• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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• pp.948-951
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• 2007

In order to improve the performance of LCD, chiral dopant is added to liquid crystal mixture. When we decide the rubbing direction, we must consider the rotation direction of liquid crystal molecules by chiral dopant. When the rotation direction of liquid crystal molecules caused by dielectric torque decided by rubbing direction and that decided by chiral dopant are coincided, the performance of LCD would be improved along to our initial cell design intentions.

• 한국전기전자재료학회논문지
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• 제21권5호
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• pp.474-480
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• 2008

In order to make full color cholesteric displays, color filter-less R, G, B sub-pixel structured cholesteric LC cells have been studied. To make R, G, B colors, UV induced pitch variant chiral dopant was added to cholesteric LC mixtures. The concentration of the photo-sensitive chiral dopant was adjusted so that the initial state showed blue color and the color was changed from blue to green and red with increase of UV irradiation to the cholesteric cells. To prevent the mixing of R, G, B reflective sub-pixel liquid crystals, separation walls were formed using negative photo resister in boundary area between sub-pixels, Through the optimization of the material concentrations and UV irradiation condition, vivid R, G, B colors were achieved.

• Bulletin of the Korean Chemical Society
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• 제16권6호
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• pp.489-492
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• 1995

A new synthetic route to chiral liquid crystal dopant, 4-[2-(7S-methylnonanyl)oxy-5-pyrimidinyl]phenyl(2S,3S)-2-chloro-3-methylpentanoate (1), starting from 4-nitrophenylacetic acid is described. The key intermediate methylthiopyrimidine compound (8) has been synthesized from 4-nitrophenylacetic acid by Vilsmyer-Haack reaction followed by the formation of pyrimidine ring, and then converted to chiral ester (1) by the replacement of nitro group by (2S,3S)-2-chloro-3-methylpentanoic acid 2 through the formation of diazonium salt.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 추계학술대회 논문집
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• pp.394-395
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• 2007

In order to make full color cholesteric displays, color filter-less R, G, B sub-pixel structured cholesteric LC cells have been studied. To make R, G, B colors, UV induced pitch variant chiral dopant was added to cholesteric LC mixtures. The concentration of the photo-sensitive chiral dopant was adjusted so that the initial state showed blue color and the color was changed from blue to green and red with increase of UV irradiation to the cholesteric cells. To prevent the mixing of R, G, B reflective sub-pixel liquid crystals, separation walls were formed using negative photo resister in boundary area between sub-pixels. Through the optimization of the material concentrations and UV irradiation condition, vivid R, G, B colors were achieved.

• 한국응용과학기술학회지
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• 제19권3호
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• pp.245-249
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• 2002

A (disk-like liquid crystal (DLC) monomer/liquid crystals(LCs)/chiral dopant/dichroic dye) composite was irradiated with ultraviolet (UV) light. The (DLC network/LCs/chiral dopant/dichroic dye) was formed in the homeotropically oriented smectic A(SA) phase by the surface orientation treatment and the electric field. A focal-conic texture exhibiting strong light scattering appeared in the heat-induced chiral nematic phase(N${\ast}$) of the composite upon heating. Thermo-recording in the composite system has been realized by using a He-Ne laser. The laser irradiation was induced the phase transitions from SA phase to chiral nematic(N${\ast}$) phase in the composite system.

• Journal of Information Display
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• 제5권3호
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• pp.8-13
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• 2004

We demonstrate a transflective liquid crystal display (LCD), doped with a chiral agent to produce a low helical twisting power, in a multimode configuration consisting of the homogeneous alignment and the hybrid alignment. The multimode transflective LCD with a single cell gap was fabricated using a single-step photoalignment technique with a self-masking process of an array of metal reflectors in the reflective region. In our configuration, the electro-optical disparity between the transmissive region and the reflective region was found to be significantly reduced by the low helical twisting power of the chiral dopant.

• 대한화학회지
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• 제59권5호
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• pp.423-428
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• 2015

(1S)-(+)-10-camphorsulfonic acid (CSA) and HCl were used together as a binary dopant in the electrodeposition of polyaniline (PAni). (+)-CSA and HCl were added in different mole ratios (9:1 and 6:4). (+)-CSA-doped and binary-doped PAni exhibited markedly different ultraviolet-visible and circular dichroism spectral characteristics due to differences in their conformations. Distinct helical structures are observed in the scanning electron microscopy images of (+)-CSA-doped PAni. The X-ray diffraction pattern of (+)-CSA-doped PAni exhibited remarkably higher crystallinity than that of HCl-doped PAni which is associated with the helical ordering along the polymer chains. The conformational changes due to the binary doping in chiral PAni had a significant effect on its chiroptical and electrochemical properties, morphology, and crystallinity, thus determined its conductivity.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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• pp.504-507
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• 2002

We investigated electro-optic and ionic properties of twisted nematic cells by using control of chiral pitch. These properties are observed in practical experiment and simulations. C-V and V-T curve characteristics were obtained from three types of cells with d/p. It is shown that d/p ratio of short cells exhibit faster response time improved by 20% than normal cell. Also, inter-gray response time is improved each rise time and decay time. And, the increase of saturation voltage is happened because of the small twist angel change from initial state at high voltage near 5V. To compensate for longer black level tail, gamma curve index was varied from g = 2.2 to g = 2.7 in module status. Additionally, adding chiral dopant into TN cells improved ionic characteristics such as increasing VHR, Ion density and DC Hysteresis were decreased..

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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• pp.105-108
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• 2005

We demonstrate an electro-optical device based on the flexoelectric effect of a short-pitched cholesteric liquid crystal. By using a dual-frequency switchable nematic, a small amount of chiral dopant and a small amount of phase-separated polymer localized on the surface, we were able to create a device that operates in amplitude (flexoelectric) and phase(dielectric) modes. At high frequency the dual frequency liquid crystal suppresses the phase mode at higher voltage, which improves the switching speed, and thereby preserving the in-plane-switching mode.

• 대한화학회지
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• 제58권5호
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• pp.456-462
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• 2014

(+)-Camphorsulfonic acid (CSA)와 hydrochloric acid (HCl)로 binary 도핑된 키랄 polyaniline (PAni)을 중합온도 $0^{\circ}C$와 상온(RT)에서 전기화학적 중합법으로 합성하였다. 순환전압전류 곡선, FT-IR과 circular dichroism spectra로부터 PAni는 각각 (+)-CSA와 HCl로 single 도핑된 PAni 혼합물이 아닌, binary 도핑된 키랄 PAni임을 확인하였다. 중합온도가 전기화학적 거동과 도핑레벨에 영향을 주었고, 이에 따라서 PAni의 결정성과 모폴로지가 변화되는 것을 확인하였다. 중합온도가 $0^{\circ}C$에서 RT로 상승됨에 따라 키랄PAni의 모폴로지가 fibrous에서 short-fibrous구조로 변화되었다. ITO 위에 적층된 PAni필름의 면저항을 4-point probe 법으로 측정하였다.