• 한국환경과학회지
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• 제26권11호
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• pp.1267-1274
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• 2017

A Controlled Low-Strength Materials (CLSM) is suitable for mine backfilling because it does not require compaction owing to it high fluidity and can be installed quickly. Therefore, a CLSM utilizing $CO_2$-solidified Circulating Fluidzed Bed Combustion (CFBC) coal ash was developed and it's properties were investigated, since. $CO_2$-solidification of CFBC coal ash can inhibit exudation of heavy metals. The chemical composition and specific surface area of Pulverized coal Combustion fly ash and CFBC fly ash were analyzed. The water ratio, compressive strength and length change ratio of CLSM were confirmed. The water ratios differed with the specific surface area of the CLSM. It was confirmed that the porosity of CLSM affected its compressive strength and length change ratio.

• KEPCO Journal on Electric Power and Energy
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• 제3권1호
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• pp.29-34
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• 2017

Leaching kinetics for extracting yttrium from the coal fly ash was investigated in the presence of sulfuric acid during extraction. The leaching kinetics of yttrium were conducted at reactant densities of 5~1,000 g coal fly ash per L of $1.0{\sim}10.0N\;H_2SO_4$, agitation speed of 250 rpm and temperature ranging from 30 to $90^{\circ}C$. As a result, the leaching kinetic model was determined in a two-step model based on the shrinking core model with spherical particles. The first step was proceeded by chemical reaction at ash surface, and the second step was proceeded by ash layer diffusion because the leaching conversion of yttrium by the first chemical reaction increases with increased the time irrelevant to the temperature whereas it increases with increased the leaching temperature. The activation energy of the first chemical leaching step was determined to be $1.163kJmol^{-1}$. After the first chemical reaction, the activation energy of ash layer diffusion leaching was derived to be $41.540kJmol^{-1}$. The optimum conditions for leaching the yttrium metal of 60 % were found to be the slurry density of 250 g fly ash per L of $H_2SO_4$, solvent concentration of $2.0N\;H_2SO_4$, second step leaching of temperatures of $30^{\circ}C$ for 3 hours and then $90^{\circ}C$ for 3 hours at agitation rate of 250 rpm.

• 한국지반공학회지:지반
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• 제14권1호
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• pp.81-92
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• 1998

화력발전소에서 대량으로 부산 되어 폐기 처리되고 있는 석탄회 폐기물로 조성된 지반을 안정 처리하여 사용하거나 또는 이러한 석탄회를 건설공사의 직접적인 재료로 활용하게 되면 결국 폐자원을 산업자원화 함으로서 건설자재 난을 해소할 수 있게 된다. 본 연구에서는 석탄회를 성토재 및 매립재로서 대량 활용할 경우와 지반변형해석에 필요한 적용 모델과 그 적용성을 중심으로 검토하였다. 그 중 Cam-clay model은 흙의 다양한 응력경로에 대해 배수와 비배수 조건에서 재하하는 동 안 변위와 공극수압을 나타낼 수 있는 완전한 구성식을 제공하고, 필요로 하는 토질정수가 극소수이고 모든 것을 실내실험을 통해 측정할 수 있는 장점이 있다. 토질기본시험, 등방압밀 및 비배수 삼축압축시험 등을 통하여 Camflay mode숙 제반 parameter를 구하였고, 수치해석을 수행하여 시험 결과와 비교하였다. 시험 결과와 수치 해석결과에서 각각 구한 parameter의 오차는 매우 근소 한 것으로 나타났다. 시험을 통해 결정한 비회와 저회 5 : 5 적정혼합회의 Parameter들은 인공으로 조성된 석탄회 매립지반의 변형해석에서 Cam-clay model을 이용하는 데에 기초자료로서 활용이 가능할 것으로 판단된다.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2000년도 학술발표회 발표논문집
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• pp.458-465
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• 2000

Although Fly ash possess viable engineering properties, an overwhelming majority of the fly ash from coal combustion is still placed in storage or disposal sites. Similarly, sludges generated from various water treatment operations are predominantly subject to the fate of land disposal. To prepare sludges for land disposal typically requires time consuming dewatering schemes, which can become extremely difficult to execute dependent upon the composition of the sludge and its affinity for water. This test was undertaken to reuse of fly ash and sludge with mix. In this paper includes of geotechnical properties of fly ash and fly ash-sludge mixture and results of compaction test, unconfined test, falling head test and CBR test and it was analyzed the effect on mixing fly ash with sludge.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
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• pp.373-376
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• 2005

The discharge of fly ash that is produced by coal-fired electric power plants is rapidly increasing in Korea. The utilization of fly ash in the raw materials would contribute to the elimination of an environmental problem and to the development of new high-performance materials. Fly ash consists of a glass phase. As it is produced from high temperature, it is a chemically stable material. Fly ash mostly consists of $SiO_{2}$ and $Al_{2}O_{3}$, and it assumes the form of an oxide in the inside of fly ash. Because this reaction has not broken out by itself, it is need to supply it with additional $OH^{-}$ through alkali activators. We used alkali activators for supplying it with additional $OH^{-}$. This paper concentrated on the strength development according to the kind of chemical activators, the curing temperature, the heat curing time.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
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• pp.1051-1060
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• 2008

The use of the coal ash for surcharge material, in a view of the environmental aspect, can decrease amount of the reclamation through recycling waste materials as well as prevent a destruction of the ecosystem attributed to sand picking. In addition, it can reduce both unit cost of material and construction expenses. In this study, new construction material as alternative surcharge material using coal ash, which is by-product from thermoelectric power plant, were developed. Mixing ratios of fly ash and bottom ash derived from the coal ash in Samchunpo thermoelectric power plants were determined. Furthermore, mixing conditions depending on the ratios of the cement and gypsum used for chemical additive were determined too. Uniaxial compression strength tests were conducted at different mixing conditions and Design graph of optimum mixing ratio at each required strength for economic efficiency is indicated in this paper.

• Advances in concrete construction
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• 제5권3호
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• pp.289-301
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• 2017

The synergistic interactions of supplementary cementitious materials (SCMs) with ordinary portland cement (OPC) in multi-blended systems could enhance the mechanical and durability properties of concrete and increase the amount of cement that can be replaced. In this study, the characteristics of the hydration products as well as paste microstructure of blended cement containing 20% coal fly ash, 10% rice hull ash and 10% sugar mill lime sludge in quaternary blended system was investigated. Portlandite content, hydration products, compressive strength, pore size distribution and microstructural architecture of hydrated blended cement pastes were examined. The quaternary blended cement paste showed lower compressive strength, reduced amount of Portlandite phases, and higher porosity compared to plain hardened cement paste. The interaction of SCMs with OPC influenced the hydration products, resulting to the formation of ettringite and monocarboaluminate phases. The blended cement paste also showed extensive calcium silicate hydrates and calcium aluminate silicate hydrates but unrefined compared to plain cement paste. In overall, the expected synergistic reaction was significantly hindered due to the low quality of supplementary cementitious materials used. Hence, pre-treatments of SCMs must be considered to enhance their reactivity as good quality SCMs can become limited in the future.

• 한국환경과학회지
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• 제20권12호
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• pp.1607-1615
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• 2011

The adsorption performance of cupper and zinc ions($Cu^{2+}$ and $Zn^{2+}$) in aqueous solution was investigated by an adsorption process on reagent grade Na-A zeolite(Z-WK) and Na-A zeolite (Z-C1) prepared from coal fly ash. Z-C1 was synthesized by a fusion method with coal fly ash from a thermal power plant. Batch adsorption experiment with Z-C1 was employed to study the kinetics and equilibrium parameters such as initial metal ions concentration and adsorption time of the solution on the adsorption process. Adsorption rate of metal ions occurred rapidly and adsorption equilibrium reached at less than 120 minutes. The kinetics data of $Cu^{2+}$ and $Zn^{2+}$ ions were well fitted by a pseudo-second-order kinetics model more than a pseudo-first-order kinetics model. The equilibrium data were well fitted by a Langmuir model and this result showed $Cu^{2+}$ and $Zn^{2+}$ adsorption on Z-C1 would be occupied by a monolayer adsorption. The maximum adsorption capacity($q_{max}$) by the Langmuir model was determined as $Cu^{2+}$ 99.8 mg/g and $Zn^{2+}$ 108.3 mg/g, respectively. It appeared that the synthetic zeolite, Z-C1, has potential application as absorbents in metal ion recovery and mining wastewater.

• 한국해양공학회지
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• 제14권1호
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• pp.74-79
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• 2000

The purpose of this paper is to recycle coal ash as structural backfill materials from electric power plants. Two million tons of coal ash are produced annually. The laboratory test was executed for the basic compatibility as substitution for structural backfill materials and the optimal mixture ratio(fly ash : bottom ash) was decided. In addition the model test was performed using medium scale earth pressure model with small size earth pressure cells model box data logger and some other apparatuses. Mixed coal ash and excellent backfill materials(coheisonless soil SW) were compared in the view of lateral earth pressure variation depending on wall displacement. The reduction of earth pressure when coal ash was used as a bockfill material was monitored comparing to that of cohesionless soil. the cost and environmental pollutants by treating coal ash can be reduced through developing the recycling technology.

• 자원리싸이클링
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• 제10권3호
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• pp.14-22
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• 2001

발전소에서 발생되는 석탄회의 재활용을 위해 석탄회 내의 미연탄소를 제거하기 위한 장치를 개발하여 실험을 수행하였다. 석탄회 중 조림 석탄회가 미연탄소 함량이 높으며 또한 마찰에 의해 정전기적으로 석탄회 내의 미연탄소분은 (+)극성을, 순수 회분은 (-)극성을 띠게 된다는 사실에 근거하여 입도 분급 및 정전기적 분리가 동시에 일어날 수 있는 싸이클론 정전분리장치를 설계하였다. 그리고 분급입도를 조절하기 위하여 싸이클론 내에 vane을 설치하였으며 전극의 형태에 따른 영향을 알아보기 위해 막대형 전극과 Ul(쳔 전극을 설계하여 실험을 수행하였다. 그 결과 막대전극의 경우 미립분의 회수율이 5-10%증가하였으며 grid전극의 경우 약 15%까지 증가하였다. 그러나 미연탄소 함량은 조립분의 경우 전극 설치 전보다 크게 증가하였으나 미립분의 경우 그다지 변하지 않았다. 따라서 본 시료의 경우 전기장을 형성시킴으로써 같은 미연탄소 함유량을 갖는 정제석탄회의 회수율은 크게 증대시킬 수 있음을 확인하였다.