• Title/Summary/Keyword: chemical transportation

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Preliminary Economic Analysis for H2 Transportation Using Liquid Organic H2 Carrier to Enter H2 Economy Society in Korea (수소경제사회 실현을 위한 액체 유기 수소캐리어를 이용한 수소 수송 관련 예비 경제성 평가)

  • LEE, BOREUM;LEE, HYUNJUN;MOON, CHANGHWAN;MOON, SANGBONG;LIM, HANKWON
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.2
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    • pp.119-127
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    • 2019
  • Reliable $H_2$ supply is necessary for entering a $H_2$ society. Among the various $H_2$ storage and transportation methods, liquid organic $H_2$ carrier (LOHC) is in the spotlight because of a lot of advantages compared to conventional one such as compressed $H_2$ and liquefied $H_2$. Therefore, we performed preliminary economic analysis of $H_2$ supply cost using LOHC for a $H_2$ production capacity of $300Nm^3\;h^{-1}$ employing itemized cost estimation and sensitivity analysis to evaluate economic viability of this technology in Korea.

Current Situation on Biogas as a fuel for Vehicles (자동차용 연료로서 바이오가스의 현황 고찰)

  • Lee, Jin-Hui;Hwang, Won-Jun;Kim, Jae-Kon
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.740-753
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    • 2013
  • It is valuable research area regarding to developing manufacturing process of biogas from organic wastes take a side view of alternative for fossil energy and to improve the environmental atmosphere leads to decrease the greenhouse gas be discharged. The regulation which is prepared by environmental department shows that biogas as a transportation fuel is required to purity of above 95%, while it of natural gas is above 88%. However, in this situation it is necessary to prepare the regulation which is distributed by department of transportation as for the fuel be connected to vehicles as well in order to take step forward, and it is suggest to develop the technics of biogas this country's own original one, not be the technics imported from foreign countries, and also to turn to higher practical use of biogas for transportation area, since it shows far much less ratio have compared to other application areas.

Explosion Likelihood Investigation of Facility Using CVD Equipment Using SEMI S6 (SEMI S6를 적용한 CVD 설비의 폭발분위기 조성 가능성 분석)

  • Mi Jeong Lee;Dae Won Seo;Seong Hee Lee;Dong Geon Lee;Se Jong Bae;Jong-Bae Baek
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.62-67
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    • 2023
  • Due to the prolonged impact of COVID-19, the demand for Information Technology (IT) products is increasing, and their production facilities are expanded. Consequently, the use of harmful and dangerous chemicals are increased, the risk of fire(s) and explosion(s) is also elevated. In order to mitigate these risks, the government sets standards, such as KS C IEC 60079-10-1, and manages explosion-prone hazardous facilities where flammable substances are manufactured, used, and handled. However, using the standards of KS, it is difficult to predict the actual possibility of an explosion in a facility, because ventilation (an important factor) is not considered when setting up a hazardous work environment. In this study, the SEMI S6, Tracer Gas Test was applied to the chemical vapor deposition (CVD) facility, a major part of the display industry, to evaluate ventilation performance and to confirm the possibility of creating a less explosive environment. Based on the results, it was confirmed that the ventilation performance in the assumed scenarios met the standards stipulated in SEMI S6, along with supporting the possibility of creating a less explosive working condition. Therefore, it is recommended to use the prediction tool using engineering techniques, as well as KS standards, in such hazardous environments to prevent accidents and/or reduce economic burden following accidents.

Spent Fuel Processing Technologies for Waste Recycling (폐기물 재활용을 위한 사용후핵연료 처리기술)

  • Park, Byung Heung;Kim, Ki-Sub
    • Journal of Institute of Convergence Technology
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    • v.2 no.1
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    • pp.7-12
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    • 2012
  • Spent fuels are discharged from nuclear reactors as a result of power generations. The spent fuels would be considered as a useful resources because the main constituent is uranium and some other actinides are included in them. In order to utilize the resources chemical processes should be developed to treat the spent fuels and obtain uranium and other actinides to be fueled in a fast reactor. The technologies are categorized into wet and dry processes. In this study, the current status of such technologies is summarized to give a insight and a deep understanding on nuclear fuel cycles.

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A Study on the safety management condition and disaster reduction measures of plant construction projects -focusing on chemical engineering plants- (플랜트 건설 사업 안전관리 실태 및 재해 저감 방안 연구 -화공 플랜트를 중심으로-)

  • Kim, Seung-Han;Lee, SUNG-ll
    • Journal of the Korea Safety Management & Science
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    • v.19 no.4
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    • pp.87-94
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    • 2017
  • The purpose of this study is to provide basic data to help ensure the safety and enhance industrial competitiveness of plant construction projects by analyzing the safety management status of, mainly, chemical engineering plant construction projects, and proposing specific measures and models to reduce human/educational, technical/systemic, institutional disasters. This study was done using literature research and case study/empirical study methods. The results of this study are summarized as follows. First, we classified the major disasters from the quarterly released 'major diaster cases in construction business' from Korea Occupational Safety and Health Agency according to the type of construction and presented the causes and prevention measures.

Synthesis of Polyamine Grafted Chitosan Copolymer and Evaluation of Its Corrosion Inhibition Performance

  • Li, Heping;Li, Hui;Liu, Yi;Huang, Xiaohua
    • Journal of the Korean Chemical Society
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    • v.59 no.2
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    • pp.142-147
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    • 2015
  • Two new chitosan derivatives, polyamine grafted chitosan copolymers have been synthesized for corrosion protection of carbon steel in acidic medium. First, methyl acrylate graft chitosan copolymer (CS-MAA) was prepared by the reaction of chitosan (CS) and methyl acrylate (MAA) via the Michael addition reaction. Then, CS-MAA was reacted with ethylene diamine (EN) and triethylene tetramine (TN) respectively to synthesize ethylene diamine grafted chitosan copolymer (CS-MAA-EN) and triethylene tetramine grafted chitosan copolymer (CS-MAA-TN), and the structures were characterized by Fourier-transform infrared spectroscopy (FT-IR). At last, the corrosion inhibition activities on Q235 carbon steel were investigated by using gravimetric measurements, metallographic microscope, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements. The compounds CS-MAA-EN and CS-MAA-TN show an appreciable corrosion inhibition property against corrosion of Q235 carbon steel in 5% HCl solution at $25^{\circ}C$. It has been observed that CS-MAA-EN shows greater corrosion inhibition efficiency than CS-MAA-TN. The inhibition efficiency of CS-MAA-EN was close to 90% when the mass fraction concentration was 0.2%~0.3%; the inhibition efficiency of CS-MAA-TN was close to 85% when the mass fraction concentration was 0.02%. The present work provided very promising results in the preparation of green corrosion inhibitors.

Changes in th Chemical Components and Antioxidant Activity of Strawberry by Slow-released ClO2 Gas Gel-Pack during Storage (서방형 이산화염소 가스 젤팩을 이용한 딸기저장 중 주요 성분 및 항산화 활성의 변화)

  • Lee, Kyung-Haeng;Yoon, Ye-Ji;Lee, Bom;Bong, So-Jung;Kim, Hyun-Kyoung;Kwak, Il-Hwan;Kim, Hong-Gil
    • The Korean Journal of Food And Nutrition
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    • v.30 no.4
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    • pp.823-829
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    • 2017
  • To increase the shelf-life of strawberry, samples were treated with two gel packs containing slow-released chlorine dioxide ($ClO_2$) gas at 3~5 ppm for 6 days at room temperature and the changes in the major chemical components (ascorbic acid, polyphenols, flavonoids and anthocyanin) contents and antioxidative activities (DPPH, ABTS radical scavenging and metal chelating activity) were investigated. The content of ascorbic acid of control was 40.38 mg% and contained 35.67~44.75 mg% during 6 days. There was no tendency to increase or decrease during storage period. The contents of ascorbic acid of control and 3~5 ppm $ClO_2$ gas treated samples were not significantly different during storage period. The content of polyphenol compounds of initial stage was 111.23 mg% and contained 117.78~132.40 mg% during 6 days. The contents of polyphenol compounds of 3~5 ppm $ClO_2$ gas treated samples were 103.51~130.25 mg%. There were no significant different between them during storage. The flavonoids and anthocyanin contents were not different from the control during storage period regardless of 3~5 ppm $ClO_2$ gas treatment. Furthermore, antioxidative activities were not different among the control and $ClO_2$ gas treatments during storage.

Extraction Equilibrium of Acrylic Acid by Aqueous Two-Phase Systems Using Hydrophilic Ionic Liquids (친수성 이온성 액체를 이용한 수상이성분계에서의 아크릴산 추출 평형)

  • Lee, Yong Hwa;Lee, Woo Youn;Kim, Ki-Sub;Hong, Yeon Ki
    • Korean Chemical Engineering Research
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    • v.52 no.5
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    • pp.627-631
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    • 2014
  • As an effective method for extraction of acrylic acid, aqueous two-phase systems based on morpholinium ionic liquids were used in this study. Effects of the alkyl chain length of cation in morpholinium ionic liquids on phase diagram and extraction efficiencies were investigated. Experimental results show that aqueous two phase systems can be formed by adding appropriate amount of morpholinium ionic liquids to aqueous $K_2HPO_4$ solutions. It can be found that the ability of morpholinium ionic liquids for phase separation followed the order [HMMor][Br]>[OMMor][Br]>[BMMor][Br]>[EMMor][Br]. There was little difference between binodal curves of imidazolium ionic liquids and those of morpholinium ionic liquids. 50~90% of the extraction efficiency was observed for acrylic acid by aqueous two phase extraction of acrylic acid with morpholinium ionic liquids. It can be concluded that morpholinium ionic liquids/$K_2HPO_4$ were effective for aqueous two phases extraction of acrylic acid comparing to imidazolium ionic liquids/$K_2HPO_4$ systems because of their lower cost.

Development of Multimedia Exposure Model for PCBs

  • Park, Shinai;Han, Jee-Yeun;Park, Jongsei
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.05a
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    • pp.166-166
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    • 2003
  • In terms of the risk assessment, qualitative and quantitative informations are needed to estimate the exposures of environmental pollutants, which may be potentiality of risks, and those are the information about the changes caused by the chemical transportation among environmental media and transformation in environmental media by duration. The various fate mechanism of chemical is possible for estimation of chemical concentration in environmental media. Since there are limitations in measuring the change of chemical concentration within all medium according to the time period, estimating method through modeling are developed.

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