• 제목/요약/키워드: co-condensation

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화학기상응축공정(Chemical Vapor Condensation)으로 제조된 Co 나노분말의 미세구조 및 자기적 성질에 미치는 운송기체의 영향 (Effect of Carrier Gas on the Microstructure and Magnetic Properties of Co Nanoparticles Synthesized by Chemical Vapor Condensation)

  • 최철진;;유지훈;김진천;김병기
    • 한국분말재료학회지
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    • 제11권1호
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    • pp.16-21
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    • 2004
  • The nano-sized Co particles were successfully synthesized by chemical vapor condensation (CVC) process using the precursor of cobalt carbonyl ($Co_2(CO)_8$). The influence of carrier gases on the microstructure and magnetic properties of nanoparticles was investigated by means of XRD, TEM, XPS and VSM. The Co nano-particles with different phases and shapes were synthesized with a change of carrier gas : long string morphologies with coexistence of fcc and hcp structure in Ar carrier gas condition; finer Co core in a mass of cobalt oxide with only fcc structure in He; rod type cobalt oxide phase in Ar+6vol%$O_2$. The saturation magnetization and coercivity was lower in Co nanoparticles synthesized in He carrier gas, due to their finer size.

Semi-Rig, Pontoon 구역 표면 결로 예방 설계 (Semi-Rig, Anti-condensation design on steel surface in pontoon area)

  • 서동재;박상언;노정환;심학무
    • 대한조선학회 특별논문집
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    • 대한조선학회 2017년도 특별논문집
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    • pp.105-108
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    • 2017
  • Condensation is one of the common issues which we can easily see in everyday life. For example, the surface of glasses with cold water is easily moisturized. This wet surface gives us uncomfortable feeling and is sometimes dangerous because it is slippery. As the safety on working space is one of the most important issue on offshore project, condensation is also important matter to take care of with precaution. Since the bottom of vessel or offshore facility is submersed in the water, the risk of having condensate on the steel surface is getting higher because sea water temperature is normally lower than ambient temperature. And if there is any electric equipment or person working in that space, condensation is normally not allowed. The pontoon of semi-submersible drilling rig is such a space which is submersed, with electric and mechanical equipments and person working periodically. To prevent condensation in pontoon, study was conducted by checking several cases.

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실내 빙상장 및 부대시설에 데시칸트 제습기 적용 (Application of Desiccant Dehumidifier on Ice-rink and Subsidiary Facilities)

  • 박승태;방영석;최세영
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2005년도 동계학술발표대회 논문집
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    • pp.533-538
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    • 2005
  • The number of domestic ice-rink is little by little increasing recently. Therefore, the demand for air-conditioning system to adjust adequately the indoor condition of ice-rink is constantly increasing. But, if air-conditioning system for ice-rink isn't designed properly, the problems such as fogging, ice surface condensation, structural deterioration, odors, generation of dew condensation on the surface of a wall occur. The solutions for these problems are to lower the relative humidify of indoor. The objectives of this paper is to apply of desiccant dehumidifier on ice-rink, solve these problems.

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수종(數種) Composite Resin의 색소침투(色素浸透)에 관(關)한 실험적(實驗的) 연구(硏究) (AN EXPERIMENTAL STUDY ON PENETRATION OF DYE IN COMPOSITE RESIN)

  • 이명종
    • Restorative Dentistry and Endodontics
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    • 제12권1호
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    • pp.155-163
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    • 1986
  • The purpose of this study was to measure penetration of dye stuff (2% Methylene blue, 2% Hematoxylin, 2% crystal violet and 2% safranin-O) on unfilled resin (Lang Dental MFG Co.) Hipol (Boopyung Dental Chemical Co. Macrocomposite resin) Durafill (Kulzer, Co. Microfilled Composite resin) and Heliosit (Vivadent Co. Microfilled Composite resin) The unfilled resin with dough stage was inserted into plastic tuble (5mm in diameter and 4mm in height) with condensation force of 1000 gr, 2000 gr and without condensation force. Hipol mixed on the mixed pad was inserted into the plastic tube by the same method as the unfilled resin. The microfilled resins which were Durafill and Heliosit were polymerized for 60 seconds with the visible light on each surface of the plastic tube which was upper and lower, under condensation force of 1000 gr, 2000 gr and without condensation force. All specimens were stored in the air for 24 hours, then specimens were immersed in the various kind of dye solution for different period of time (1 hour and 24 hours). These dye-treated specimens were polished horizontally until removing 0.5mm of each surface on the emery paper (#1000), and the dye penetration in the polished surface was measured under the digital microscope (Japan Fosuh). Following results were obtained 1. The penetration of dyes was the most excessive in Durafill and was not influenced on the condensation force and the period of immersion time. 2. All dyes were penetrated into Hipol, and Crystal violet was penetrated most excessively in all dyes. 3. The penetration of dye in all resins was not influenced by the period of immersion time and condensation force. 4. There was no evidence of dye penetration in unfilled resin.

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기상응축법으로 제조한 나노 WC및 WC-Co분말의 후속 열처리에 의한 상 및 협상 변화 (Change of Particle Morphology and Ingredient Phase of WC and WC-Co Nanopowders Fabricated by Chemical Vapor Condensation during Subsequent Heat-Treatment)

  • 김진천;하국현;김병기
    • 한국분말재료학회지
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    • 제11권2호
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    • pp.124-129
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    • 2004
  • Nanosized WC and WC-Co powders were synthesised by chemical vapor condensation(CVC) process using the pyrolysis of tungsten hexacarbonyl(W(CO)$_6$) and cobalt octacarbonyl(Co$_2$(CO)$_8$). The microstructural changes and phase evolution of the CVC powders during post heat-treatment were studied using the XRD, FE-SEM, TEM, and ICP-MS. CVC powders were consisted of the loosely agglomerated sub-stoichimetric WC$_{1-x}$ and the long-chain Co nanopowders. The sub-stochiometric CVC WC and WC-Co powders were carburized using the mixture gas of CH$_4$-H$_2$ in the temperature range of 730-85$0^{\circ}C$. Carbon content of CVC powder controlled by the gas phase carburization at 85$0^{\circ}C$ was well matched with the theoretical carbon sioichiometry of WC, 6.13 wt%. During the gas phase carburization, the particle size of WC increased from 20 nm to 40 nm and the long chain structure of Co powders disappeared.

알루미늄 버터플라이밸브의 표면 결로방지에 관한 연구 (A Study of Anti-Condensation on the Surface for Aluminum Butterfly Valves)

  • 곽경민;이중형;조경철;이은하
    • 한국기계가공학회지
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    • 제20권4호
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    • pp.73-79
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    • 2021
  • The objective of this study is to prevent or decrease condensation on the surface of aluminum butterfly valves used in high humidity air conditions. We proposed a new valve with an anti-condensation device, a heat resistance medium, instead of a conventional valve. We, then, compared the surface temperature distribution between the proposed and conventional valves using experimental and analytical methods. The size of the evaluated valve is 100A and fluid conditions are 35℃/RH 75% in the air outside the valve and 5℃ in the cooling water inside the valve. The experimental results show that the surface temperature of the proposed valve is 23~42% higher than that of a conventional valve, thereby exhibiting an anti-condensation effect. As a result, we observed the complete prevention of condensation on a gear box mounted to the proposed valve, showing surface temperature distribution above the dew point temperature of air. The analytical results are in agreement with the trends in experimental results.

도재의 재료와 축성방법에 따른 표면거칠기의 비교 (Comparison of Surface Roughness according to Porcelain Materials and Condensation)

  • 이청희
    • 구강회복응용과학지
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    • 제18권3호
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    • pp.179-184
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    • 2002
  • To compare surface roughness in various porcelains and know effects of condensation, We used Ceramco dentin porcelain, Creation dentin porcelain, Creation margin porcelain, Vintage margin porcelain, Vintage dentin porcelain, and Vita dentin porcelain, and built up the powders with condensation or not, and then fired according to the instructions with porcelain furnace( Dekema, Germany ). We polished the samples step by step using the porcelain adjustment kit( Shofu Inc., Japan ), and then measured, compared and analysed Ra, Rz, and Rmax with Surftest SV-400( Mitutoyo Co., Japan ). 1. With condensation, roughness is significantly increased in Ceramco dentin porcelain (p<0.05) and decreased in Vita dentin porcelain(p<0.05). 2. In Ra, Vita dentin porcelain is significantly the roughest and Creation margin porcelain is rougher than others in no condensation, (p<0.05), and there is no difference under condensation. 3. In Rz, Vita dentin porcelain is significantly the roughest and Creation margin porcelain is rougher than others in no condensation, and Creation margin porcelain is significantly the roughest and Creation dentin porcelain is rougher than others under condensation(p<0.05). 4. In Rmax, Vintage dentin porcelain is significantly the roughest and Creation margin porcelain is rougher than others in no condensation, and Creation margin porcelain is significantly the roughest than others under condensation(p<0.05).

Partial Purification and Characterization of ${\beta}$-Ketothiolase from Alcaligenes sp. SH-69

  • Oh, Deok-Hwan;Chung, Chung-Wook;Kim, Jeong-Yoon;Rhee, Young-Ha
    • Journal of Microbiology
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    • 제35권4호
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    • pp.360-364
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    • 1997
  • A ${\beta}$-ketothiolase was purified 180-fold from the cell extracts of Alcaligenes sp. SH-69 by a series of chromatography on DEAE-Dephadex A-50, Sephacryl S-200, and hydrozyapatitie columns, The optimum pH values of the partially purified enzyme were 7.5 for condensation reaction and 8.3 for thiolysis reaction were estimated to be 0.12mM and $18.7\;{\mu}M$, respectively. The $K_m$ valued for acetoacetyl-CoA and free CoASH in the thiolusis in the condensation reaction was 0.70mM. The condensation reaction of the ${\beta}$-ketothiolase was inhibited even by low concentrations of free CoASH($K_i=30.4{\mu}M$). Pretreatment of the enzyme with NADH and NADPH markedly inhibited the thiolysis reaction of the enzyme. The potent inhibition of the enzyme by sulfhydryl reagents suggests the involvement of cystein residue in the active site.

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피동 원자로건물 냉각계통 실험에 관한 수치적 연구 (Numerical Investigation on Experiment for Passive Containment Cooling System)

  • 하희운;서정수
    • 한국안전학회지
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    • 제35권3호
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    • pp.96-104
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    • 2020
  • The numerical simulations were conducted to investigate the thermal-fluid phenomena occurred inside the experimental apparatus during a PCCS, used to remove heat released in accidents from a containment of light water nuclear power plant, operation. Numerical simulations of the flow and heat transfer caused by wall condensation inside the containment simulation vessel (CSV), which equipped with 18 vertical heat exchanger tubes, were conducted using the commercial computational fluid dynamics (CFD) software ANSYS-CFX. Shear stress transport (SST) and the wall condensation model were used for turbulence closure and wall condensation, respectively. The simulation using the actual size of the apparatus. However, rather than simulating the whole experimental apparatus in consideration of the experimental cases, calculation resources, and calculation time, the simulation model was prepared only in CSV. Selective simulation was conducted to verify the effects of non-condensable gas(NC gas) concentration, CSV internal pressure, and wall sub-cooling conditions. First, as a result of the internal flow of CSV, it was observed that downward flow due to condensation occurred surface of the vertical tube and upward flow occurred in the distant place. Natural convection occurred actively around the heat exchanger tube. Due to this rising and falling internal flow, natural circulation occurred actively around the heat exchanger tubes. Next, in order to check the performance of built-in condensation model using according to the non-condensable gas concentration, CSV internal flow and wall sub-cooling, the heat flux values were compared with the experimental results. On average, the results were underestimated with and error of about 25%. In addition, the influence of CSV internal pressure and wall sub-cooling was small, but when the condensate was highly generated due to the low non-condensable gas concentration, the error was large compared to the experimental values. This is considered to be due to the nature of the condensation model of the CFX code. However, in spite of the limitations of CFD, it is valid to use the built-in condensation model of CFD for PCCS performance prediction from a conservative perspective.

화학기상응축법으로 제조한 Fe-Co 나노복합 분말의 미세구조와 자기적 특성 (Characterization of Fe-Co Nanocomposite Powders Produced by Chemical Vapor Condensation Methods)

  • 김병기;;최철진;김진천
    • 한국분말재료학회지
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    • 제9권5호
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    • pp.322-328
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    • 2002
  • Fe-Co nanocomposite powders with different composition were prepared by chemical vapor condensation (CVC) process and their characterizations were studied by means of X-ray diffraction, transmission electron microscopy, and vibrating sample magnetometer. The particles having the mean size of 5~25 nm consisted of metallic cores and oxide shells. The Co contents and particle size increased with increasing the carrier gas flow rate of Co precursor. The saturation magnetization and coercivity increased with increasing Co content. and the saturation magnetization maximized at the 40 wt.%Co. The Fe-Co nanocomposite powder oxidized at $400^{\circ}C$ showed the maximum coercivity of 1739 Oe.