• 제목/요약/키워드: chloride content of surface

검색결과 122건 처리시간 0.023초

다공성 탄소전극상 무전해 니켈도금의 산성과 알칼리용액 비교 연구 (Comparison of Acidic and Alkaline Bath in Electroless Nickel Plating on Porous Carbon Substrate)

  • 천소영;강인석;임영목;김두현;이재호
    • 한국표면공학회지
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    • 제43권2호
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    • pp.105-110
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    • 2010
  • Electroless nickel plating on porous carbon substrate for the application of MCFC electrodes was investigated. Acidic and alkaline bath were used for the electroless nickel plating. The pore sizes of carbon substrates were 16-20 ${\mu}m$ and over 20 ${\mu}m$. The carbon surface was changed from hydrophobic to hydrophilic after immersing the substrate in an ammonia solution for 40 min at $60^{\circ}C$. The contact angle of water was decreased from $85^{\circ}C$ to less than $20^{\circ}$ after ammonia pretreatment. The deposition rate in the alkaline bath was higher than that in the acidic bath. The deposition rate was increased with increasing pH in both acidic and alkaline bath. The content of phosphorous in nickel deposit was decreased with increasing pH in both acidic and alkaline bath. The contents of phosphorous is low in alkaline bath. The minimum concentration of $PdCl_2$ for the electroless nickel plating was 10 ppm in alkaline bath and 5 ppm in acidic bath. The thickness of nickel was not affected by the concentration of $PdCl_2$.

고기능성 쌀단백질 소재 개발 연구 (A study on the development of high functional food protein ingredient from rice bran)

  • 이의석;김기종;김재현;홍순택
    • 농업과학연구
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    • 제37권1호
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    • pp.61-68
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    • 2010
  • Rice bran proteins from different cultivars(Youngan, Sindongjin, Suwon 511) were extracted with Xylanase using orthogonal analysis method and their functional properties were investigated. The optimum extraction conditions, based on protein content in the extract found to be at 1 wt% xylanase, pH 7 and 50:1, solvent to rice bran ratio(v/w %). Nitrogen solubility indices(NSI) of rice bran protein concentrates were shown a minimum value at pH 4 ranged 2~23%, varied with different cultivars and a maximum (NSI${\geq}$90% for all cultivars) at pH 10. As for water adsorption and fat adsorption capacity, rice bran protein concentrates were shown to be better than Na-caseinate and isolated soy protein, respectively. Emulsifying activities were observed high in order of Na-caseinate>Youngan rice bran protein>Shindongjin rice bran protein>Suwon 511 rice bran protein>isolated soy protein. In general, the surface tension of rice bran protein solution($10^{-3}$ wt%, 5 mM bis-tris, pH 7) was increased with increasing concentrations and found a minimum value near pI. On heating, it was decreased slightly with increasing temperatures up to $70^{\circ}C$ and then increased above $80^{\circ}C$. Addition of sodium chloride was made the surface tension decrease. In conclusion, with Xylanase, rice bran protein concentrate can be successfully extracted from the rice bran of different cultivars and the Youngan rice bran protein was thought to have best functionality among rice cultivars tested. It might be used as a milk protein substitute.

고분자성 Al(III) 응집제의 특성이 상수원수의 응집특성에 미치는 영향 (Effects of Characterization of Polymeric Al(III) Coagulants on Coagulation of Surface Water)

  • 이선기;한승우;강임석
    • 상하수도학회지
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    • 제12권2호
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    • pp.99-105
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    • 1998
  • This research explored the feasibility of preparing and utilizing a preformed polymeric solution of Al(III) for coagulation in water treatment. Slow base(NaOH) injection into supersaturated aluminum chloride solutions did produce high yields of the type of Al polymers useful to water treatment applications. PACl's characteristic analysis showed that the quantity of polymeric Al produced at value of $r(OH_{added}/Al)=2.2$ was 83% of the total aluminum in solution, as showing maximum contents and precipitate was dramatically increased when r was increased above 2.35. And PACl was stable during sitoring period so aging effect was negligible. Results of the coagulation of Nakdong river waters with three PACls showed that the effectiveness of the three coagulants can be considered as r = 2.2 > r = 2.0 > r = 2.35 which are also the order of higher polymeric aluminum contents. Coagulation results for synthetic water exhibited optimum dose of 0.25mM Al, for three PACls, but above optimum dose, r = 2.0 and 2.2 PACl impaired the coagulation and sedimentation of turbidity and humic acid because of the restabilization of particulate. The effect of pH for on coagulation of Nak Dong River water showed that it had much effect turbidity and TOC removal, especially near pH 7. But pH effect was little for turbidity and TOC removal when r = 2.35 PACl was used for coagulation, that PACl had much more precipitates content.

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Studies on the Processing Properties and Interactions Between Porcine Blood Proteins and Waxy Rice Starch During Making Porcine Blood Cake

  • Lin, Chin-Wen;Yang, Jeng-Huh;Chu, Hsien-Pin;Su, Ho-Ping;Chen, Hsiao-Ling;Huang, Chia-Cheong
    • Asian-Australasian Journal of Animal Sciences
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    • 제14권3호
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    • pp.358-364
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    • 2001
  • The physiochemical properties and interactions between porcine blood and waxy rice were determined. Addition of calcium chloride (0.15%) improved acceptability of blood cake and increased the gelatinization degree of waxy rice. The water-holding capacity of porcine blood gel (blood/water=60/40, v/v), extent of absorption and gelatinization of waxy rice, and scanning electron microscopy showed that blood protein matrix and waxy rice are competitors for holding water in the cooking procedure. Non-haem iron content increased linearly (R=0.95) when heating temperature rose. The presence of blood proteins caused increasing of peak temperature (Tp) of gelatinization in differential scanning calorimetric thermal gram, The microstnlcture of plasma proteins and haemoglobin appeared continuous changes, and interacted with surface of waxy rice flour in terms of network and mosaic form, respectively. The electrophoretic patterns revealed an interaction between plasma proteins and waxy rice glutelin and haemoglobin when heated could be found at temperatures above $60^{\circ}C$.

Statistical Approach for Corrosion Prediction Under Fuzzy Soil Environment

  • Kim, Mincheol;Inakazu, Toyono;Koizumi, Akira;Koo, Jayong
    • Environmental Engineering Research
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    • 제18권1호
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    • pp.37-43
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    • 2013
  • Water distribution pipes installed underground have potential risks of pipe failure and burst. After years of use, pipe walls tend to be corroded due to aggressive soil environments where they are located. The present study aims to assess the degree of external corrosion of a distribution pipe network. In situ data obtained through test pit excavation and direct sampling are carefully collated and assessed. A statistical approach is useful to predict severity of pipe corrosion at present and in future. First, criteria functions defined by discriminant function analysis are formulated to judge whether the pipes are seriously corroded. Data utilized in the analyses are those related to soil property, i.e., soil resistivity, pH, water content, and chloride ion. Secondly, corrosion factors that significantly affect pipe wall pitting (vertical) and spread (horizontal) on the pipe surface are identified with a view to quantifying a degree of the pipe corrosion. Finally, a most reliable model represented in the form of a multiple regression equation is developed for this purpose. From these analyses, it can be concluded that our proposed model is effective to predict the severity and rate of pipe corrosion utilizing selected factors that reflect the fuzzy soil environment.

질소 및 가리 급원이 들잔디(Zoysia japonica Steud.)의 생육 및 품질에 미치는 영향 (Effects of Nitrogen and Potassium Sources on the Growth and Quality of Zoysia japonica Steud.)

  • 황규성;이용범;한동욱
    • 아시안잔디학회지
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    • 제5권1호
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    • pp.1-10
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    • 1991
  • The purpose of the experiment was to determine the effect of nitrogen sources (urea, ammonium sulphate, ammonium nitrate) and potassium sources (potassium chloride, potassium sulphate) on the growth and quality of Zoysia japonica Steud. This experiment was conducted at Seoul City University turf field from 1988 to 1989. The results of this experiment were summarized as follows; 1. Urea and Ammonium sulphate resulted in superior clipping yield compared to ammonium nitrate. The growth of rhizome and stolon increased significantly with urea forms, but ammonium sulphate treated plots exhibited the highest the growth rate of root. 2. Ammonium sulphate showed best turf color rating while ammonium nitrate resulted in the poorest. Prolongation of the green period showed longer in ammonium sulphate and urea treated plots than ammoium nitrate. 3. Urea and ammonium sulphate exhibited superior visible quality and shoot density compared to ammonium nitrate. 4. The uptake of mineral nutrient showed the highest concentration with urea plots. Surface soil pH was allowed to become slightly acid with the ammonium sulphate and potassium sulphate treatments, while the application of N and K sources did not cause significant differences in mineral element content in soil.

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초음파 분무법으로 제조한 ZnO:Al 박막의 전기 및 광학적 특성 (The electrical and optical properties of ZnO:Al films Prepared by ultrasonic spray Pyrolysis)

  • Lee, Soo-Chul;Moon, Hyun-Yeol;Lee, In-Chan;Ma, Tae-Young
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 1999년도 하계종합학술대회 논문집
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    • pp.283-286
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    • 1999
  • Transparent conductive aluminum-doped ZnO(AZO) films Were prepared by a ultrasonic spray pyrolysis method at the substrate temperature below 23$0^{\circ}C$. A vertical type hot wall furnace was used as a reactor in the deposition system. Zinc acetate dissolved in methanol was selected as a precursor. The substrate temperature was varied from 18$0^{\circ}C$to 24$0^{\circ}C$. Aluminum (Al) was doped into ZnO films by incorporating anhydrous aluminum chloride (AlCl$_3$) in the zinc acetate solution. The proportion of the Al in the starting solution was varied from 0 wt % to 3.0 wt %. The crystallographic properties and surface morphologies of the films were analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The resistivity of the films was measured by the Van der Pauw method, and the mobility and carrier concentration were obtained through the Hall effect measurements Transmittance was measured in the visible region. The effects of substrate temperature and aluminum content in the starling solution on the structural and electrical properties of the AZO films are discussed

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Sulfur Polymer를 사용한 콘크리트 구조물용 내화학성 표면보호재의 성능 평가 (Efficiency Test for Surface Protecting Agents for the Chemical Resistance of Concrete Structures Using Sulfur Polymers)

  • 이병재;이의성;정우정;김윤용
    • 한국구조물진단유지관리공학회 논문집
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    • 제18권5호
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    • pp.1-8
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    • 2014
  • 본 연구에서는 유황을 폴리머화하여 내화학성능이 요구되는 구조물의 콘크리트 표면보호재로 활용할 수 있도록 성능을 검토하였다. 평가 결과, 유황폴리머 표면도포재의 중력식 스프레이가 적절한 것으로 나타났으며, 도포횟수는 왕복 3회 이상 도포했을 때 1MPa 이상의 부착강도 확보가 가능하였다. 표면보호재가 도포될 콘크리트 표면조건은 상온조건 ($20{\sim}30^{\circ}C$) 이상에서 높은 부착강도를 나타내었으며, 온도가 높을수록 부착강도가 증가하였다. 표면보호재의 채움재 혼입량에 따른 강도특성 평가결과, 20~40% 정도 혼입된 채움재는 유황폴리머의 수축을 저감시키는 효과를 나타내어 강도 향상에 기여하였다. 또한, 플라이애시 보다는 규사 혼입시 부착강도가 높았고, 동시 혼입시 가장 우수한 부착강도 특성을 나타내었다. 화학저항성은 플라이애시 및 규사를 각각 20% 대체한 배합에서 부착강도 저하가 최소로 되어 우수한 내화학성을 나타내었다. 염소이온 침투에 대한 성능평가를 수행한 결과, 표면보호재를 도포하지 않은 시험체에 비하여 유황폴리머 표면보호재를 도포한 경우, 29~48% 정도 염소이온침투저항성이 증대되었다. 표면보호재의 도포조건, 압축강도, 부착강도, 화학저항성, 염해저항성 등을 모두 고려하여 볼 때, 본 연구범위에서는 유황폴리머에 채움재로서 규사와 플라이애시를 각각 20%씩 대체하는 것이 적절한 수준인 것으로 판단된다.

콩을 이용한 치-즈제조에 관한 연구 (Studies on Preparation of a Cheese-like product from Soybean Milk)

  • 김창식;신효선
    • 한국식품과학회지
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    • 제3권1호
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    • pp.57-63
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    • 1971
  • 1. 5섯가지 젖산균을 대두유에 접종배양 하여 산 생성도를 비교 하였드니 Str. thermophilus 와 Str. diacetilactis가 Str. lactis, Str. cremoris 및 L. bulgaricus보다 높았다. 2. 대두유와 탈지 분유를 7 : 3의 비로 혼합하여 젖산균 발효를 하였을 때에 침전물의 수획량이 가장 많고 또한 그의 단백질 함량이 가장 많으며 수분의 량이 적고 견고한 curd를 만들수 있음을 알았다. 3. 대두유와 탈지분유를 7 : 3의 비로 혼합한 것에 젖산균 starter로 Str. thermophilus를 첨가하고 Pen. caseicolum을 접종하여 제조한 치-즈를 3주간 숙성$(15^{\circ}C,\;RH:\;85{\sim}90%)$ 하였드니 숙성 7일째부터 Pen. caseicolum의 생육이 왕성하게 되며 pH가 상승함과 동시에 proteolytic activity는 14일째에 최고치에 도달하였다, 또 total water soluble nitrogen, water soluble protein nitrogen 및 amino-N도 숙성 7일째부터 증가하기 시작하여 숙성 21일째는 이들의 값이 각각 total nitrogen의 52%, 32% 및 14%에 이르렀다. 그리고 이차원 paper chromatography에 의하여 3주간 숙성한 치-즈에서 17종의 아미노산을 검출 하였다. 또 3주간 숙성한 후 제품의 일반성분 조성은 수분 63.2%, 조단백질 17.5%, 조지방 13.2%, 조회분 2.8% 및 식염 2.5%였다.

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폴리머 시멘트 슬러리로 코팅한 도장철근의 내식성 평가 (Evaluations of Corrosion Resistance of Coated Steel Using Polymer Cement Slurry)

  • 조영국;김영집;소양섭
    • 콘크리트학회논문집
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    • 제15권1호
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    • pp.117-124
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    • 2003
  • 최근 강모래의 고갈로 인하여 해사의 사용이 증대되고 있는 실정에 있다. 그러나 해사는 철저하게 제염처리 하여 사용하지 않으면 철근 콘크리트 구조물의 철근에 막대한 영향을 미칠 수 있다. 본 연구에서는 제염처리하지 않은 해사를 시멘트 콘크리트에 직접 사용하여도 철근의 부식을 억제할 수 있는 방청재료를 개발하기 위한 연구의 일환으로서, 기존의 에폭시 철근과 비교하여 경제적이고 방식 성능면에서 우수한 재료로서 폴리머 시멘트 슬러리를 이용하고자 하였다. 각종 폴리머를 사용하고 여러 가지 부식촉진 실험을 통하여 도장하지 않은 철근과 도장한 철근과의 성능을 비교평가하였다. 연구결과, 폴리머 시멘트 슬러리로 도장한 철근은 도장하지 않은 철근에 비해 염화나트륨 수용액에 대한 침지 및 분무시험과 시멘트 콘크리트 속에서의 부식에 관한 실험에 있어서도 매우 우수한 방식성능을 발휘하였다. 다양한 부식촉진 실험결과, 철근의 부식은 염분, 중성화 및 촉진양생에 의해 크게 영향을 받으며, 복합적인 인자가 작용될 때, 더욱더 심한 부식이 발생하였다. 이러한 부식을 폴리머 시멘트 슬러리에 의한 도장으로 억제할 수 있는데, 폴리머 시멘트 슬러리의 매트릭스에 존재하는 폴리머 필림의 연속된 막에 의해 염화물 이온의 침투가 차단되었기 때문이며, 폴리머 시멘트 슬러리의 완벽한 방식효과는 도장두께로 조절할 수 있을 것이다.