• 한국염색가공학회지
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• 제14권3호
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• pp.26-33
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• 2002

Dyeing properties and crosslinking effect of bifunctional reactive dyes on chitosan fiber were investigated to improve the stability of chitosan fiber against the mild acidic solution and the wet processing. Chitosan fibers were crosslinked with epichlorohydrin for comparing purpose, and dyed with C. I. Reactive Red 194, C. I. Reactive Blue 50, and the reactive dye having two $\alpha$-bromoacrylamide groups at various concentrations. The initial dyeing rates of reactive dyes are rapid and chitosan fibers absorb the relatively large amount of dyes. The chitosan fibers dyed with these dyes show the low degree of swelling and the low solubility in 1 % acetic acid solution and also represent the higher thermal stability The reactive dye with two $\alpha$-bromoacrylamide groups shows higher crosslinking effect than other dyes.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.529-529
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• 2012

Dispersion of carbon nanotubes in biocompatible media are of particular interest for diverse biomedical and nanomedicine applications. Various biomolecules and biopolymers such as DNA, proteins, poly L-lysine, starch, gelatin, steroid biosurfactants, and chitosan have shown capability for the effective dispersion of carbon nanotubes in water. Chitosan has demonstrated capacity for effective dispersion of single-walled carbon nanotubes (SWCNTs) in acidic medium and it also showed tendency to preferentially disperse smaller diameter nanotubes. Chemical functionalizations of chitosan enable its solubility in neutral pH water by reducing the intra and inter molecular hydrogen bonding. Herein, we present a neutral pH water soluble chitosan derivative, chitosan-hydroxyphenyl acetamide (CHPA), obtained by functionalizing the amino groups of chitosan with 4-hydroxyphenyl acetic acid, as an efficient biocompatible dispersant for debundling and solubilization of SWNTs in neutral aqueous solutions. Various process conditions for individual dispersion of SWCNTs are analyzed based on optical absorption and Raman spectroscopy.

• 통합자연과학논문집
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• 제4권4호
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• pp.323-331
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• 2011

In this study, ${\alpha}$-chlorosuccinic acid was synthesized through the reaction of maleic anhydride with HCl(g), (UV)250 nm~300 nm wavelength in presence of $CCl_4$. For the second reaction of N-(monochloro)succinic acid contained glucosamine derivatives(I) was accomplished by a modification of the general acylation using excess ${\alpha}$-chlorosuccinic anhydride in the presence of 2% acetic acid with methanol condition as a solvent at elevated temperature($70^{\circ}C$). We considered organic acid derivatives were useful especially for treatment for the cultivating porphyra.

• Fibers and Polymers
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• 제6권3호
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• pp.229-234
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• 2005

In this paper, chitosan was suggested for using as a replacement for sodium alginate in the pretreatment print paste for digital ink-jet printing for cotton fabric. Pretreatment print pastes prepared from the mixture of chitosan and acetic acid with the appropriate viscosity gave satisfactory prints on the cotton fabric. Chitosan-treated cotton fabrics were digitally ink-jet printed with four different colors and the color fastness rating of the printed fabrics was satisfactory. Experimental results revealed the possibility of pre-treating the cotton with chitosan to replace the sodium alginate normally present in the pretreatment print paste recipe.

• 한국염색가공학회지
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• 제31권4호
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• pp.258-267
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• 2019

Synthetic suede without PFCs(perfluorinated compounds) are followed by subsequent high temperature treatment. But migration fastness of synthetic suede may be reduced due to sublimation of disperse dyes that results from the high temperature treatment. Therefore, in this study, chitosan treatment was used to improve the migration fastness before polyurethane dipping process. Polyester fiber was treated with sodium hydroxide aqueous solution before chitosan processing. This samples treated with a chitosan concentration upto 0.5% were dyed and coated with PUD(polyurethane dispersion). The migration fastness was most improved at 0.35% application. This is presumably due to the fact that the chitosan may increase the dye-binding capability through intermolecular hydrogen bonding.

• 한국의류산업학회지
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• 제7권4호
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• pp.439-444
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• 2005

This article describes the change in the hand value of chitosan-crosslinked cotton fabrics. The chitosan-crosslinked cotton fabrics were manufactured by mercerizing process using epichlorohydrin(ECH), 2% aqueous acetic acid and 20% aqueous sodium hydroxide. It proposed that the crosslinking and mercerizing were performed with the mixture of four different molecular weight chitosan and ECH in a single step. Cotton fabrics were dipped in the mixed solution of chitosan and ECH, picked up by mangle roller, pre-dried at $130^{\circ}C$, mercerized and crosslinked in NaOH solution and finally washed and dried. Mechanical and physical properties of the chitosan crosslinked fabric were measured on concentration and molecular weight by Kawabata Evaluation System(KES) and other instruments. As the concentration of chitosan solution increased, LT, WT, B, 2HB were increased. WT, B, 2HB, MIU, SMD, $T_0$, $T_m$ were decreased when chitosan was depolymerized. On the other hand, RT was increased when chitosan was depolymerized.

• 한국염색가공학회지
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• 제15권3호
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• pp.146-153
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• 2003

This article describes the metal ions adsorption of chitosan fibers. The chitosan fibers were manufactured by wet spinning using 2% acetic acid as solvent, 10% aqueous sodium hydroxide as non solvent, and 4%chitosan solution as a solvent. The adsorption characteristics of chitosan fibers towards 100ppm solutions of various metal ions such as Cu(II), Cd(II), Cr(III), Hg(II) were examined at different pH value by ICP-Atomic Emission Spectrometer. The adhesiveness of metallic ions to the chitosan fiber were increased with the increase of pH and the decrease of denier. On the other hand, from pH4, chitosan fiber that is immersed in metal ion aqueous solution of Cu(II) and Cd(II) became homogeneous solution because is dissolved. The adhesiveness of metallic ions to chitosan fiber were found to increased in a sequence of Hg(II)> Cr(III)> Cu(II)> Cd(II). The antimicrobial characteristics of the chitosan fiber by adhered metal ions, virgin chitosan fiber, and cotton fiber were evaluated. The antimicrobial activity of the fibers were increased with the decrease of denier.

• 복식문화연구
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• 제17권3호
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• pp.424-430
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• 2009

Taegwondo uniforms need powerful durability in fabrics against friction and shock because of higher exercising power. Therefore, in this study we developed more comfortable Taegwondo uniform for functional fabrics(deodorization rate, antibacterial activity and static charge). Chitosan is a deacetylated product of chitin, has widely been used in the biomedical sector, food industry, and textile industry. For the purpose of this study, we used the chitosan, which was congenial to the human body. Then, we compared the differences between the chitosan treated fabrics and non treated fabrics of Taegwondo uniform(100% polyester, 65% polyester/35% cotton). Chitosan was dissolved in 1% acetic acid. Also, the fabrics were washed using distilled water. Afterward, its treatment with chitosan was completed by padding the sample to its wet pick-up at $80{\pm}5%$ and by heating $150^{\circ}$ for 3 minutes. The chitosan treated Taegwondo uniform was improved on deodorization rate than non treated uniform. And the chitosan treated Taegwondo uniform was improved remarkably the antibacterial activity in all samples. In the further researches, the static charge was reduced in chitosan treatment uniform.

• 한국의류산업학회지
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• 제6권5호
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• pp.660-666
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• 2004

This article describes the change of hand value of chitosan crosslinked cotton fabrics. The chitosan crosslinked cotton fabrics were manufactured by mercerizing process using epichlorohydrin(ECH) as crosslinkins agent, 2% aqueous acetic acid as a solvent of chitosan and ECH, and 20% aqueous sodium hydroxide as a mercerizing agent and crosslinking catalyst. Cotton fabrics were dipped in the mixed solution of chitosan and ECH, picked up by mangle, mercerized and crosslinked in NaOH solution, and finally wash and dry. Mechanical and physical properties of the chitosan crosslinked fabric were investigated using Kawabata Evaluation System(KES) and other instruments. Tensile energy and tensile strain were decreased with the increase of the concentration of chitosan. Tensile resilience, compression resilience bending rigidity, bending hysteresis, shear stiffness, shear hysteresis, coefficient of friction, geometrical roughness, compression linearity, compressional energy, and thickness were increased with the increase of the concentration of chitosan. On the other hand, bending rigidity, bending hysteresis, coefficient of friction, geometrical roughness, compressional resilience, and thickness were increased with the increase of the concentration of crosslinking agent(epichlorohydrin).

• 한국염색가공학회지
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• 제32권1호
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• pp.51-56
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• 2020

This study aims to pursue the multi-functional textile finishing method to detoxify chemical warfare agent by simply treating the well-known antimicrobial agent, chitosan, to cotton fabric. For this purpose, DFP(diisopropylfluorophosphate) was sele cted as a chemical warfare agent simulant and cotton fabric was treated with 0.5, 1.0, and 2wt% chitosan solution in 1wt% acetic acid. DFP decontamination properties of the chitosan treated cotton fabrics were evaluated and compared with the untreated cotton fabric. The chitosan treated cotton fabrics showed better DFP decontamination than the untreated cotton. Decontamination properties of the chitosan treated cotton fabrics improved with the increased chitosan solution used. Especially, the cotton fabrics treated with 2wt% chitosan solution showed 5 times more DFP decontamina tion than the untreated cotton fabrics. This suggested that the chitosan treated fabric has potential to be used as a material for protective clothing with chemical warfare agent detoxifying and antimicrobial properties.