• Journal of the Korean Society of Safety
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• v.33 no.4
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• pp.8-14
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• 2018

In the industrial chemical process involving combustible materials, reliable safety data are required for design prevention, protection and mitigation measures. The accurate combustion properties are necessary to safely treatment, transportation and handling of flammable substances. The combustion parameters necessary for process safety are lower flash point, upper flash point, fire point, lower explosion limit(LEL), upper explosion limit(UEL)and autoignition temperature(AIT) etc.. However, the combustion properties suggested in the Material Safety Data Sheet (MSDS) are presented differently according to the literatures. In the chemical industries, tetralin which is widely used as a raw material of intermediate products, coating substances and rubber chemicals was selected. For safe handling of tetralin, the lower and flash point, the fire point, and the AIT were measured. The LEL and UEL of tetralin were calculated using the lower and upper flash point obtained in the experiment. The flash points of tetralin by using the Setaflash and Pensky-Martens closed-cup testers measured $70^{\circ}C$ and $76^{\circ}C$, respectively. The flash points of tetralin using the Tag and Cleveland open cup testers are measured $78^{\circ}C$ and $81^{\circ}C$, respectively. The AIT of the measured tetralin by the ASTM E659 apparatus was measured at $380^{\circ}C$. The LEL and UEL of tetralin measured by Setaflash closed-cup tester at $70^{\circ}C$ and $109^{\circ}C$ were calculated to be 1.02 vol% and 5.03 vol%, respectively. In this study, it was possible to predict the LEL and the UEL by using the lower and upper flash point of tetralin measured by Setasflash closed-cup tester. A new prediction method for the ignition delay time by the ignition temperature has been developed. It is possible to predict the ignition delay time at different ignition temperatures by the proposed model.

• Korean Chemical Engineering Research
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• v.57 no.1
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• pp.105-110
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• 2019

Effect of height on the size and shape of carbon nanotube (CNT) aggregates in the freeboard region of a bubbling fluidized bed ($0.15m\;i.d.{\times}2.6m\;high$) has been determined. Feret diameter and Heywood diameter of the CNT aggregates in the freeboard region of fluidized bed increased with increasing gas velocity. The average aggregate diameters and CNT particle number in the aggregates decreased with increasing of height in the freeboard. Aspect ratio increased as the location was closer to the surface of the dense phase, but decreased at the highest location. Solidity did not show any significant changes with height. The results showed the aggregates formation process is affected by the height in the freeboard. A correlation was proposed to predict the Heywood diameter of the CNT aggregates.

• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.438-443
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• 2019

A new measurement method is suggested to quantify the phosphate poisoning of cathodic Pt catalyst for HT-PEMFC. To do that, hydrogen peroxide was used as an indicator to reduce the error which has been occurred in conventional electrochemical measurement such as CV or ORR RDE with high concentration of phosphate ions. As a result, the current density induced from the reaction of hydrogen peroxide decomposition increased proportionally to the concentration of phosphate ion while the conventional methods show has a significant error with high concentration of phosphate ion. Thus, it is confirmed that the suggested way is superior to the conventional measurement method for the quantification of phosphate ion poisoning in an atmosphere similar to the actual operation condition of HT-PEMFC.

• International Journal of Concrete Structures and Materials
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• v.2 no.1
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• pp.21-25
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• 2008

Surface treatments act as a barrier between the environment and the concrete, preventing or retarding the entry of harmful substances and cutting off the transportation path into concrete. The effectiveness of a surface protection preventing the permeation depends on how close and strongly connected are the resin molecules. This work intends to contribute to a better understanding of the performance of protected concrete in chemically aggressive environments, by presenting results of ion diffusion and resistance to aggressive solutions of several hydrophobic agents and coatings used to protect concrete. Three different types of surface protections were tested: silicone hydrophobic agent, acrylic and epoxy coatings. The obtained results indicate that the overall performance of epoxy resin was better than the other selected types of protections.

• Journal of Institute of Convergence Technology
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• v.10 no.1
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• pp.31-36
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• 2020

The purpose of this study is to discuss how to introduce micro degree for innovation in convergence education in our university. To this end, the background of the introduction of micro and nano degrees and domestic and foreign applications were reviewed. The reason why the rate of students completing the multi-degree was low was that the credits required for graduation were higher than that of other domestic universities, and the difficulty of the courses offered in the convergence major did not match the students. In order to reduce the burden of students learning convergence subjects while acquiring new knowledge and skills, the introduction of a micro degree is considered to be an alternative to the current convergence education.

• Journal of the Korean Society of Marine Environment & Safety
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• v.8 no.1
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• pp.15-52
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• 2002

According to International Maritime Organization. more than 50% of cargoes transported by sea today can be regarded as dangerous or hazardous ones, mainly consisting of chemical cargoes in bulk, likely solid or liquid and other materials, such as gases and products for and of the oil refinery industry. 46% of total cargoes handled in ports of Korea in 1999. is said to be dangerous cargoes. These dangerous and hazardous cargoes are quite within a high realms of possibility of accidents, likely to be grave disaster. This paper reviews current risk management system for the dangerous and hazardous cargoes sea-transportation, mainly focusing on the prevailing regal regimes in both USA and Korea. And it aims to suggest some points for advancing the existing Korean system.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.30 no.11
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• pp.693-698
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• 2017

In this study, the thermal degradation properties of polyethylene terephthalate film has been examined by the capacitance, Tan ${\delta}$, thermography, FTIR, and SEM results at temperatures of $90{\sim}170^{\circ}C$ and frequencies of 0.3~3,000 kHz. It was found that the capacitance decreased with increasing thermal imaging temperature, probably caused by weakening of chemical bond with increasing temperature. Tan ${\delta}$ decreased upon increasing temperature from $90^{\circ}C$ to $170^{\circ}C$, probably due to the molecular motion of COOH radical or OH radical. The FT-IR measurement reveals that no structural change of the material occurs upon thermal radiation. The SEM measurement shows that the material is stabilized by thermal decomposition with increasing temperature; however, excessive thermal degradation obstructs the stabilization of the material.

• Journal of Institute of Convergence Technology
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• v.3 no.1
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• pp.9-14
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• 2013

Recently, the development of renewable energy sources in Mongolia has been needed due to climate change and air pollution in Ulaanbaatar as rapid economic growth. Biodiesel can be considered as an alternative fuel for petroleum based diesel in order to decrease air pollution in Ulaanbaatar because of its no emission of particle materials from internal combustion engine in automobile. Rapeseed oil having low cloud point and pour point was suggested as a promising raw material for biodiesel production in Mongolia. Considering high population density and severe air pollution by particle materials and SOx in Ulaanbaatar, prior supplying site of biodiesel in Mongolia was the capital region including Ulaanbaatar. In the production of biodiesel in Mongolia, adsorption process was a effective alternative to washing process for the removal of residual alkali catalyst and reactants due to long winter time in Mongolia. For the stable supply of biodiesel, subsidy and no tax policy is needed in the early stage of biodiesel supply in Mongolia.

• Environmental and Resource Economics Review
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• v.12 no.1
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• pp.91-120
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• 2003

This paper is intended to measure sectoral sustainabilities and inter-industry linkage effects of natural capital depletion of the Korean industries, and to analyze sources of their change over time using the familiar input-output model. The sustainability indicator that we are measuring in this paper is based on the so-called genuine saving concept proposed by the World Bank(1997). We accommodated the concept in the extended analytical framework of Proops et al.(1999) to analyze sectoral sustainabilities of the Korean industries. We decomposed sectoral sustainabilities so measured into their composing factors based on the decomposition method devised by Chung & Rhee (2001). According to our analysis, overall sustainability of the Korean industries has been declined since 1995. In heavy and chemical, transportation, and electricity sectors, their sustainabilities has been gotten worse. Among four major factors influencing the sustainability, change in GDP was the most important followed by changes in savings, industrial structures, and demand patterns.

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2003.05a
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• pp.207-212
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• 2003

The flash point are used to classify combustible liquids according to their relative flammability. The regulations for the safe handling, transportation, and storage of such substances are dependent on this classification, and the flash points are therefore of great important in the chemical industry.(omitted)