• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2015년도 춘계 학술논문 발표대회
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• pp.50-51
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• 2015

In marine and coastal environments, penetration of chloride ions is one of the main mechanisms causing concrete reinforcement corrosion. Currently, most of experimental investigations about submerged penetration of chloride ions are started after the four weeks standard curing of concrete. The further hydration of cement and reduction of chloride diffusivity during submerged penetration period are ignored. To overcome this weak point, this paper presents a numerical procedure to analyze simultaneously cement hydration reaction and chloride ion penetration process. First, using a cement hydration model, degree of hydration and phase volume fractions of hardening concrete are determined. Second, the dependences of chloride diffusivity and chloride binding capacity on age of concrete are clarified. Third, chloride profiles in hardening concrete are calculated. The proposed numerical procedure is verified by using chloride penetration test results of concrete with different mixing proportions.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.731-736
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• 2002

The degradation of reinforced concrete (RC) structures due to physical and chemical attacks has been a major issue in construction engineering. Deterioration of RC structures due to chloride attack followed by reinforcement corrosion is one of the serious problems. The objective of this study is to develop a form of mathematical model of chloride ingress into concrete. In order to overcome some limits of the previous approaches, a mathematical model of chloride ingress into concrete consisting of chloride solution intrusion through the capillary pore and chloride ion diffusion through the pore water was proposed. Moreover, the variability of diffusivity of chloride ion due to degree of hydration of concrete, relative humidity in pore, exposure condition, and variation of chloride binding was considered in the chloride ingress model.

• Macromolecular Research
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• 제12권4호
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• pp.427-430
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• 2004

Calix[4]crown-6-2,4-bis(2-hydroxyethyl ether) (2), which has crown-6 moieties at the 1- and 3-positions and hydroxyethyl functions at the 2- and 4-positions, was prepared for the syntheses of polyester 3 and polyurethane 4 by reactions with adipoyl chloride and hexamethylene diisocyanate, respectively. The ion binding characteristics of monomer 2 and polymers 3 and 4 toward alkali and alkali earth metal ions were measured by liquid-liquid extraction from the aqueous phase into the organic phase. We observed that the polyurethane 4 has a higher binding affinity toward various metal cations when compared to polyester 3, which exhibits cesium ion selectivity.

• 한국해안해양공학회지
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• 제15권2호
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• pp.71-79
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• 2003

본 논문에서는 염소이온 침투해석에 사용되는 염소이온 확산계수. 염소이온 고정화 관계식, 증발가능 수량에 대한 일반 예측식들을 제시하였다. 이러한 식들을 염소이온 확산 모델링에 대입하여 그 식들의 유효성을 검토하였다. 상대습도와 양생온도의 염소이온 확산에 대한 영향은 주로 확산계수를 변화시켜 고려한다. 상대습도가 증가하면 염소이온 확산깊이는 증가하고 재령이 경과할수록 상대습도가 확산깊이에 미치는 영향은 커진다. 반면에, 양생온도가 증가하면 확산깊이가 조금 증가하지만 재령이 경과할수록 양생온도가 확산깊이에 미치는 영향은 감소한다. 한편, 염소이온의 고정화에 영향을 미치는 시멘트의 $C_3$A양이 증가하면 표면에서는 고정염소이온의 증가로 인해 전체 염소이온량이 증가하지만 깊이가 깊어질수록 확산되는 자유염소이온의 감소로 인해 전체 염소이온량이 감소한다. 물-시멘트비가 감소하면 염소이온의 확산깊이는 급격히 감소하고 염소이온의 확산을 막는 가장 효과적인 방법은 물-시멘트비를 감소시키는 것임을 알 수 있다

• Bulletin of the Korean Chemical Society
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• 제5권6호
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• pp.249-253
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• 1984

Mutual diffusion coefficients of choline chloride were determined by using the diaphragm cell method in aqueous solutions of chondroitin sulfate A at $25^{\circ}C$. The diffusion coefficients of choline chloride in 0.1g/100ml, 0.5g/100ml and 1g/100ml respectively of chondroitin sulfate solutions were compared with those of binary systems of water-choline chloride. At low concentrations, the diffusion coefficients of the choline chloride in the presence of chondroitin sulfate were significantly smaller than the values obtained in the absence of chondroitin sulfate, indicating a strong interaction between these solutes. The effect of this interaction on the diffusion of choline ion is largest at higher chondroitin sulfate concentrations and at lower choline chloride concentrations. The influence of chondroitin sulfate is overcome at higher choline chloride concentrations. Self-diffusion coefficients of choline ion in the presence of chondroitin sulfate are also obtained. Excellent agreements were obtained between the experimental data and the calculated values obtained by using the Manning's equations. These observations suggest that the interaction between choline chloride and chondroitin sulfate involves primarily a long range electrostatic effect and there is no appreciable "condensation" or binding of choline ion to the chondroitin sulfate.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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• pp.437-442
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• 1999

Corrosion of steel reinforcment is the most significant factor of deterioration in reinforced concrete structures. Chloride ion is considered one of the most common culprits on the corrosion of steels in concrete. This study is effect of cement hydraulic degree on the chloride binding in hardened cement pastes. With increasing the cement hydration, cement products such as CSH and Ca(OH)2 were increased, and the part of added chloride were binded with them. With respect to A type, in first, the additional contents of chloride of 27.08mM/L in pore solution were reduced as 4.3mM/L at 3 days, 4.0mM/L at 7 days, 3.6mM/L at 28 days.

• 한국방재학회 논문집
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• 제10권1호
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• pp.15-22
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• 2010

자연환경 중 다양한 형태로 존재하는 염화물은 콘크리트 구조물의 철근 부식을 야기하며 이에 따른 심각한 내구성 저하와 함께 구조물의 수명을 감소시킨다. 현재 콘크리트 중의 염화물 침투 특성을 규명하기위한 연구는 해안가 장기 폭로 시험과 전기화학적 촉진 시험에 의한 확산계수 평가 등에 의해 지속적인 발전을 이루어왔으나 콘크리트의 배합, 수화도, 고정화능력, 공극률의 재료적 특성을 고려한 이성적이며 포괄적인 염화물 침투 모델에 관한 연구는 부족한 실정이다. 따라서 본 연구에서는 실내 염화물 침지 실험을 통해 콘크리트의 염화물 고정화 특성을 파악하고 이를 고려한 염화물 침투 모델로서 비정상상태의 염화물 침투 해석과 함께 해양침지환경하의 철근콘크리트 구조물의 내구수명 예측을 시도하였으며 SHRP 기준과 20~40%의 내구수명의 차이를 보였다.

• Journal of Photoscience
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• 제9권2호
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• pp.308-310
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• 2002

Bacteriorhodopsin (bR) and halorhodopsin (hR), which exist in the membrane of Halobacterium salinarum, are light-driven ion pumps. In spite of high similarity of primary and tertiary structures between bR and hR, these membrane proteins transport different ions, proton and chloride, in the opposite direction. From alignment of the amino acid sequences, Thr-89 of bR is homologous to Ser-l15 of hR from Halobacterium salinarum (shR). X-ray structure of shR has revealed that OH group of this residue directly interacts with CI$\^$-/ Thus, Ser-lI5 of shR is expected to play an important role in CI$\^$-/ binding and transport. In this study, we expressed wild type hR from Natronobacterium pharaonis (PhR) and Sl30A, which corresponds to Ser-l15 of shR, in E. coli in order to clarify binding affinity of chloride ion and photocycle reactions. From the titration with CI$\^$-/, affinity of Sl30A became quite lower than that of WT (WT 6 mM, Sl30A 89 mM). Furthermore, from the flash photolysis with pulse laser of λ$\_$max/ at 532 nm, the reaction rate of SI30A from 0 intermediate to hR ground state was found to become apparently slower than that of WT. The singular value decomposition (SVD) and global fitting analyses of the photocycles were performed to identify all photointermediates and determine the reaction rates.

• Macromolecular Research
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• 제13권2호
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• pp.141-146
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• 2005

Calix[4]crown-6-2,4-bis(4-aminobutyl ether), which has a crown-6 moiety at the 1,3-position and amino function at the 2,4-position, was prepared as an intermediate for the subsequent synthesis of calix[4]crown-6-containing polyamide and polyimide using adipoyl chloride and 1,2,4,5-benzenetetracarboxylic dianhydride. The chemical structures were characterized by IR, $^{1}H NMR$ spectroscopy and elemental analysis, and some of their physical properties, including their thermal behavior, were examined. The ion binding characteristics of the monomer and polymers for alkali metal and alkali earth metal ions were measured by liquid-liquid extraction from the aqueous phase into the organic phase. It has been observed that polyamide has a high binding ability towards various metal cations as compared to polyimide, which showed cesium ion selectivity.

• Bulletin of the Korean Chemical Society
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• 제32권spc8호
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• pp.2891-2892
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• 2011