produce various kinds of wax-treated paper using by different coating methods and to analyse the morphological properties of wax-treated paper. The analysis of SEM demonstrates that beeswax treated paper made by brushing method produces flatter surface and more excellent penetration. Wax layer is produced on the cross section of beeswax treated paper as the increase of coating amount.

• Bulletin of the Korean Chemical Society
• /
• 제35권5호
• /
• pp.1333-1336
• /
• 2014

Expanded polytetrafluoroethylene (ePTFE) grafts have been used as vascular access for many patients suffering from end stage renal disease. However, the vascular graft can cause significant clinical problems such as stenosis or thrombosis. For this reason, many studies have been performed to make drug eluting graft, but initial burst is major problem in almost drug eluting systems. Therefore we used biodegradable polymer to reduce initial burst and make sustained drug delivery. The ePTFE grafts were dipped into a paclitaxel-dissolved solution and then PLGA-dissolved solution was passed through the lumen of ePTFE. We analyzed whether the dose of paclitaxel is enough and the loading amount of PLGA on ePTFE graft increases according to the coating solution's concentration. Scanning electron microscope (SEM) images of various concentration of PLGA showed that the porous surface of graft was more packed with PLGA by tetrahydrofuran solution dissolved PLGA. In addition, in vitro release profiles of Ptx-PLGA graft demonstrated that early burst was gradually decreased as increasing the concentration of PLGA. These results suggest that PLGA coating of Ptx loaded graft can retard drug release, it is useful tool to control drug release of medical devices.

• 한국추진공학회지
• /
• 제18권2호
• /
• pp.52-59
• /
• 2014

액체로켓 엔진 연소기에 대한 연소/냉각 성능 통합 해석 및 연소 시험 결과와의 비교를 통하여 내열 세라믹 열차폐 코팅 조건에 따른 냉각 성능 변화 경향을 고찰하였다. 연소기 헤드부 근처에서의 막냉각 적용 여부 및 막냉각 유량에 따른 냉각수 온도 및 열차폐 코팅 표면 온도 변화 경향 또한 확인하였다. 본 연구를 통하여 재생냉각 방식 로켓 엔진 연소기의 냉각 기구 설계 시 고려 사항이 검토되었으며, 향후 지속적인 해석 도구 검증이 수행될 예정이다.

• KSTLE International Journal
• /
• 제4권2호
• /
• pp.56-59
• /
• 2003

Boron carbide thin coatings were deposited on silicon wafers by DC magnetron sputtering using a ${B}_4$C target with Ar as processing gas. Various amounts of methane gas (${CH}_4$) were added in the deposition process to better understand their influence on tribological properties of the coatings. Reciprocating wear tests employing an oscillating friction wear tester were performed to investigate the tribological behaviors of the coatings in ambient environment. The chemical characteristics of the coatings and worn surfaces were studied using X-ray Photoelectron Spectroscopy (XPS) and Auger Electron Spectroscopy (AES). It revealed that ${CH}_4$addition to Ar processing gas strongly affected the tribologcal properties of sputtered boron carbide coating. The coefficient of friction was reduced approximately from 0.4 to 0.1, and wear resistance was improved considerably by increasing the ratio of ${CH}_4$gas component from 0 to 1.2 vol %. By adding a sufficient amount of ${CH}_4$(1.2 %) in the deposition process, the boron carbide coating exhibited lowest friction and highest wear resistance.