• Title/Summary/Keyword: chemical safety

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A Study on the Emission Changes in Reduction Chemical Substances in Korea (유해화학물질 배출량 변화에 관한 연구: 배출저감계획서 작성 대상물질 중심으로)

  • Im, JiYoung;Lee, MyeongJi;Kim, HyunJi;Ryu, JiSung;Yun, DaeSik;Jang, YongChul;Lee, ChungSoo
    • Journal of Environmental Health Sciences
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    • v.46 no.2
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    • pp.159-169
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    • 2020
  • Objectives: The purpose of this study was to investigate changes among the nine kinds of reduction chemical substances in Korea over the period of 2008-2017. We will define basic data for improving the management methods for reducing chemical substances. Methods: A survey of hazardous pollutant emissions for 2008-2017 was conducted through the pollutant Release and Transfer Register homepage. Nine kinds of designated reduction chemical substances (Benzene, Vinyl chloride, Trichloro ethylene, 1,3-butadiene, Dichloro methane, Tetrachloro ethylene, N,N-dimethylformamide, Acrylo nitrile, and Chloroform) provided the study subjects. The emission of hazardous chemicals and health effects used the National Health Statistics and Integrated Chemicals Information System (ICIS) as a reference. Results: Hazardous pollutant emissions increased by 1.2 times over the past decade, and nine types of reduction chemical substances increased by 1.6 times. By region, the emissions of reduction chemical substances over the last 10 years were in the order of Chungbuk, Gyeonggi, and Gyeongbuk. Emissions of Dichloro methane was the highest in Chungbuk and Gyeongbuk. N,N-dimethylformamide was the highest in Gyeonggi. Carcinogen pollutant emissions showed a tendency to increase continuously. In addition, group 1 carcinogen emissions showed a tendency to decrease. Conclusion: In the last decade, the amount of hazardous chemical emissions has been continuously increasing. Hazardous chemical emissions require facility improvement for continuous emissions reduction. More research on reduction of emissions is needed.

Subacute(13-week) Inhalation Toxicity Study of Methyl Acrylate in Rats (랫드를 이용한 Methyl Acrylate의 아급성(13주) 흡입독성 연구)

  • Han, Jeong Hee;Park, Sang Yong;Kang, Min Gu;Chung, Yong Hyun;Yang, Jung Sun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.22 no.4
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    • pp.316-328
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    • 2012
  • Objectives: This study was designed to provide the information regarding chemicals classification and health hazard by evaluating the toxicological effect through repeated inhalation exposure of methyl acrylate(MA) in Sprague-Dawley(SD) rat for 13 weeks. Methods: According to the notification with Ministry of Labor(No. 2009-68) and OECD Test Guideline 413, the rats were exposed to MA at concentration of 0, 56, 168, 280 ppm via whole body inhalation for 6 hours per day, 5 days per week, for 13 weeks. All animals were observed for mortality, morbidity and the change of body weight and food consumption were determined during the exposure period. Necropsy finding, organ weight, hematology, clinical biochemistry and histopathological examination following exposure were also performed. Results: There were no death and abnormal clinical signs relate to exposure MA. However, At 160 ppm and 280 ppm exposure groups, body weight and food consumption showed statistically significant decrease and histopathological changes in lung, trachea, nasal cavity, larynx were observed. Conclusions: MA was mainly affected respiratory tract. It is consequently provided to be classified as category 2(0.2 mg/L/6h < category 2 ${\leq}$ 1.0 mg/L/6h) for specific target organ toxicity following repeated exposure according to Standard for Classification and Labeling of Chemical Substance and Material Safety Data Sheet. The NOAEL(no observable adverse effect level) of MA was also determined to be lower than 56 ppm.

Model Development for Estimating Total Arsenic Contents with Chemical Properties and Extractable Heavy Metal Contents in Paddy Soils (논토양의 이화학적 특성 및 침출성 중금속 함량을 이용한 비소의 전함량 예측)

  • Lee, Jeong-Mi;Go, Woo-Ri;Kunhikrishnan, Anitha;Yoo, Ji-Hyock;Kim, Ji-Young;Kim, Doo-Ho;Kim, Won-Il
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.6
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    • pp.920-924
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    • 2012
  • This study was performed to estimate total contents of arsenic (As) by stepwise multiple-regression analysis using chemical properties and extractable contents of metal in paddy soil adjacent to abandoned mines. The soil was collected from paddies near abandoned mines. Soil pH, electrical conductively (EC), organic mater (OM), available phosphorus ($P_2O_5$), and exchangeable cations (Ca, K, Mg, Na) were measured. Total contents of As and extractable contents of metals were analyzed by ICP-OES. From stepwise analysis, it was showed that the contents of extractable As, available phosphorus, extractable Cu, exchangeable K, exchangeable Na, and organic mater significantly influenced the total contents of As in soil (p<0.001). The multiple linear regression models have been established as Log (Total-As) = 0.741 + 0.716 Log (extractable-As) - 0.734 Log (avail-$P_2O_5$) + 0.334 Log (extractable-Cu) + 0.186 Log (exchangeable-K) - 0.593 Log (exchangeable-Na) + 0.558 Log (OM). The estimated value in total contents of As was significantly correlated with the measured value in soil ($R^2$=0.84196, p<0.0001). This predictive model for estimating total As contents in paddy soil will be properly applied to the numerous datasets which were surveyed with extractable heavy metal contents based on Soil Environmental Conservation Act before 2010.

Evaluation of Skin & Eye Irritation of Plant Extracts, Neem and Sophora (유기농업자재 중 님과 고삼 추출물의 피부 및 안점막자극성)

  • Oh, Jin-A;Choi, Jin-Hee;Choe, Mi-Seon;Kim, Jin-Hyo;Paik, Min-Kyoung;Park, Kyung-Hun;You, Are-Sun;Lee, Je-Bong;Kim, Doo-Ho
    • The Korean Journal of Pesticide Science
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    • v.17 no.4
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    • pp.478-481
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    • 2013
  • This study was performed to evaluate the acute skin and eye irritation of plant extracts (neem and sophora) against rabbit. The result of skin irritation test indicated that neem extracts and sophora extracts were not irritant. For eye irritation test, the result showed no irritation for neem extracts. Sophora extracts have a severe eye irritation and the symptoms have been reduced to day 3. Thus, safety guidelines for agricultural workers is considered to be needed when sophora extracts is used as an organic agricultural materials.

A CASE STUDY OF ASBESTORSIS

  • Chung, Yong-Hyun;Chang, Hee-Kyung;Lee, Yong-Hwan;Kiyoshi Sakai;Naomi Hisanaga;Han, Jeong-Hee;Lee, Yong-Mook;Chung, Ho-Keun;Yu, Il-Je
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 1999.05a
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    • pp.72-72
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    • 1999
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Evaluation of Honeybee Acute Toxicity of Plant Extracts, Neem, Sophora and Derris (식물추출 유기농업자재 3종(님, 고삼, 데리스 추출물)의 꿀벌에 대한 독성평가)

  • Oh, Jin-A;Choi, Jin-Hee;Choe, Mi-Seon;Kim, Jin-Hyo;Paik, Min-Kyoung;Park, Kyung-Hun;Hong, Soon-Sung;Lee, Je-Bong;Kim, Doo-Ho
    • The Korean Journal of Pesticide Science
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    • v.17 no.4
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    • pp.473-477
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    • 2013
  • This study was performed to evaluate the acute contact and oral toxicity of plant extracts (neem, sophora and derris) against Honeybee (Apis mellifera L.). As a result of acute contact toxicity test, $LD_{50}$ of neem and derris extracts were more than 100 ${\mu}g/bee$ while $LD_{50}$ of sophora extracts were 1.7 ${\mu}g/bee$. In case of acute oral toxicity test, $LD_{50}$ of neem and derris extracts were more than 100 ${\mu}g/bee$ while $LD_{50}$ of sophora extracts were 1.7 and 0.3 ${\mu}g/bee$. In conclusion, it is evaluated that neem and derris extracts are practically nontoxic while sophora extracts are highly toxic.

A Study on the Variation of Hazardous Pollutant Emissions in Korea from 2006 to 2015 (2006~2015년 동안 국내 유해화학물질 배출량 변화에 관한 연구)

  • Im, JiYoung;Kim, HyunJi;Kim, MinSun;Lee, JiHo;Lee, SangMok;Lee, ChungSoo
    • Journal of Environmental Health Sciences
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    • v.44 no.1
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    • pp.15-23
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    • 2018
  • Objectives: The purpose of this study was to investigate the changes in hazardous pollutant emissions in Korea over the period of 2006-2015. Methods: A survey of hazardous pollutant emissions was conducted through the homepage for 2006-2015. The emission of hazardous chemicals and the health effect was examined using the Annual Report of Air Quality in Korea (2016) and National Health Statistics (2015) as references. Results: Hazardous pollutant emissions increased by 1.1 times over the past decade, and the circulation amount of chemicals was 15% compared to the previous year. $PM_{10}$ concentrations showed a tendency to decrease, but emissions have not declined. In addition, asthma and atopic dermatitis correlated with similar emissions, but allergic disease showed no connection. Conclusion: These results on hazardous pollutant emissions indicate that they have increased. However, no association between emissions and health effects was shown, so more research is needed.

Web-based Integrated Safety, Health and Environment Management System in Gas Industry (가스공정의 웹기반 통합 안전, 보건, 환경 관리시스템 (WISHE))

  • Yoon En Sup;Han Kyounghoon;Park Jeong Su;Jung Ki Taek;Kim Ku Hwoi;Shin Dongil
    • Journal of the Korean Institute of Gas
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    • v.8 no.1 s.22
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    • pp.48-55
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    • 2004
  • ln this paper, we showed Web-based Integrated Safety, Health and Environment management system(WISHE) in gas industry, which was inspired from the integrated gas safety management system. Using the object oriented information flow to analysis basic modules of safety, health and environment, we made web-based, which enables us to access system anywhere, integrated system and its modules that can meet various laws and rules. This system also can reduce man power and management cost.

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A Study on the Management System Integrated Safety$\cdot$Health and Environment in Chemical Industries (화학공장에서의 안전$\cdot$보건, 환경 통합체제 구축에 관한 연구)

  • Im Cha-Soon;Kim Sung-Bin;Kim Ky-Soo;Lim Dong-Ho;Baek Jong-Bae;Um Sung-In;Ko Jae Wook
    • Journal of the Korean Institute of Gas
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    • v.3 no.3 s.8
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    • pp.17-22
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    • 1999
  • This study established management system integrated Safety$\cdot$Health, Management System(SHMS) and Environment Management System(ISO 14000) which satisfy all the systems through analyzing the PSM, SMS, BS 8800 and ISRS. Also, this study presented the guideline model which can make regular document forms in the integrated Safety, Health and Environment Management System. Furthermore, integrating management system developed in this study can reduce the duplication and inefficiency of materials and human resources in chemical industries

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Analysis of Safety of the Chemical Facilities by Korea Risk Based-Inspection in the Petrochemical Plant (석유화학공장에서의 한국형 위험기반검사에 의한 화학설비의 안정성 평가)

  • Kim, Tae-Ok;Lee, Hern-Chang;Shin, Pyng-Sik;Choi, Byung-Nam;Jo, Ji-Hoon;Choi, Byung-Young;Park, Sung-Hoo;Kim, Hung-Kun
    • Journal of the Korean Society of Safety
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    • v.22 no.6
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    • pp.35-40
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    • 2007
  • As a way of improving the safety of the chemical facilities, the risk based-inspection(RBI) was executed for the facilities of the applied petrochemical plant using KS-RBI Ver. 3.0 program developed based on the API-581 based resource document(BRD). From an evaluation result of KS-RBI program, we could find the evaluation of the process safety management(PSM) for the applied plant, risk of the applied process, risk of static facilities and pipes, and the demage mechanism of the facilities. Also, we could suggest a proper inspection plan(frequency and method of inspection) using the calculated risk and the status of the facilities. Therefore, the applied plant could be achieved a reduced inspection cost by an extension of inspection frequency, improved productivity, improved reliability of the facilities, and a computerized history management.