• 제목/요약/키워드: chloride content

검색결과 849건 처리시간 0.026초

Curing Characteristics of Low Molar Ratio Urea-Formaldehyde Resins

  • Fan, Dongbin;Li, Jianzhang;Mao, An
    • 접착 및 계면
    • /
    • 제7권4호
    • /
    • pp.45-52
    • /
    • 2006
  • Five low molar ratio urea-formaldehyde (LUF) resins were synthesized in this study. The effects of molar ratio, free formaldehyde content, and catalysts on the curing characteristics of LUF resins were studied by measuring its free formaldehyde content, pH value change after catalysts added, curing rate, and pot life, observing its cured appearance, and analyzing its thermal behavior. The results indicate that: 1) The LUF resin with lower molar ratio than 1.0 can still cure; 2) Free formaldehyde content is not the main factor in affecting curing rate of LUF resin; 3) Compared with ammonium chloride as a traditional catalyst, persulfate salts markedly accelerate the curing rate of LUF resin, and result in the different appearance; 4) the addition of sodium chloride to catalysts can accelerate the curing rate of LUF resin, but the effect is moderate.

  • PDF

콘크리트의 동결융해 내구성에 공기량이 미치는 영향 분석 (Affecting Analysis of Air Content on the Freeze-Thaw Durability of Concrete)

  • 이병덕;김현중;강혜진
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
    • /
    • pp.565-568
    • /
    • 2008
  • 우리나라의 경우 매년 전국적으로 일평균기온이 0$^{\circ}C$이하로 되는 경우가 대부분이므로 거의 모든 지역의 콘크리트가 반복되는 동결융해의 피해를 입고 있다고 볼 수 있다. 이러한 동결융해의 반복에 대한 콘크리트의 내구성은 콘크리트의 공기량과 매우 관계가 깊다. 따라서, 현재 콘크리트의 동결융해에 대한 저항성을 향상시키기 위해 AE제 등을 사용하고 있으며 콘크리트의 기포간극계수를 $250{\mu}m$ 이하로 권장하고 있다. 외국의 경우도 마찬가지로 AE제 및 감수제에 관한 품질규격에서 기포간극계수를 캐나다의 경우 각각 $200{\mu}m$ 이하 및 $230{\mu}m$ 이하로 규정하고 있으며 일본학회에서도 기포간극계수 $250{\mu}m$ 이하가 적당하다고 보고되고 있다. 또한, 융설제와 동결융해의 복합작용에 의해 콘크리트의 스켈링 저항성을 향상시키는 데에도 일반 동해와 마찬가지로 공기량이 상당히 중요하다고 알려져 있다. 따라서, 반복되는 동결융해에 의한 동해를 동시에 받는 복합열화 환경하에 있는 일반콘크리트의 내구성에 크게 영향을 미치는 인자로 알려져 있는 공기량에 따른 동결융해 내구성을 알아보고자 Non AE(공기량 1.5%), AE(공기량 4.5%, 7.2%) 콘크리트를 통해 동결융해에 따른 상대동탄성계수와 중량감소율, 스켈링 저항성 및 공극특성을 비교검토 하였다.

  • PDF

0.1M $Na_2SO_4+ NaCl$ 수용액에서 마멸 전극 기법을 이용한 Fe-Cr강의 재부동태 특성 (Repassivation Characteristics of Fe-Cr Steels Using the Abrading Electrode Technique in Aqueous 0.1M $Na_2SO_4+ NaCl$ Solutions)

  • 함동호;이재봉
    • 전기화학회지
    • /
    • 제2권4호
    • /
    • pp.195-201
    • /
    • 1999
  • 탈기된 0.1 M $Na_2SO_4$ 수용액에서 Fe-Cr강의 재부동태 특성을 Cr함량, 인가전위 그리고 염소이온의 농도를 변화시키면서 관찰하였다. 염소이온이 없는 경우 재부동태 속도를 나타내는 식 log i=k-n log t에서 -n값은 Cr함량에 관계없이 -1에 수렴하였으나 Cr함량이 증가할수록 재부동태 전류밀도는 낮아졌다. A. C. impedance spectroscopy측정 결과, Cr 함량과 인가전위가 증가할수록 형성된 재부동태 피막의 charge transfer resistance$(R_{ct})$ 값은 상승하였다. 또한 재부동태 동안 흐르는 전류밀도를 Faraday식을 이용하여 피막의 두께를 계산해보면 Cr함량이 증가할수록 얇은 부동태 피막이 형성된다는 것을 알 수 있었다. 그러나 염소이온이 존재하는 경우, 염소이온이 Fe-Cr강의 재부동태를 방해하는 효과는 인가전위가 증가할수록 상승하였다.

Effects of added chlorides and their concentrations on growth and nitrate content in leaf lettuce(Lactuca sativa L.) in hydroponics.

  • Lee, Guang-Jae;Shin, Hyun-Man;Kim, Ki-Sik;Lee, Cheol-Hee;Kim, Jin-Han
    • Plant Resources
    • /
    • 제2권1호
    • /
    • pp.26-30
    • /
    • 1999
  • Nitrate in edible vegetables is converted to nitrite by nitrate reductase(NR) and/or bacteria in intestines. Nitrite and amino, in the intestine of some animals and human, bind to form nitrosamine, which is toxic and known as carcinogen. This study was carried out to examine the effect of added chlorides and their concentrations on growth, yield and nitrate content in leaf lettuce plants in hydroponics. Seeds of lettuce cv, "Samsunjokchukmyon" were planted on April 29, and seedlings were planted on June 2, and were cultured until July 5 in 1998. KCI and CaCl₂ were used as chloride source and their concentrations were 1, 2 and 4 me/L, respectively, in the lettuce standard nutrient solution for National Horticultural Research Institute(NHRI). Completely randomized design with 3 replications was used. Nitrate content and NR activity were measured 2 and 5 weeks after planting(WAP). The obtained results were summarized as the follows : Leaf weight per plant was difference from harvest dates and treatments, but total leaf weight was not significantly different among treatments. Number of leaves was higher in KCI 2 me/L, CaCl₂1 me/L and control at 2 WAP than the others, and was higher in KCI 1 me/L, and control at 3 WAP than others, and was higher in control at 5 WAP. Total number of harvested leaves was the highest in control with 14, which followed by KCI 2 me/L and CaCl₂1 me/L. Nitrate content was decreased by addition of chloride in nutrient solution. Nitrate content in the 3rd and 9th leaves was significantly decreased. NR activity was higher in control and CaCl₂ addition treatments, while KCI addition treatments reduced NR activity. However, no direct relationship with nitrate was observed. Growth characteristics such leaf length and leaf width were not significantly influenced by chloride addition.

  • PDF

청파활성분획이 허혈성 뇌손상에 미치는 실험적 연구 (Experimental Study of Fraction of Citri Reticulatae Viride Pericarpium extract on the Brain Damage in Cerebral Ischemia)

  • 노영호;정현우;이원석
    • 동의생리병리학회지
    • /
    • 제16권5호
    • /
    • pp.893-898
    • /
    • 2002
  • Citri Reticulatae Viride Pericarpium extract(CRVP) have been used in oriental medicine for many centuries as a therapeutic agent for smoothing the liver and regulating the circulation of qi, and promoting digestion and removing stagnated food. The effects of CRVP on the inhibition of brain damage in cerebral ischemia is not known. Therefore, this Study was designed to investigate the cerebral protective effects of CRVP on the transient cerebral ischemia using modern techniques, and further to provide the possibility of scientification of oriental medicine. The size of cerebral infarct size was measured by morphometry, and brain edema was measured by morphometry and brain water content determination. The results were a$ follows ; 1. Water fraction of CRVP was reduced infect area of rats brain slices which were subjected to a transient cerebral ischemia in a dose-dependent manner. 2. Methylene chloride fraction and hexane fraction of CRVP was significantly reduced infarct area of rats brain slices which were subjected to a transient cerebral ischemia in a dose-dependent manner. 3. Methylene chloride fraction and hexane fraction of CRVP was significantly reduced infarct volume of rats brain which was subjected to a transient cerebral ischemia in a dose-dependent manner. 4. Methylene Chloride fraction and hexane fraction of CRVP was significantly decreased brain edema induced by a transient cerebral ischemia in a dose-dependent manner. 5. Methylene chloride fraction and hexane fraction of CRVP was significantly decreased brain water content of rats which were subjected to a transient cerebral ischemia. It is suggested that CRVP has an anti-ischemic effect through the inhibition of brain damage in a transient cerebral ischemia, and that in future further development of main effective constituent in CRVP can provide a novel therapeutic strategy for cerebral ischemia.

상전이물질(PCM)과 Nylon 6를 이용한 Sheath/Core 형태의 복합섬유 제조, 물리적 특성 및 항균가공특성 연구 (Preparation, Physical Characteristics and Antibacterial Finishing of PCM/Nylon Fibers having Sheath/Core Structure)

  • 김학수;황지용;임상현;임정남;손영아
    • 한국염색가공학회지
    • /
    • 제26권4호
    • /
    • pp.311-321
    • /
    • 2014
  • In this study, Aftertreatment properties of PCM/Nylon sheath/core fabrics have been determined. Especially, the relationship between finishing property and content including of PCM ratio. Samples of PCM/Nylon fabrics were monitored, separately, with 2% o.w.f solutions of each of the berberine chloride, cetylpyridinium chloride(CPC), benzyldimethylhexadecyl ammonium chloride(BDHAC) and dodecyltrimetyl ammonium bromide(DTAB). Various temperatures and liquor ratio and pH conditions were also studied to optimize aftertreatment properties. Berberine chloride finished sample showed the good color fastness. Cetylpyridinium chloride(CPC) finished sample showed very effective antibacterial properties against Staphylococcus aureus and Klebsiella pneumoniae.

Effect of Cu Addition on the Properties of Duplex Stainless Steels

  • Hwangbo, D.;Yoo, Y.R.;Choi, S.H.;Choi, S.J.;Kim, Y.S.
    • Corrosion Science and Technology
    • /
    • 제21권4호
    • /
    • pp.273-281
    • /
    • 2022
  • The effect of addition of Cu on the localized corrosion performance of aged duplex stainless steel in chloride media has yet to be explained in a consistent manner, and there is some controversy in the literature regarding the composition of stainless steel and the experimental conditions (pH, temperature, chloride concentration, etc.) used. In this work, the effect of the addition of Cu on the microstructure, hardness, and corrosion resistance of duplex stainless steel in an acidic chloride or high concentration sulfuric acid solutions was investigated for annealed and aged alloys. The Cu addition of annealed duplex stainless steel strengthened the alloy and reduced the ferrite contents of the alloy, and it also increased the polarization behavior in chloride or sulfuric solutions, except for the case of a high potential in acidic chloride solution. However, the Cu addition of aged duplex stainless steel reduced the formation of harmful phases such as sigma and kai and increased the polarization behavior in acidic chloride or sulfuric solutions up to 0.8 wt% of the Cu content, after which it slightly decreased at 0.8 wt% Cu or more.

Effects of Relative Humidity and Temperature on the Transport of Chloride in the Concrete

  • Nam Jin-Gak;Hartt William H.;Kim Ki-Joon
    • 콘크리트학회논문집
    • /
    • 제17권5호
    • /
    • pp.821-828
    • /
    • 2005
  • To investigate the role of RH and temperature on the transport of chloride in the concrete, two groups of specimens were configured. For both groups, mix design was based on w/c=0.45, $400kg/m^3$ cement, $794kg/m^3$ fine aggregate and $858kg/m^3$ coarse aggregate. After specimen fabrication these were exposed to four different RH (35, 55, 75 and $95\%$ RH) and temperature (0, 20, 30 and $40^{\circ}C$) conditions. After 3 and 6 months $15\%$ NaCl exposure 5mm cores were taken. These cores were sliced and individual cores were ground to powder. In addition, to evaluate the effect of temperature on the chloride binding some powder samples were leached in the each of four temperature chambers. Chloride titration fur these was performed using FDOT acid titration method. Based upon the resultant data conclusions were reached regarding that 1) effective diffusion coefficient, $D_e$, increased with increasing exposure RH, suggesting that the size and number of water paths increased with elevated moisture content in the specimens, 2) $D_e$ increased with increasing temperature in the range of 0 to $40^{\circ}C$ possibly by elevated thermal activation of chloride ions and reduced chloride binding at higher temperature, 3) water soluble chloride concentration, $[Cl^-]_s$, increased with increasing temperature, and 4) chloride concentration profile for initially dry concrete specimens was higher than for the initially wet ones indicating pronounced capillary suction (sorption) occurred for the dry concrete specimens.

Solid SCR용 암모니아 저장물질인 Calcium Ammine Chloride의 합성방법 및 물질분석 연구 (A Study on Synthetic Method and Material Analysis of Calcium Ammine Chloride as Ammonia Transport Materials for Solid SCR)

  • 신종국;윤천석;김홍석
    • 한국자동차공학회논문집
    • /
    • 제23권2호
    • /
    • pp.199-207
    • /
    • 2015
  • Solid materials of ammonia sources with SCR have been considered for the application of lean NOx reduction in automobile industry, to overcome complex problems of liquid urea based SCR. These solid materials produce ammonia gas directly with proper heating and can be packaged by compact size, because of high volumetric ammonia density. Among ammonium salts and metal ammine chlorides, calcium ammine chloride was focused on this paper due to low decomposition temperature. In order to make calcium ammine chloride in lab-scale, simple reactor and glove box was designed and built with ammonium gas tank, regulator, and sensors. Basic test conditions of charging ammonia gas to anhydrous calcium chloride are chosen from equilibrium vapor pressure by Van't Hoff plot based on thermodynamic properties of materials. Synthetic method of calcium ammine chloride were studied for different durations, temperatures, and pressures with proper ammonia gas charged, as a respect of ammonia gas adsorption rate(%) from simple weight calculations which were confirmed by IC. Also, lab-made calcium ammine chloride were analyzed by TGA and DSC to clarify decomposition step in the equations of chemical reaction. To understand material characteristics for lab-made calcium ammine chloride, DA, XRD and FT-IR analysis were performed with published data of literature. From analytical results, water content in lab-made calcium ammine chloride can be discovered and new test procedures of water removal were proposed.

COD 분석시 염소이온의 간섭작용에 관한 연구 (A Suitable Dichromate Reflux Method for the Analysis of Chlorous Wastewater)

  • 김종규;김남천;민달기
    • 한국환경보건학회지
    • /
    • 제15권2호
    • /
    • pp.33-40
    • /
    • 1989
  • Dichromate reflux method for COD analysis is one of the useful and precise way to solve the organic content of the wastewater. But the standard procedure for COD is not entirely satisfactory for sample containing appreciable amounts of inhibiting substance, especially chloride ion. Under the conditions of the established test, a big disadvantage of the method is that dichromate oxidizes chloride quantitatively to chlorine. When it is necessary to use silver sulfate as a catalyst in the COD procedure, chloride must be removed before the addition of the catalyst. Silver sulfate and mecuric sulfate forms a precipitate of AgCl and HgCl$_{2}$ separately which is not completely oxidized during the test and, therefore, cannot be corrected for. So, we evaluate and compensate the amount of chloride oxidation in the absence of chemicals during the experimental procedure. Calculation of COD is made using the following reviced formula: real COD = tested COD - 0.2277Cl.

  • PDF