• Title/Summary/Keyword: clean room

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Facile and Clean Synthetic Route to Non-Layered Two-Dimensional ZIF-67 Nanosheets

  • Choi, Chang-Ho
    • Clean Technology
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    • v.26 no.4
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    • pp.257-262
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    • 2020

  • Two-dimensional (2D) metal organic framework (MOF) nanosheets (NSs) have recently gained considerable interest owing to their structural advantages, such as large surface area and exposed active sites. Two different types of 2D MOF NSs have been reported, including inherently layered MOFs and non-layered ones. Although several studies on inherently layered 2D MOFs have been reported, non-layered 2D MOFs have been rarely studied. This may be because the non-layered MOFs have a strong preference to form three-dimensionality intrinsically. Furthermore, the non-layered MOFs are typically synthesized in the presence of the surfactant or modulator, and thus developing facile and clean synthetic routes is highly pursued. In this study, a facile and clean synthetic methodology to grow non-layered 2D cobalt-based zeolitic imidazolate framework (ZIF-67) NSs is suggested, without using any surfactant and modulator at room temperature. This is achieved by directly converting ultrathin α-Co(OH)2 layered hydroxide salt (LHS) NSs into non-layered 2D ZIF-67 NSs. The comprehensive characterizations were conducted to elucidate the conversion mechanism, structural information, thermal stability, and chemical composition of the non-layered 2D ZIF-67. This facile and clean approach could produce a variety of non-layered 2D MOF NS families to extend potential applications of MOF materials.

  • https://doi.org/10.7464/ksct.2020.26.4.257 인용 PDF KSCI

A Study on Flow Distribution in a Clean Room with Multiple Exits (다수의 출구를 가지는 크린룸 내부의 기류분포에 관한 연구)

  • Lee, Jae-Heon;Lee, Sie-Un;Kim, Sukhyun
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.17 no.4
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    • pp.418-425
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    • 1988

  • Since conventional computer program is workable only with velocity boundary condition, in practical fluid passage such as clean room which usually have wide inlets and outlets, it is not easy to measure velocity itself because of its vector property. Furthermore a certain assumption of velocity at boundaries may lead to physically unreasonable results. From this motivation, we have developed a computer program to predict whole flow field imposed on pressure-based boundary condition which can be measured by relatively simple method. The only additional velocity boundary condition that should be imposed on to make the problem unique, are no slip condition at all walls and zero cross stream velocity at inlet. The result of present study was compared with that by Bernoulli equation being used practically. They were coincident well each other within 5%, therefore the validity of the present method is proved. In the present work, the flow field in a clean room subject to pressure-based boundary conditions at an inlet and two exits was predicted numerically. The pressure difference between the inlet and the left exit which keeps relatively low pressure among two exits is fixed as 150[Pa] and the pressure at the right exit is varied from zero to 150[Pa] by the increment of 25[Pa]. For each cases the flow characteristics in the clean room, the velocity profile at the inlet, and the flow rate through the two exits was predicted. The flow rate through the right exit imposed on relatively higher pressure than the left exit decreased linearly according to the increase of pressure of the right exit. When the pressure of the right exit is increased enough to cause back flow at the exit, the flow rate is rapidly decreased.

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