• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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• pp.787-792
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• 2001

The chloride ion penetrating into concrete is classified as the fixed chloride ion being bound in reacting to cement hydrate and the free chloride ion having a direct effect on rebar corrosion because being in solution inside porosity of concrete. Therefore, in order to study the diffusion properties of chloride ion, it is needed to evaluate binding chloride ion in concrete. In this study, we tried to give a fundamental information on diffusion of chloride ion in concrete with mineral admixtures through analysis of micro-structure transformations in concrete and effects on binding of chloride ion in cement paste when mixed with fly-ash, blast furnace slag, silica fume etc. which are used to improve durability and permeability of concrete

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1997년도 봄 학술발표회 논문집
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• pp.186-190
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• 1997

Corrosion of steel reinforcement is the most significant factor of deterioration in reinforced concrete structures. It breaks down the passive film and allows the steel to be corroded severely at a high rate. The main object of this study is to determine the critical chloride ion concentrations in the pore solutions and chloride binding effect of cement pastes. It is found that binding chloride ion ratio of cement is between 0.04% and 0.3% and Cl/OH in pore solution under 0.3.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2016년도 춘계 학술논문 발표대회
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• pp.51-52
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• 2016

This paper researches the Chloride Binding of Cement Paste according to the Ca/Si and Ca/Al Ratio. The mechanisms of chloride ion binding are not completely known, although it is believed that Alumina contents in cementitious system have an important role. For changing cement paste composition, Ordinary Portland Cement(OPC) paste is substituted by Granulated Ground Blast Slag(GGBS). With increasing the ratio of GGBS substitution(Thus alumina contents is increasing), The chloride binding capacity has a tendency to increase of binding chloride ion capacity.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2018년도 춘계 학술논문 발표대회
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• pp.27-28
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• 2018

Deterioration of reinforced concrete structures due to salt corrosion is a phenomenon that can be easily seen, and the main reason for deterioration is chloride ion. Therefore, researches are actively conducted to control chlorine ion penetration worldwide. The purpose of this study is to evaluate the chloride ion fixation capacity of Portland cement paste containing Hydrotalcite. For this purpose, cement paste containing 0%, 2.5%, and 5% of Hydrotalcite was sealed and cured for 28 days, and the cured cement paste was crushed. Chloride ion solution was prepared at a concentration of 0.5M using NaCl, and the powdered cement paste was reacted for a specific time in aqueous chloride ion solution. After the reaction, the concentration of the chloride ion aqueous solution was measured using a silver nitrate potentiometric titrator, and the reacted cement paste was analyzed using XRD and FT-IR.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1995년도 봄 학술발표회 논문집
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• pp.106-110
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• 1995

Chloride ion is considered one of the most common culprits in the corrosion of steel in concrete. It breaks down the passive film and allows the steel to corrode actively at a high rate. The main objective of this study is to determine the critical chloride ion concentrations in the pore solutions and chloride binding effect of cement pastes made with and without fly ash. Cement pastes with water-ratio of 0.5 allowed to hydrate in sealed containers for 28 days and to express poresolution. T도 expressed pore fluids were analyzed for chloride and hydroxyl ion concentrations. It was found that the replaced cement with fly ash have little effect on Chloride binding capacity ratio.

• 콘크리트학회지
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• 제7권6호
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• pp.209-215
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• 1995

철근의 부식은 철근콘크리트 구조물의 열화에 가장 영향이 큰 요소이며, 염화물 이온에 의한 염해는 철근부식을 일으키는 가장 일반적인 원인 중의 하나이다. 본 연구는 콘크리트의 성능개선과 내구성 향상을 위해 사용량이 증가하고 있는 플라이 애쉬의 시멘트 경화체 내에서의 $Cl^-$고정화에 미치는 영향을 검토하기 위해 밀봉용기 내에서 양생시킨 재령28일 공시체의 세공용액을 추출하여 세공용액 중의 $Cl^-$, $OH^-$농도 측정과 세공용액 추출용과 같은 배합 공시체의 증발수량 측정으로 세공용액량 및 시멘트 페이스트내에서의 $Cl^-$ 고정화량을 산정한 것이다. 연구결과 플라이 애쉬 치환이 시멘트 경화체내 세공용액의 $Cl^-$농도와 프리델씨염 생성량 및 고정화량 증가에 미치는 영향은 거의 없고, 철근부식에 관계하는 $Cl^-$/$OH^-$는 증가하는 것으로 나타났다.

• Computers and Concrete
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• 제11권4호
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• pp.305-316
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• 2013

This paper aims to study the effect of measurement methods and cracking on chloride transport of concrete materials. Three kinds of measurement methods were carried out, including immersion test, rapid migration test and steady-state migration test. All of these measurements of chloride transport show that chloride ion diffusion coefficient decreased with the reduction of water to cement ratio. Results of the immersion test were less than that of rapid migration test and steady-state migration test. For the specimen of lower water to cement ratio, the external electrical field has little effect on chloride binding relatively. Compared with the results obtained by these different measurement methods, the lower water to cement ratio may cause smaller differences among these different methods. The external voltage can reduce chloride binding of concrete, and the higher electrical field made a strong impact on the chloride binding. Considering the effect of high voltage on the specimen, results indicate that results based on the steady-state migration test should be more reasonable. For cracked concrete, cracking can accelerate the chloride ion diffusion.

• 한국건축시공학회지
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• 제4권4호
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• pp.95-101
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• 2004

The purpose of this paper is to compare free-chloride content with water-soluble chloride in blast furnace cement(BSC) paste. The content of free-chloride in cement paste measured by pore solution analysis and water-soluble chloride measured by ASTM. The result of this study are as follows: 1. The concentration of chloride ion in pore solution of BSC-solidified matrix is almost as low as 43-71% compared to that of OPC-solidified matrix containing the same chloride content in cement paste. 2. The binding capacity of specimens, OPC Pl-P5, are 93.5-77%, but the binding capacity of specimens, BSC Pl-P5 are 97.1-86.1%, which is to be as high as 2-9.1% compared to OPC containing the same chloride content. 3. In terms of water-soluble chloride content in BSC paste are 15-31.7 percent of chloride addition but free-chloride content in pore solution are 2.9-13.9 percent of chloride addition. The free-chloride content in pore solution is 19.3-43.8 percent lower for the water-soluble chloride content in cement paste.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1994년도 가을 학술발표회 논문집
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• pp.87-92
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• 1994

The main objective of this study is to determine the critical chloride ion concentrations in the pore solutions causing depassivation of steel reinforcement in concrete made with cements of different $C_3A$ contents. Cement pastes with water-ratio of 0.5 were prepared using four cements with $C_3A$ contents of 0.46, 5.97, 9.14, and 9.65 percent. The pastes were allowed to hydrate in sealed containers for 28days and then objected to pore solution expression. The expressed pore fluids were analyzed for chloride and hydroxyl ion concentrations. It was found that the free cholride concentration in the pore solution decreases significantly with an increase in the $C_3A$ content of the cement. With increasing level of chloride addition, although the alsolute amount of bound chloride increase, the ratio of bound to total chlorides decreases.

• Corrosion Science and Technology
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• 제8권2호
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• pp.81-88
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• 2009

Chloride induced corrosion of steel reinforcement inside concrete is a major concern for concrete structures exposed to a marine environment. It is well known that transport of chloride ions in concrete occurs mainly through ionic/molecular diffusion, as a gradient of chloride concentration in the concrete pore solution is set. In the process of chloride transport, a portion of chlorides are bound in cement matrix then to be removed in the pore solution, and thus only the rest of chlorides which are not bound (i.e. free chlorides) leads the ingress of chlorides. However, since the measurement of free/bound chloride content is much susceptible to environmental conditions, chloride profiles expressed in total chlorides are evaluated to use in many studies In this study, the capacity of chloride binding in cement matrix was monitored for 150 days and then quantified using the Langmuir isotherm to determine the portions of free chlorides and bound chlorides at given total chlorides and the redistribution of free chlorides. Then, the diffusion of chloride ion in concrete was modeled by considering the binding capacity for the prediction of chloride profiles with the redistribution. The predicted chloride profiles were compared to those obtained from conventional model. It was found that the prediction of chloride profiles obtained by the model has shown slower diffusion than those by the conventional ones. This reflects that the prediction by total chloride may overestimate the ingress of chlorides by neglecting the redistribution of free chlorides caused by the binding capacity of cement matrix. From the evaluation, it is also shown that the service life prediction using the free chloride redistribution model needs different expression for the chloride threshold level which is expressed by the total chlorides in the conventional diffusion model.