• Polymer(Korea)
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• v.30 no.5
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• pp.422-425
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• 2006

Due to their periodic helical structure, cholesteric liquid crystals (CLC) have a unique ability to selectively reflect visible light. CLC films reflecting a broad wavelength band were prepared by inducing a pitch gradient in CLC layers through a diffusion of small molecules and through a thermal mixing of cyclic siloxane CLC molecules with different pitch lengths. Various pitch gradients in the CLC cell were observed using UV/Vis spectrometer and SEM technique.

• Applied Chemistry for Engineering
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• v.28 no.2
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• pp.230-236
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• 2017

We synthesized liquid crystalline polymers containing isosorbide group as a cholesteric derivative and methylene group for controlling the transition temperature to the liquid crystal phase. Effects of the concentration of the isosorbide group and the position of the methylene group on the properties of the liquid crystalline polymer were investigated. Among all the synthesized polymers, polymers (MnHI-x) with a methylene group in the main chain showed higher melting transition temperature and thermal stability than those (SnBI-x) with a methylene group in the side chain. All the synthesized polymers showed an enantiotropic liquid crystal phase. The polymers having 10 mol% isosorbide as a cholesteric liquid crystal phase derivative showed nematic phase, and those having 20 mol% or more isosorbide showed a cholesteric or chiral smectic phase. Thus, we can conclude that the isosorbide group plays a role as a cholesteric liquid crystal phase derivative.

• Proceedings of the Optical Society of Korea Conference
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• 2005.07a
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• pp.288-289
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• 2005

• Journal of Information Display
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• v.2 no.4
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• pp.15-18
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• 2001

We report simple techniques to manufacture low-powered, high-resolution, reflective cholesteric displays using flexible plastic substrates. We use wax transfer printing to replace photo-lithography and incorporate polymer walls to increase the mechanical strength and lifetime of the displays. These printing methods can easily be adapted to roll-to-roll production.

• Polymer(Korea)
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• v.34 no.3
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• pp.242-246
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• 2010

FTIR spectroscopy has been employed in order to quantitatively investigate the relationship between planar arrangements and selective reflectance of cholesteric liquid crystals. It was found that the selective reflection was enhanced as the amount of planar arrangements in cholesteric liquid crystals increased. Although the planar arrangements of cholesteric liquid crystals can be induced only by the shear force effect, it was more effective to use the alignment layer to obtain the perfect planar arrangements.

• Elastomers and Composites
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• v.52 no.3
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• pp.173-179
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• 2017

Side-chain liquid crystalline polymers having polysiloxane skeletons were synthesized by a thiol-ene reaction, using two kinds of mesogenic groups: a cholesteryl group for induction into a cholesteric liquid crystal phase and a triazomesogenic group for imparting light-sensitivity. All the synthesized polymers were crystalline, except the one with a single cholesteryl group. Crystallinity, glass transition temperature, and melt transition temperature increased with increasing content of the azomesogenic group. The polymer (P-C10A0) with a single cholesteryl group has a cholesteric phase, the one (P-C0A10) with a single azomesogenic group has a smectic phase, and those with both types of mesogenic groups showed both smectic and cholesteric phases. The temperature ranges of the two liquid crystalline phases in the co-polymers were independent of the contents of the two types of mesogenic groups. The rate of photoisomerization of the light-sensitive azobenzene group in the polymer decreased with increasing azobenzene content due to steric hindrance between the azomesogenic groups.

• Bulletin of the Korean Chemical Society
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• v.30 no.4
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• pp.935-937
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• 2009

• Polymer(Korea)
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• v.24 no.3
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• pp.418-430
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• 2000

A new hydroxylpropyl chitosan (HPCTO) capable of forming both thermotropic and lyotropic liquid crystalline phases was synthesized by reaction of alkali chitosan with propylene oxide and its solid films cross-linked with glyoxal were prepared by casting the liquid crystalline solution in methanol. The thermal and swelling properties of the cross-linked films were investigated. The films displayed fingerprint patterns characteristic of cholesteric liquid-crystalline phase, and their pitches increased with increasing temperature and cross-linker concentration. The cross-linked samples exhibited an anisotropic swelling in both water and methanol, suggesting that the two-dimensional cross-linking preferentially performs between HPCTO molecules. The degree of anisotropy highly depended on the solvent, but hardly on the cross-linker concentration investigated.

• 한국정보디스플레이학회:학술대회논문집
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• 2005.07a
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• pp.437-438
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• 2005

A polymer stabilization method is employed to reduce the transition time from field-induced homeotropic(H) state to reflecting planar(P) state in the cholesteric liquid crystal(ChLC) display. To stabilize ChLC by polymer, we mixed ChLC with diacrylate of 2 $wt%{\sim}6$ wt%. Two samples were made with different method of stabilization. For one sample the diacrylate of 2 wt% was polymerized with the ChLC in P state, while for the other sample diacrylate of 16 wt% was polymerized with ChLC in H state. In the former case, the transition time was 1000 times faster then those in the pure sample. In the latter sample, the transition time was 1700 times faster than those in pure ChLC sample.

• Polymer(Korea)
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• v.31 no.2
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• pp.148-152
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• 2007

The prototype of color fitters for the liquid crystal displays (LCD) using cholesteric liquid crystal monomers was produced. Cholesteric liquid crystal is characterized by the unique optical features of selective reflection, which is due to the helical twisting structures of LCs comparable to the wavelength of the incident light under certain conditions of substrate treatment. In the results of the experiment, cholesteric films for red, green, and blue light reflections respectively were produced and the viewing angle dependence of these films were investigated. Reflective light of red and green films shifted to shorter wavelength regions as viewing angle becomes greater, but blue one shifted very little. Periodic micrometer-sized half-spherical photoresist formed by thermal reflow method after photo-lithography was patterned on glass substrates. The viewing angle dependence of reflective light colors of red, green, and blue films on the patterned substrates compared with those on no patterned substrates was investigated. We could confirm the dependences were much smaller on the patterned substrates by bare eyes and Lab-color coordination methods qualitatively.