• Resources Recycling
• /
• v.14 no.4 s.66
• /
• pp.3-9
• /
• 2005

In this study, the utilization possibility of coal-preparation refuse emitted from Hwasun coal mine in Korea as a raw material for ceramic body was investigated. The firing shrinkage ratio of ceramic specimen made from the coal-preparation refuse was reduced with increasing the addition amounts of that, while the compressive strength was slightly decreased. The weight of ceramic body was also reduced because carbon contained in the coal-preparation refuse was burn by fring. The water adsorption ratio of the ceramic specimen was under 10 wt%, and the compressive strength of that was over 21 MPa at over $1,150^{\circ}C$ for 2 hr. Therefore, it was possible to make the 1st garde clay brick of KS L 4201 from the coal-preparation refuse.

• Journal of the Korean Society of Combustion
• /
• v.12 no.4
• /
• pp.47-56
• /
• 2007

Utilization of sewage sludge for industrial fuel should be considered in appropriate calory with low emission of environmental pollutants and the amount of sewage sludge for continuously long-time operation. For the low grade fuel(<4,000kcal/kg), one of proper processes is that coal and oil are added into sewage sludge to remove impurities and increase calory(>7,000kcal/kg) and the amount of fuel having sewage sludge. Recently, 2-step agglomeration has been attempted by secondarily agglomerate sewage sludge onto the primary nuclei formed by agglomeration of coal and oil. Furthermore, sawdust and waste oil can substitute about 1/3 each for coal and mineral oil consumed in this process, which will lead to securing alternative energy resources from environmental pollutants as well as cost reduction.

• Korean Chemical Engineering Research
• /
• v.46 no.3
• /
• pp.443-450
• /
• 2008

Efficient use of low rank coals (LRC) have been investigated as a method to cope with recent high oil price. Among the coals used in industry, lignite and sub-bituminous coals are belong to the LRC, and have abundant deposit and are distributed worldwide, but high moisture contents and self ignition properties inhibits their utilization. In this paper, chemical coal cleaning to produce ash-free coal from LRC has been investigated. Two technologies, that is, UCC(Ultra Clean Coal) process removing ash from coal and Hyper Coal process extracting combustibles from coal were compared with. UCC process has merits of simple and reliable when it compared with Hyper Coal process, but the remaining ash contents werehigher than Hyper Coal. Hyper Coal has ash contents under the 200ppm when raw coal is treated with appropriate solvent and ion exchange materials to remove alkali materials in extracted solution. The ash-free coal which is similar grade with oil can be used as alternate oil in the industry, and also used as a high grade fuel for IGCC, IGFC and other advanced combustion technology.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1998.10a
• /
• pp.233-238
• /
• 1998

For substitution for crushed sand, high strength aggregate for cement and concrete using coal ash as a main material was prepared and then compared its physical properties with those of crushed sand. Effect of mix proportion change of raw materials on the property of aggregate was checked. On the basis of these experimental results we are going to comprehend the reutilization of coal ash and utilize a basic data for judging possibility the substitution of crushed sand.

• Korean Journal of Materials Research
• /
• v.23 no.5
• /
• pp.276-280
• /
• 2013

Coal tar is the primary feedstock of premium graphitizable carbon precursor. Coal tars are residues formed as byproducts of thermal treatments of coal. Coal tar pitches were prepared through two different heat treatment schedules and their properties were characterized. One was prepared with argon and oxidation treatment with oxygen; the other was prepared with oxygen treatment at low temperature and then argon treatment at high temperature; both used coal tar to prepare coal tar pitches. To modulate the properties, different heat treatment temperatures ($300{\sim}400^{\circ}C$) were used for the coal tar pitches. The prepared coal tar pitches were investigated to determine several properties, such as softening point, C/H ratio, coke yield, and aromaticity index. The coal tar pitches were subject to considerable changes in chemical composition that arose due to polymerization after heat treatment. Coal tar pitch showed considerable increases in softening point, C/H ratio, coke yields, and aromaticity index compared to those characteristics for coal tar. The contents of gamma resin, which consists of low molecular weight compounds in the pitches and is insoluble in toluene, showed that the degree of polymerization in the pitches was proportional to C/H ratio. Using an oxidizing atmosphere like air to prepare the pitches from coal tar was an effective way to increase the aromaticity index at relatively low temperature.

• Proceedings of the Korean Institute of Resources Recycling Conference
• /
• 2002.05a
• /
• pp.135-136
• /
• 2002

• Korean Chemical Engineering Research
• /
• v.48 no.2
• /
• pp.129-139
• /
• 2010

Coal gasification process, which had developed originally to convert coal from hydrogen and carbon monoxide, has used and developed in many countries because of environmental advantages such as carbon dioxide storage, decrease of pollutants and so on. Generally entrained-flow gasification process using pulverized coal under $75{\mu}m$ is used in Integrated Gas Combined Cycle(IGCC) because of easy scale up and high efficiency of energy conversion. Especially entrained-flow gasifers with coal water slurry have been used in many applications due to its fully developed technologies. In this paper, several technologies for coal-water slurry gasification that involves slurry preparation, burner, gasifier, slag melting and numerical simulation for plant design and operation were investigated. Entrained-flow gasification with coal water slurry can be used for synfuel production, SNG, chemicals as well as IGCC. To develop hybrid gasification process and use different types of coal, it is necessary to develop new technologies that will increase efficiency of the process.

• Journal of Hydrogen and New Energy
• /
• v.22 no.2
• /
• pp.249-256
• /
• 2011

In this study, the Ni-based catalysts for the production of synthetic natural gas were prepared by various preparation methods such as the co-precipitation, precipitation, impregnation and physical mixing methods. The ranges of the reaction conditions were the temperatures of 250~$350^{\circ}C$, $H_2$/CO mole ratio of 3.0, the pressures of 1 atm and the space velocity of 20000 $ml/g_{-cat{\cdot}}{\cdot}h$. It was found that the catalyst prepared by precipitation method had higher CO conversion than the catalyst prepared by co-precipitation method. While the catalyst prepared by precipitation method had the formation of NiO structure, the catalyst prepared by co-precipitation method had the formation of $NiAl_2O_4$ structure. It was confirmed that Ni-based catalyst prepared by the physical mixing method had the lowest CO conversion because it was deactivated by the production of $Ni_3C$ during the methanation. As a result, it was shown clearly that Ni-based catalysts prepared by impregnation method expressed the highest catalytic activity in CO methanation.

• Journal of Environmental Health Sciences
• /
• v.36 no.2
• /
• pp.136-140
• /
• 2010

The integrated gasification combined cycle (IGCC) is one of the most promising proposed processes for advanced electric power generation that is likely to replace conventional coal combustion. This emerging technology will not only improve considerably the thermal efficiency but also reduce or eliminate the environmentally adverse effects normally associated with coal combustion. The IGCC process gasifies coal under reducing conditions with essentially all the sulfur existing in the form of hydrogen sulfide ($H_2S$) in the product fuel gas. The need to remove $H_2S$ from coal derived fuel gases is a significant concern which stems from stringent government regulations and also, from a technical point of view and a need to protect turbines from corrosion. The waste seashells were used for the removal of hydrogen sulfide from a hot gas stream. The sulphidation of waste seashells with $H_2S$ was studied in a thermogravimetric analyzer at temperature between $600^{\circ}C$ and $800^{\circ}C$. The desulfurization performance of the waste seashell sorbents was experimentally tested in a fixed bed reactor system. Sulfidation experiments performed under reaction conditions similar to those at the exit of a coal gasifier showed that preparation procedure and technique, the type and the amount of seashell, and the size of the seashell affects the $H_2S$ removal capacity of the sorbents. The pore structure of fresh and sulfided seashell sorbents was analyzed using mercury porosimetry, nitrogen adsorption, and scanning electronmicroscopy.

• Proceedings of the KAIS Fall Conference
• /
• 2009.12a
• /
• pp.259-262
• /
• 2009

본 연구에서는 석탄광산 선탄장설비와 국소배기시스템의 일부를 모형화하여 포집특성과 유동특성실험을 수행하였으며 동일조건에서 수치해석을 수행하여 그 결과를 비교 검토하였다. case 5가 46.35%의 가장 높은 포집효율을 보였으며 실험의 3가지 변수 중 고무 커튼의 사용유무가 국소배기시스템의 포집효율에 가장 큰 영향을 미치는 것으로 판단된다. 또한 case 1, 5, 6에 대해 포집된 입자크기 확인 결과, 포집성능이 우수한 case 5가 입경 $20{\mu}m$ 초과 입자들이 약 55%로 가장 많이 포집된 것을 알 수 있었다. 따라서 제어거리는 0.5m 이상이 적절한 것으로 판단된다.