• Title/Summary/Keyword: co-firing

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Evaluation of Magnesia Cement Using MgCO3 and Serpentine (MgCO3와 사문석을 사용한 마그네시아 시멘트의 특성평가)

  • Lee, Jong-Kyu;Soh, Jung-Sub;Chu, Yong-Sik;Song, Hun;Park, Ji-Sun
    • Korean Journal of Materials Research
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    • v.22 no.11
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    • pp.598-603
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    • 2012
  • MgO based cement for the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. Furthermore, adding reactive MgO to Portland-pozzolan cement can improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, the basic research for magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as starting materials was carried out. In order to increase the hydration activity, $MgCO_3$ and serpentinite were fired at a temperature higher than $600^{\circ}C$. In the case of $MgCO_3$ as starting material, hydration activity was highest at $700^{\circ}C$ firing temperature; this $MgCO_3$ was completely transformed to MgO after firing. After the hydration reaction with water, MgO was totally transformed to $Mg(OH)_2$ as hydration product. In the case of using only $MgCO_3$, compressive strength was 35 $kgf/cm^2$ after 28 days. The addition of silica fume and $Mg(OH)_2$ led to an enhancements of the compressive strength to 55 $kgf/cm^2$ and 50 $kgf/cm^2$, respectively. Serpentine led to an up to 20% increase in the compressive strength; however, addition of this material beyond 20% led to a decrease of the compressive strength. When we added $MgCl_2$, the compressive strength tends to increase.

Experimental Investigation into the Combustion Characteristics on the Co-firing of Biomass with Coal as a Function of Particle Size and Blending Ratio (바이오매스(우드펠릿) 혼소율 및 입자크기에 따른 연소 특성에 관한 연구)

  • Sh, Lkhagvadorj;Kim, Sang-In;Lim, Ho;Lee, Byoung-Hwa;Kim, Seung-Mo;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.1
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    • pp.31-37
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    • 2016
  • Co-firing of biomass with coal is a promising combustion technology in a coal-fired power plant. However, it still requires verifications to apply co-firing in an actual boiler. In this study, data from the Thermogravimetric analyzer(TGA) and Drop tube furnace(DTF) were used to obtain the combustion characteristics of biomass when co-firing with coal. The combustion characteristics were verified using experimental results including reactivity from the TGA and Unburned carbon(UBC) data from the DTF. The experiment also analyzed with the variation of the biomass blending ratio and biomass particle size. It was determined that increasing the biomass blending ratio resulted in incomplete chemical reactions due to insufficient oxygen levels because of the rapid initial combustion characteristics of the biomass. Thus, the optimum blending condition of the biomass based on the results of this study was found to be 5 while oxygen enrichment reduced the increase of UBC that occurred during combustion of blended biomass and coal.

Effect of the Variation in Alkaline-Earth Oxides (RO) Content on Electrical Properties of $RO-Al_2O_3-SiO_2$ Porcelain System (알칼리 토속 산화물이 물라이트 자기의 전기적 특성에 미치는 영향)

  • 주기태;장성도
    • Journal of the Korean Ceramic Society
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    • v.18 no.3
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    • pp.171-181
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    • 1981
  • Alkaline-earth porcelains have been prepared from mixture of kaolin, quartz, and synthetic calcines obtained by calcining a mixture of kaolin and more than two different kinds of alkaline-earth carbonates. They were magnesium, calcium and barium carbonates which are inexpensive and readily available. The vitrification behavior of the batch mixes was investigated in the firing range of 1240$^{\circ}$to 1380$^{\circ}$, in relation to the body compositions. It appeared that the density and the firing temperature depended largely on the content of alkaline-earth oxides in the body. These porcelains posses excellant dielectric properties, and are especially valuable as bases for deposited carbon resistors for which they were developed. An illustrative composition is 50% Dong Hwa kaolin, 22.4% Chang Shin quartz, 27.6% calcine. The composition of the calcine is 70% Dong Hwa kaolin, 10.7% BaCO3, 13.5% CaCO3, 5.8% MgCO3. The specific resistance of this body is $1.2{\times}10^{15}$ ohm-cm at 5$0^{\circ}C$, $2.5{\times}10^{14}$ ohm-cm 10$0^{\circ}C$, $2.5{\times}10^{13}$ ohm-cm at 15$0^{\circ}C$, $1.8{\times}10^{12}$ohm-cm at 20$0^{\circ}C$.

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Experimental Study of Co-firing and Emission Characteristics Fueled by Sewage Sludge and Wood Pellet in Bubbling Fluidized Bed (기포 유동층 반응기를 이용한 하수슬러지 및 우드펠렛 혼소에 관한 연소 특성 분석 및 비교)

  • Lee, Youngjae;Kim, Jongmin;Kim, Donghee;Lee, Yongwoon
    • Clean Technology
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    • v.23 no.1
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    • pp.80-89
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    • 2017
  • The bubbling fluidized bed (BFB) reactor with a diameter of 0.1 m and a height of 1.2 m was used for experimental study of co-firing and emission characteristics fueled by sewage sludge (SS) and wood pellet (WP). The facility consists of a fluidized bed reactor, feeding system, cyclone, condenser and gas analyzer, The mean particle diameter and minimum fluidization velocity are $460{\mu}m$ and $0.21ms^{-1}$ respectively. SS produced from Korea and WP from Canada were examined. The various mixing ratios of WP were 20, 50, and 80% based on HHV. The equivalence ratio of 1.65, reactor temperature of $800^{\circ}C$, air flow rate of $100Lmin^{-1}$, and fluidization number of 4 were fixed in the BFB experiment. In TGA, the range of combustion temperature of SS was wider than that of WP. It represents that the combustibility of WP is higher than that of SS. The BFB reactor temperature was maintained between 800 and $900^{\circ}C$. CO emission of SS was high because of lower combustibility. $NO_X$ and $SO_X$ formation of SS were higher than that of WP since high nitrogen and sulfur contents of SS. CO, $NO_X$, and $SO_X$ formation were suppressed as the mixing ratio of WP was increased. The slagging and fouling tendencies show high in all test conditions.

The effect of powder characteristics on the behavior of Co-firing of ferrite and varistor (Ferrite/varistor의 동시소성 거동에 대한 분체특성의 영향)

  • Han, Ik-Hyun;Lee, Yong-Hyun;Myoung, Seong-Jae;Chun, Myoung-Pyo;Cho, Jeong-Ho;Kim, Byung-Ik;Choi, Duck-Kyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.2
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    • pp.63-68
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    • 2007
  • A number of process problems should be solved in the multi-layered ceramic devices such as EMI filter. In particular, it is essential to control the sintering shrinkage in co-firing of different materials for obtaining defect-free samples such as crack, camber, and delamination which usually occur near the surface and interface. We studied the effect of the powder properties of ferrite on the co-firing behavior of green ceramic layers composed of ferrite and varistor. Three kind of ferrite powder samples as a function of milling time (24, 48, and 72 hr) were prepared. Varistor and ferrite ceramic green sheet were made by means of doctor blade process using slurry (ceramic powder and binder solution). Here, slurry was prepared by mixing 55 wt% powder with 45wt% binder solution. Varistor and ferrite green sheets were laminated at $80 kg/cm^2$, and co-fired at $900^{\circ}C$ and $1000^{\circ}C$ for 3 hr. We obtained the camber-free and co-fired ferrite/varistor layer structure by controlling the milling time and sintering temperature.