• Title/Summary/Keyword: chloride-free

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A Hardening Properties of Eco-Friendly SCW Grouting Material (친환경 SCW공법용 그라우팅재의 경화특성)

  • Jo, Jung-Kyu;Park, In-Wook;Mun, Kyung-Ju;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.2
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    • pp.109-115
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    • 2018
  • Since the current method of SCW cement milk pouring method uses one to one ratio of cement milk with OPC, there are some problems such as drying shrinkage, increased cost, difficulty of controlling mix proportions for various conditions of applied soil, and precipitation of $Cr^{6+}$ due to the excessively used cement. Specifically, in aspect of sustainability issues of cement manufacturing, the consumption of cement should be reduced. Hence, in this research, as a replacement of cement for SCW method, blast furnace slag with sulfate or alkali as a stimulant, and expansive admixture were used. By using blast furnace slag as a hardening composite of SCW, there are many advantages such as free controllable mix proportions, rapid setting time with less mud occurrence, less cost with less energy for mixing, constant strength development, and less precipitation of $Cr^{6+}$. Regarding the alternative composites for SCW, in this research, durability and chloride resistance were evaluated.

Real-time Internal Stress of Nickel Sulfamate Electroform (니켈쌀파메이트 전주층의 실시간 잔류응력)

  • Kim I.;Kang K.;Lee J.;Kwon S.C.;Kim M.;Lee J.Y.
    • Journal of the Korean institute of surface engineering
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    • v.38 no.1
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    • pp.14-20
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    • 2005
  • The control of internal stress is extremely important in electroforming because of the deliberately low adhesion between the electro form and the mandrel. Excessive tensile or compressive stress can cause distortion, separation problem, curling, peeling or separation of electroform prematurely from the mandrel, buckling and blistering. Nickel sulfamate bath has been widely used in electroforming because of its low internal stress and moderate hardness. In this study, real-time stress sensor has been used for stress control in chloride-free nickel sulfamate bath for 400 mm x 300 mm x 500 ㎛ nickel electroform. It was found that compressive stress found at low current density indicated the contamination of electrolyte, which is very useful in procuring buckling and peeling of electroform. No compressive stress is allowed for plate electroform. The real-time stress can also be used for accurate stress control of nickel electroform. The tensile stress was found to be increased slightly with increase in nickel electroform thickness, i.e., from initial 1.47 ksi to 2.02 ksi at 320 ㎛.

Tensile Properties of Nickel Electroform(l) (니켈 전주층의 인장 물성(1))

  • Kim I.;Lee J.;Kang K.;Kwon S.C.;Kim M.;Lee J.Y.
    • Journal of the Korean institute of surface engineering
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    • v.38 no.1
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    • pp.21-27
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    • 2005
  • Tensile properties and hardness of nickel electroform from chloride-free nickel sulfamate electrolyte at 50℃ and PH 4.5 were investigated. Current density varied from 20 to 60 mA/㎠. The deposit thicknesses were 360, 480 and 980 ㎛. It was found in 480 ㎛ thick electroform that highest tensile and yield strengths and hardness of 83.7 ksi, 53.6 ksi and 216 DPH, respectively were obtained at a current density of 40 mA/㎠ and they were slightly decreased at 20 and 60 mA/㎠. However the ductility was lowest of 7.9% at 40 mA/㎠. Such a high strength and low ductility at 40 mA/㎠ seems to be related to the narrower columnar structure than those of other current densities. All the deposits exhibited pronounced necking behavior. Tensile strength, yield strength and ductility increased as the nickel electroform thickens. Initial strong (200) texture developed on stainless steel mandrel decreased and (111) and (220) textures increased as deposit thickness increased, whereas (200) texture was preferred as the current density increased.

Construction of Antibacterial Electrospun Nanofiber from Poly(styrene-co-sulfadiazine) via Electrospinning (폴리(스티렌-설파디아진) 공중합체를 이용한 항균 나노섬유 제조)

  • Hwang, Seok-Ho;Ahn, Kyung-Hwan;Cha, Heechul;Kim, Jeong-Yeol;Hwang, Hong-Gu;Huh, Wansoo;Lee, Sangwon
    • Applied Chemistry for Engineering
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    • v.20 no.4
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    • pp.386-390
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    • 2009
  • In this study, sulfadiazine acrylamide monomer was synthesized by the reaction of sulfadiazine, known as an antibiotic substance, with acryloyl chloride. The monomer was characterized by $^1H-NMR$, and $^{13}C-NMR$. Using the synthesized sulfadiazine acrylamide monomer and styrene monomer, a copolymer, poly(styrene-co-sulfadiazine), was obtained by the free radical copolymerization and characterized by $^1H-NMR$, GPC, DSC and TGA. The copolymer nanofibers web has been successfully prepared by electrospinning technique under DMF solution. The diameter of the nanofibers was in the range between 500 and 800 nm. Antibacterial activity of the nanofiber web was evaluated utilizing the colony counting method against Staphylococcus aureus and Escherichia coli.

Effects of Hwangryunhaedok-tang plus Yukmijihwang-tang add Chogudeung on Blood Pressure and Renal Function in Spontaneously Hypertensive Rats (황연해독탕 합 육미지황탕 가 조구등이 자발적 고혈압 백서의 혈압 및 현장 기능에 미치는 영향)

  • Sohn Eun Jin;Kang Dae Gill;Lee An Sook;Kim Bok Hae;Lee Ho Sub
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.16 no.2
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    • pp.359-364
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    • 2002
  • The present study examined the effects of water extract of Hwangruynhaedoktang plus Yukmijihwangtang add Chogudeung (HYC) on the blood pressure and renal function in spontaneously hypertensive rats (SHR). The HYC water extract blocked increase of systolic blood pressure (SBP) in SHR. The urinary volume (UV), sodium (UNaV), potassium (UkV), and chloride (UclV) excretions were significantly increased in SHR administered with high dose of water extract of HYC, but urinary osmolality was not changed. The creatinine clearance (Ccr), which is index of glomerular filtration rate (GFR), was increased by administration of HYC, while solute-free water reabsorption (TcH2O) was not changed. Taken together, these results suggest that the depressor effects of HYC, at least in part, caused by diuretic effect due to increase of glomerular filtration rate.

Effects of Chunmagudeungeumgamibang on Hypertension (천마구등음가미방(天麻鉤藤飮加味方)이 고혈압에 미치는 영향)

  • Kim, Eun-Hye;An, Jung-Jo;Jo, Hyun-Kyung;Yu, Ho-Ryong;Seol, In-Chan;Kim, Yoon-Sik
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.21 no.5
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    • pp.1176-1184
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    • 2007
  • Chunmagudeungeumgamibang(CGE) has been used for many years as a therapeutic agent for acute stage of cerebrovascular disease and hypertension in oriental medicine. But the effect of CGE on hypertension and vascular system is not well-known. This study was done to investigate the effects of CGE on hypertension. The results were obtained as follow : CGE showed a safety in cytotoxicity and toxicity of liver. CGE showed scavenging activity on DPPH free radical. CGE showed the inhibitory effect on ROS and ACE. CGE significantly decreased the blood pressure and pulse in DOCA-salt hypertensive rat. CGE significantly decreased the levels of aldosterone in DOCA-salt hypertensive rat. CGE significantly decreased the levels of dopamine, epinephrine in DOCA-salt hypertensive rat. CGE significantly decreased the levels of potassium and chloride in DOCA-salt hypertensive rat. CGE significantly increased the levels of calcium in DOCA-salt hypertensive rat. These results suggest that CGE might be effective in treatment and prevention of hypertension

Changes in Nutritional Components of Toha-jeot (Salt- Fermented Toha Shrimp) during Fermentation (토하젓의 숙성과정중 영양성분의 변화)

  • 박원기;박영희;박복희;김희경
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.25 no.4
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    • pp.665-671
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    • 1996
  • Changes in the nutritional components of Toha-jeot, salt-fermented Toha shrimp(Caridina denticulata denticulata $D_{E} H_{AAN}$), which was salted with 20%(w/w) sodium chloride and fermented during 60 days at $4\pm1^{\circ}C$ were investigated. The free amino acid contents in Toha-jeot, of which glutamic acid, leucine, Iysine, arginine, glycine and alanine occupy the majority, in order of abundance, increased gradually up to 50 days of fermentation. Most of the nucleotides were decomposed to hypoxanthine; thus ATP and ADP were not detected. Fermentation decreased inosine, IMP and unsaturated fatty acid contents and increased saturated fatty acid contents of Toha-jeot. Palmitic acid was the most abundant fatty acid, followed by palmitoleic acid, linoleic acid, EPA and stearic acid. Among the mineral constituents of Toha-jeot, Na and Ca were dominantly occupying. The Hunter "L" and "b" values of Toha-jeot increased during fermentation while "a" value remained unchanged.

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Effect of Hwangryunhaedok-tang on Blood Pressure and Renal Functions in Spontaneously Hypertensive Rats (황연해독탕(黃連解毒湯)이 자발적(自發的) 고혈압(高血壓) 백서(白鼠)의 혈압(血壓) 신장(腎臟) 기능(機能)에 미치는 영향(影響))

  • Kook Yoon-Bum
    • Herbal Formula Science
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    • v.10 no.1
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    • pp.113-129
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    • 2002
  • The present study designed to investigate whether hwangryunhaedok-tang show an anti-hypertensive effect and elucidate its possible mechanism in spontaneously hypertensive rats. The systolic blood pressures (SBP) were significantly decreased as an oral administration of hwangryunhaedok-tang compared with their control group. The urine volume was significantly increased by administration of hwangryunhaedok-tang but urinary sodium (UNaV), potassium (UKV), chloride excretion (UCIV) were not remarkably affected. The urinary creatinine excretion rate (UcrV) was significantly increased in rats administered with hwangryunhaedok-tang in association with increase of creatinine clearance (Ccr). The urine osmolality (Uosmol) was significantly decreased in SHR administered with hwangryunhaedok-tang without being changed in solute-free water reabsorption ( TcH20). The expressions of Aquaporin 2 (AQP-2). 3 and ${\alpha}\;1$, ${\beta}\;1$ subunits of Na.K-ATPase were determined by Western blot analysis to assess the role of these proteins in association with changes of renal functions in SHR administered with hwangryunhaedok-tang. The expression of AQP-2 and 3 protein was significantly down-regulated in the kidney of SHR administered with hwangryunhaedok-tang compared with those in control rats without being altered expression of ${\alpha}\;1$, ${\beta}\;1$ subunits of Na,K-ATPase. In the in vitro assay, Angiotensin converting enzyme (ACE) was inhibited by hwangryunhaedok-tang in a dose-dependent manner. Berberine and/or palmatine, which are well known as a main components of hwangryunhaedok-tang, also have an ACE inhibitory effects in a dose-dependent manner. Taken together, these results suggest that hwangryunhaedok-tang lowered blood pressure through the increase of diuresis caused by down-regulation of water channels and the inhibition of Angiotensin converting enzyme.

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Effect of C/N ratio on polyhydroxyalkanoates (PHA) accumulation by Cupriavidus necator and its implication on the use of rice straw hydrolysates

  • Ahn, Junmo;Jho, Eun Hea;Nam, Kyoungphile
    • Environmental Engineering Research
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    • v.20 no.3
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    • pp.246-253
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    • 2015
  • The effects of carbon-to-nitrogen (C/N) ratio in simulated rice straw hydrolysates using glucose and ammonium chloride on polyhydroxyalkanoates (PHA) accumulation by Cupriavidus necator was investigated. In general, PHA accumulation rate was higher under higher degrees of N-deficient conditions (e.g., C/N ratio of 360:1) than lower degrees of N-deficient conditions (e.g., C/N ratio of 3.6:1 and 36:1). Also, the most PHA accumulation was observed during the first 12 h after the PHA accumulation initiation. This study showed that the similar PHA accumulation could be achieved by using different accumulation periods depending on C/N ratios. N source presence was important for new cell production, supported by approximately ten times greater PHA accumulation under the N-deficient condition ($NH_4Cl$ 0.01 g/L) than the N-free (without $NH_4Cl$) condition after 96 h. C/N ratio of the rice straw hydrolysate was approximately 160:1, based on the glucose content, and this accumulated $0.36{\pm}0.0033g/L$ PHA with PHA content of $21{\pm}3.1%$ after 12 h. Since external C or N source addition for C/N ratio adjustment increases production cost, an appropriate accumulation period may be used for PHA accumulation from organic wastes, based on the PHA accumulation patterns observed at various C/N ratios and C and N concentrations.

Corrosion Protection Method of Reinforcing Steel in Concrete by Using Corrosion Inhibitors

  • Bae Su-Ho;Chung Young-Soo;Kim Dae-Ho
    • KCI Concrete Journal
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    • v.14 no.4
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    • pp.145-150
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    • 2002
  • Reinforced concrete is inherently a durable composite material. When properly designed for the environment to be exposed and carefully constructed, reinforced concrete is capable of giving maintenance-free performance. However, unintentionally using improper materials such as non-washed sea sand having much salt together with poor controlled quality, or the concrete are placed in highly severe environment such as marine atmosphere, the corrosion of reinforcing steel in concrete becomes one of the most significant concerns of concrete. The purpose of this experimental research is to evaluate the performance of corrosion inhibitors for normal strength and high strength concrete, and to propose desirable measures for controlling corrosion of reinforcing steel in concrete. Test specimens in normal strength and high strength concrete were made with and without corrosion inhibitors. The accelerated corrosion test for reinforcing steel in concrete was adopted in accordance with JCI-SC3, which required the periodic 20 cycles for 140 days. One cycle includes 3 days for the wetting condition of $65^{\circ}C$ and $90\%$ RH, and 4 days for the drying condition of $15^{\circ}C\;and\;60\%$ RH. It was observed from the test that corrosion inhibitors in normal strength concrete and high strength concrete showed excellent corrosion resistance for reinforcing steel in concrete, but the silica fume in high strength concrete was found to have a negligible corrosion resistance if not used with corrosion inhibitors, since the chloride corrosion threshold limit in concrete containing silica fume without corrosion inhibitor was found to be considerably smaller than that of the case with corrosion inhibitor.

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