• 폴리머
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• 제34권1호
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• pp.32-37
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• 2010

액정표시소자의 광배향막으로 적용하기 위하여 올리고머 신나메이트와 폴리(비닐 신나메이트) (PVCi)의 블렌드를 이용하여 그루브 패턴을 형성하고 광배향 특성을 관찰하였다. UV-vis 스펙트럼 분광계를 이용하여 자외선 조사 시간에 따른 광반응 속도를 평가한 결과 올리고머 신나메이트는 폴리(비닐 신나메이트)에 비해 빠른 반응속도를 나타내었다. 폴리(비닐 신나메이트)를 주성분으로 하여 올리고머 신나메이트를 블렌드한 경우 반응속도가 약간 향상되는 특성을 확인하였다. 올리고머 신나메이트는 높은 결정성으로 인해 표면 그루브 패턴을 단독으로 형성할 수 없었지만 폴리(비닐 신나메이트)와의 블렌드를 통하여 그루브 패턴을 형성할 수 있었으며 그루브 패턴에서도 polar plot에 의해 분자 배향성을 나타냄을 확인하였다. 올리고머 신나메이트와 고분자계 신나메이트의 블렌드를 통하여 반응속도의 향상과 박막 구조의 패턴을 형성하기에 적합함의 확인을 통해 새로운 광배향막 재료로 적용 가능함을 알 수 있었다.

• Macromolecular Research
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• 제16권1호
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• pp.31-35
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• 2008

Photoreactive polymers as a color filter resist containing both photoreactive acrylate and cinnamate double bonds were synthesized usin two step reactions. The chemical structures of the synthesized polymers were confirmed by $^1H$-NMR and FT-IR spectroscopy. The photoreactive polymers were quite soluble in most common organic solvents and produced excellent quality thin films by spin-coating. The photocuring kinetics of the acrylate and cinnamate double bonds were examined by FT-IR and UV- Vis spectroscopy, which confirmed the excellent photoreactivity of both the acrylate and cinnamate double bonds in the polymers. Upon UV irradiation, photocuring was almost completed within approximately 5 min, irrespective of the type of the prepolymers. The polymers also exhibited superior thermal stability, showing little change in transmittance in the visible region even after heating to $250^{\circ}C$ for one hour. Photolithographic micropatterns could be obtained with a resolution of a few microns.

• 한국식품영양학회지
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• 제12권5호
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• pp.513-517
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• 1999

Theessential oils of anise darkopal lettuce and sweet basils cultivated in Korea were extracted by simulatneous steam distillation and extraction method and were analyzed by GC/MSD. Total 41 com-ponents were identified in essential oils including 11 alcohols, 6 carbonyls 19 hydrocarbons and 5 esters components. The major components were 1,8-cineole linalool $\alpha$-bergamotene $\beta$-elemene methyl chavicol, $\beta$-cubebene methyl cinnamate and eugenol. Darkopal lettuce and sweet basils were rich in linalool(30.1-36.5%) methyl chavicol(8.1-25.5%) and relatively poor in methyl cinnamate(0-2.71%) Anise basil was rich in linalool(28.5%) and methyl cinnamate(23.1%) However methyl chavicol which was known as one of the main components of bisil was not detected.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1997년도 하계학술대회 논문집 C
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• pp.1588-1590
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• 1997

The viewing angle characteristics of amorphous(a)-twisted nematic(TN)-liquid crystal display (LCD) on poly(vinyl)cinnamate (PVC) surfaces with photo polymerrization were investigated. It was found that the threshold voltage increases with increasing the polymerization of PVC surfaces. That the domain size of a-TN-LCD is affected by the surface crystallization with increasing the photo polymerization of the photo-alignment film. We observed that the viewing angle of a-TN-LCD increased with increasing the photo polymerization on PVC surfaces. Finally, we consider that the viewing angle of a-TN-LCD on PVC surfaces is large compared to a-TN-LCD on polyimide(PI) surface.

• 대한화학회지
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• 제13권4호
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• pp.379-386
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• 1969

Polyethylene maleate (PEM) and epoxy resin cinnamate (BEC) were prepared to investigate their photosensitivity. Various samples coated on glass plate were exposed to light under various conditions and steeped in the same solvent as used for coating, and then the yield of residual film (W/$W_0$) was calculated. The yield (W/$W_0$), which was closely related to the sensitivity of the film, was affected by the degree of polymerization of the film, light source, sensitizers land their concentration. In polymer homologs, the sensitivity depended upon degree of polymerization. Most effective sensitizers for PEM and BEC among those used here were benzanthrone and 2,6-dichloro-4-nitroaniline.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집
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• pp.358-361
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• 2001

A new photoalignment material PM15CA, poly{N-(phenyl)maleimide-co-3-[4-(pentyloxy) cinnamate]propyl-2-hydroxy-1-methacrylate}, was synthesized and the electro-optical (EO) characteristics in the vertical-aligned (VA) liquid crystal display (LCD) photo-aligned on the photopolymer surface were studied. Excellent voltage-transmittance(V-T) characteristics in the VA-LCD photoaligned with polarized UV exposure of oblique direction on the pohotopolymer surfaces for 1 min can be achieved. The transmittance of the VA-LCD photoaligned on the photopolymer surface decreased with increasing UV exposure time. We suggest that the decrease of transmittance in the VA-LCD photoaligned on the photopolymer surface is attributed to the dissociation of the ester linkage in the photodimerized cinnamate structure with increasing UV exposure time

• E2M - 전기 전자와 첨단 소재
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• 제10권6호
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• pp.576-580
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• 1997

In this paper, the viewing angle characteristics of amorphous (a) - twisted nematic (TN)-liquid crystal display (LCD) on poly(vinyl)cinnamate (PVC) surface with UV (ultraviolet) light irradiation were investigated. It was found that the threshold voltage increases with increasing the polymerization of PVC surfaces. We observed that the domain size of a-TN-LCD decreases with increasing the photo polymerization by increasing UV light irradiation time on PVC films. Also, we observed that the viewing angle of a-TN-LCD increased with increasing the photo polymerization on PVC surfaces. Finally, we consider that the viewing angle of a-TN-LCD on PVC surfaces is large compared to a-TN-LCD on polyimide (PI) surface.

• Journal of the Korean Wood Science and Technology
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• 제31권4호
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• pp.63-70
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• 2003

송이(Tricholoma matsutake) 자실체의 메탄올(methanol, MeOH) 추출물로부터 4개의 화합물을 분리하였으며, 기기분석 결과 adenosine (9-𝛽-D-ribofuranosyladenine)을 비롯하여, methyl trans-cinnamate, ergosterol (ergosta-5, 7, 22-triene-3𝛽-ol) 및 ergosta-4, 6, 8 (14), 22-tetraen-3-one으로 각각 동정하였다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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• pp.317-319
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• 2008

Photo-alignment layer which contains cinnamate is difficult to generate pretilt angle of liquid crystals. In order to enhance pretilt angle, blending poly (amic acid) between containing fluorine poly (amic acid) and 1,2,3,4-cyclobutanetetracaroxylic dianhydride (CBDA) / 3,5-diaminobenzyl alcohol (DBA) were used. For photoreaction, cinnamate was conjugated by interfacial reaction with blending polyimide.

• 폴리머
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• 제30권5호
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• pp.417-421
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• 2006

신나모일 그룹의 광배향 메커니즘과 공정 조건들과의 관계를 이해하기 위하여 폴리(실록산 신나메이트) (PSCN)를 이용한 광배향 연구를 진행하였다. DSC와 편광현미경 실험에서 PSCN의 등방성 온도는 $105^{\circ}C$ 이상이었으며 액정 온도 구간에서 한 번 배열된 분자들은 저온이나 고온의 등방성 온도 구간에서도 없어지지 않는 열안정성을 보였다. UV/Vis 흡수 실험을 통해서는 광이량화 반응이 주된 광배향 반응이며 신나모일기가 스스로 배열되는 경향이 강하여 광이량화 반응의 효율을 높이는데 기여하지만 광조사가 지나칠 경우 경쟁 관계에 있는 photo-fries 반응이 증가하여 오히려 광배향 성질이 떨어짐을 알 수 있었다. 한편, photo-fries 반응은 UV의 파장을 조절하여 억제할 수 있었다.