• Title/Summary/Keyword: chloride-free

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Optimum Conditions for Introducing Free Radical Polymerizable Methacrylate Groups on the MWCNT Surface by Michael Addition Reaction (MWCNT 표면에 Michael 부가 반응으로 자유 라디칼 중합 가능한 Methacrylate기 도입에 대한 최적 개질 조건)

  • Kim, Sunghoon;Park, Seonghwan;Kwon, Jaebeom;Ha, KiRyong
    • Korean Chemical Engineering Research
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    • v.53 no.1
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    • pp.83-90
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    • 2015
  • In this study, we investigated optimum conditions for the introduction of a lot of free radical polymerizable methacrylate groups on the multi-walled carbon nanotube (MWCNT) surface. Carboxyl groups were introduced first on MWCNT surfaces by treating with a mixture of sulfuric acid and nitric acid with ultrasonic bath for 2 hours, and oxidized MWCNTs were reacted further with thionyl chloride followed by triethylenetetramine (TETA) to introduce amino groups on the oxidized MWCNT surface, to make MWCNT-$NH_2$. To introduce free radical polymerizable methacrylate groups on the MWCNT-$NH_2$, MWCNT-$NH_2$ was reacted with 3-(acryloyloxy)-2-hydroxypropyl methacrylate (AHM) by Michael addition reaction. We investigated progress of modification reactions for MWCNT by fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and elemental analysis (EA). We found maximum degree of Michael addition reactions between AHM and TETA grafted on MWCNT-$NH_2$ for 10:1 mol ratio and 8 hour reaction time in our reaction conditions.

The Effects of Sodium Chloride and the Cultivation Method on Antioxidant Compounds and Activities in Wheat (Triticum aestivum) Sprouts (염화나트륨 처리 및 재배방법이 새싹밀의 항산화 성분 및 활성에 미치는 영향)

  • Yang, Ji Yeong;Lee, HanGyeol;Seo, Woo Duck;Lee, Mi Ja;Song, Seung-Yeob;Choi, June-Yeol;Kim, Hyun Young
    • The Korean Journal of Food And Nutrition
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    • v.35 no.3
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    • pp.213-222
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    • 2022
  • Sprouts have various health benefits. Specifically, wheat sprouts are rich in bioactive compounds, such as vitamins and polyphenols. Elicitation induces and enhances secondary metabolite biosynthesis in plants. Therefore, in this study, we investigated the effects of sodium chloride (NaCl) treatments on the growth profile, free amino acid content, and antioxidant activity of germinated wheat (Triticum aestivum). Wheat seeds were germinated at 20℃ for 10 days and treated with 0, 2, 4, 7.5, and 10 mM of NaCl 10 days before harvesting. Treating the soil bed with NaCl increased the nutritional component amounts, such as free amino acids and γ-aminobutyric acid. The chlorophyll a and b concentrations were the highest in the hydroponic system treated with 7.5 mM NaCl. In addition, the polyphenol and flavonoid contents of sprouts treated with 2 and 7.5 mM NaCl were 1.94 and 1.34 times higher than that of the control sprouts (0 mM NaCl, water only), respectively. These results suggest that 2 to 4 mM NaCl treatments improve the nutritional and food quality of wheat sprouts more than water only.

A study on the ulcerous inhibitory effects of Taeumchowetang (태음조위탕(太陰調胃湯)의 유탕억제효능(遺瘍抑制效能)에 관(關)한 연구(硏究))

  • Park, Dong-Un;Kim, Dal-Rae
    • Journal of Sasang Constitutional Medicine
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    • v.9 no.2
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    • pp.227-243
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    • 1997
  • The experimental study used in this paper was done to examine the clinical effects of Taeumchowetang for the gastric ulcer and the function of gastrointestinal tract using rats and mice which were administered orally the water extraction from Taeumchowetang. Then, the counter-action of the water extraction on the isolated ileum and gastric fundus, the inhibitory effects of pylorus-ligated ulcer and indomethacin-induced ulcer, the associations with gastric juice secretion, total acidity, pepsin output, the transportability in the small and large intestine, were studied with administering acetylcholine chloride and barium chloride. In addition, it was investigated whether the central nervous system related to pain control and sleeping time was influenced by Taeumchowetang. The following results have been obtained; 1. As resulting from injection of acetylcholine chloride and barium chloride into the isolated ileum of rats and mice, Taeumchowetang led to have an inhibitory effect on the muscle contraction of the ileum. Then, acetylcholine chloride was measured as lower effect than barium chloride 2. For the inhibitory effect on contraction for the gastric fundus strip in rats by either acetylcholine chloride or barium chloride, the one showed low inhibitory effect, on the other hand the other showed density-dependent effect. 3. The water extraction was given on the pylorus ligated ulcer with using two different administration groups of 1,300mg/kg and 2,600mg/kg, each result was measured as 22.9% and 36.5% for an ulcerous inhibitory effect (p<0.05). 4. According to the two administration groups, the preventive effect was tabulated 18.1% and 29.3% for indomethacin-induced ulcer (p<0.05, P<0.01). 5. For associations with gastric juice secretion, total acidity, pepsin output in the administration group 2,600mg/kg, Taeumchowetang was recognized as having an inhibitory effects related to suppressive actions involving gastric juice secretion(p<0.05), and free acidity(p<0.01), but there was no significant association with total acidity and pepsin output. 6. To know the transportability in the intestine, BaSO4 solution was used. The transportability of the small intestine in the administration group 2,600mg/kg was 22.2% which was statistically significant compared with the large intestine's transportability(P<0.01). 7. In the administration group 1,300mg/kg and 2,600mg/kg, analgesic effect with against acetic acid was measured as being 16.8% and 24.4% which was shown as statistically siginificant(p<0.01). 8. No statistically significant association between Taeumchowetang and sleeping time was found in both 1,300mg/kg and 2,600mg/kg by administering phenobarbital-Na. According to the results of this study, Taeumchowetang has agreed with the effects of literature review. Further more in this study, Taeumchowetang also has preventive effects on pylorus-ligated ulcer. Hence, Teaumchowetang can be significant effect such as both anti ulcer agent and increasing gastric activity for the patients who suffer from gastric ulcer.

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Chromate Removal from Wastewater using Micellar Enhanced Ultrafiltration and Activated Carbon Fibre Processes; Validation of Experiment with Mathematical Equations

  • Bade, Rabindra;Lee, Seung-Hwan
    • Environmental Engineering Research
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    • v.13 no.2
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    • pp.98-104
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    • 2008
  • In this study, chromate and cetylperidinium chloride (CPC) removal from artificial wastewater was monitored by using micellar enhanced ultrafiltration (MEUF) and activated carbon fibre (ACF) adsorption hybrid processes. For the efficient chromate removal, molar concentration of the CPC should be five times that of chromate and it should be at least one critical micelle concentration (CMC). The MEUF was found to be effective in the chromate removal while ACF in the CPC adsorption to produce chromate and CPC free effluents. The chromate and CPC removal was 99.8% from MEUF-ACF process. Effluent chromate concentration was exponentially correlated with molar ratio of CPC to chromate and pH.

A Study on the Antimicrobial Activity of Allylamine Polymers(II) (Allylamine계 항균제의 합성 및 그 항균성에 관한 연구(II))

  • 심재윤;조예경;윤남식;박태수
    • Textile Coloration and Finishing
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    • v.11 no.6
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    • pp.36-42
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    • 1999
  • The antimicrobial activities of the copolymer of N,N'-dimethyl- N,N'-diallyl ammonium chloride(DMDAAC) and diallyl amino(DA) were investigated. The copolymer of DMDAAC and DA was prepared by free radical Polymerization through an intra-intermolecular propagation mechanism ie, cyclopolymerization. The copolymer was, then, reacted with cyanuric chloride for reactivity with hydroxyl group of cellulose. Cotton fabrics were finished by synthesized polymer, and their antimicrobial activities and fastness to launderings were tested. Dichlorotriazinyl DMDAAC-DA copolymer has MIC value of 1ppm against S. aureus and 10ppm against K pneumoniae. The antimicrobial fastness of the finished cotton to launderings were good enough to show colony reduction above 70% against S. aureus and K pneumoniae after 50 repeated laundering in anionic commercial detergent. Optimum treatment concentrations of the polymer were 0.5% in cold pad-batch method, and 0.1% in pad-dry method.

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Dissolution Kinetics of Sphalerite in Aqueous Ferric Chloride Solution (염화제이철 수용액에서 섬아연광의 용해에 관한 속도론적 연구)

  • Yoo, Seung-Joon;Park, Hyung-Sang;Choi, Cheong-Song;So, Chil-Sup
    • Economic and Environmental Geology
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    • v.26 no.3
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    • pp.421-429
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    • 1993
  • Dissolution reactions of chemical grade zinc sulfide and natural sphalerite were studied in ferric chloride solution as an oxidant. To enhance the leaching reaction, ultrasonic technique was employed in this investigation. For the reaction with pure zinc sulfide, chemical reaction was the rate limiting step in the range of low conversion irrespective of applying ultrasonic wave. And the diffusion through liquid film instead of diffusion through product layer of free sulfur was the rate determining step because ultrasonic vibration removes the product from reaction zone. In the case of sphalerite with the ultrasonic vibrator, it was found that inert mineral layer diffusion was the rate determining step, in which the elemental sulfurs formed were removed by the ultrasonic action. Experimental results showed that the ultrasonic technique proved to be the methods which can significants improve the leaching performance.

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Factors that Influence Biofilm Formation in Vibrio parahaemolyticus (장염비브리오의 biofilm 형성에 영향을 미치는 인자)

  • No, A-Reum;Park, Kwon-Sam
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.42 no.5
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    • pp.456-460
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    • 2009
  • Biofilm is a structured community of microorganism encapsulated within a self-developed polymeric matrix and adherent to a living or a solid surface. In this study, we investigated the effects of various substrates on the formation of biofilm in Vibrio parahaemolyticus. We found that biofilm formation profoundly increased in a substrate, that consisted of calcium chloride, calcium nitrate, and calcium sulfate in 1% peptone water. On the other hand, a dramatic reduction in biofilm formation was observed in a substrate, that consisted of glucose and ferric chloride in LB broth. These results suggest that V. parahaemolyticus prefer to form a biofilm on the surface of a crustacean or a clam, where calcium ion is rich, and also where seawater temperature is relatively lower. In contrast, high levels of glucose in a crustacean or a clam body resulting from increased seawater temperature, can make V. parahaemolyticus detach from it and lead to free floating.

Tolerance of the Mutants of Pyricularia oryzae against Mercuric Chloride (자외선조사에 의해 유도된 도열병균의 승홍에 대한 내성에 관하여)

  • 김경호
    • Journal of Plant Biology
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    • v.22 no.3
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    • pp.85-91
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    • 1979
  • Tolerance against mercuric chloride in mutants of Pyricularia oryzae Cavara induced by ultraviolet(UV) irradiation has been investigated. The tolerant isolates obtained using ultraviolet(UV) irradiation were maintained a high level of tolerance even after 15 times transfer to the chemical free media. Each isolate of mutants UM-1, UM-2, and UM-3 on the successive monoconidial culture has genetically homogeneous for tolerance. The tolerant isolates sporulated less and showed a higher percentage of germination of conidia on media without the chemical than the parental isolate. The xotins released from the parental and the tolerant isolates have been identified as piricularin and $\alpha$-picolinic acid by paper-chromatography. The tolerant isolates produced more piricularin and its virulence on seedlings of rice varieties were higher than the parental isolates. Both piricularin production and virulance on rice were highest in the UM-2 isolate.

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The Synthesis of Poly(DADM) Flocculant and Properties in Potable Water Treatment (Poly(DADM) 고분자 응집제의 합성 및 상수처리 특성)

  • 박이순;신준호;최상준;신명철;이석훈
    • Journal of Environmental Science International
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    • v.7 no.5
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    • pp.687-692
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    • 1998
  • Poly(DADM) was synthesized for the drinking water treatment. Poly(DADM) was produced by the free radical polymerization of diallyldimethylammonium chloride(DADM) monomer and its properties were characterized. The effects of monomer concentration, initiator concentration and reaction time on synthesis of poly(DADM) were investigated. Poly(DADM) flocculant was applied to Nak-dong river water to examine its efficiency in reducing turbidity. The synthesized poly(DADM) was effective as flocculant for drinking water treatment. The addition of 1 mg/L of poly(DADM) flocculant caused the reduction of 50% PAC(polyaluminium chloride).

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Experimental Studies on the Effects of Kamikwakjeongtang (가미곽정탕(加味藿正湯)의 효능(效能)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Ahn, Joung-Ran;Ryu, Bong-Ha;Park, Dong-Won;Rhy, Ki-Won
    • The Journal of Korean Medicine
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    • v.15 no.2 s.28
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    • pp.184-197
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    • 1994
  • In order to investigate the effects of Kamikwakjeongtang by using the experimental animals. the action on gastrointestinal smooth muscles. the action of gastric juice secretion, the action of antiulcer. the transport ability of intestinal contents. the action of anticatharsis and the actions on the central nervous system were studied. The results were as follow: 1. Spontaneous motility of the isolated ileum of mice was suppressed and antiacetylcho-line chloride action was recognized. 2. Anti-action on barium chloride of fundus-strip of white rat was recognized. 3. Supression effects on gastric juice secretion. free acidity was recognized. 4. Preventive effect on the ulcer induced by pylorus-ligated was recognized. 5. Supression effects of large intestinal transport ability was recognized. 6. Anti-carthartic action was shown but was not recognized. 7. Analgesic effect by the acetic-acid method and prolonged effect of the total sleep time by pentobarbital-Na were recognized. According to the above results, effects based on oriental medical reference were consistent with the actual experimental effects.

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