• Journal of the Korean Society of Safety
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• v.33 no.5
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• pp.42-50
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• 2018

The Chemical Controls Act strictly regulates for the chemical companies to establish sufficient space between the liquid chemical tank and dike, but facilities already installed suffer from the space shortage between the tank and dike. Installing leakage preventing plates on the dike is considered as one of the economic solutions that can alleviate the space deficiency. However, there is no technical and reasonable criterion for the safety evaluation of the leakage preventing plate on the dike. In order to address this problem, we provide generalized and verified calculating equations that give maximum height and horizontal distance of leakage trajectories. Through the proposed equations, proper heights of the leakage preventing plates on the dike can be easily determined. In this study, new calculating methods are also developed to determine the impact force of the liquid to the leakage preventing plates. In addition, we performed the reactivity experiments between four corrosive liquid chemicals and two stainless steel materials that are candidate substances for the construction of the leakage preventing plate. The results of this study is expected to be applicable as a guideline in the design of safe dike and its leakage preventing plates.

• Environmental Analysis Health and Toxicology
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• v.24 no.1
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• pp.43-52
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• 2009

Fullerene의 유전독성을 평가하기 위하여 Chinese hamster유래의 난소유아세포(CHO-K1 cell)를 이용하여 직접법(-S9)과 대사활성화법(+S9 mix)의 염색체이상시험을 실시하였다. 시험물질은 1% CMC 나트륨염의 현탁액(1% CMC 용액)에 희석하여 조제하였다. 대사활성화를 시키지 않은 직접법의 염색체이상시험에서 24시간 투여군은 8단계의 농도(0.078, 0.156, 0.313, 0.625, 1.25, 2.5, 5, 10 mM)로 투여하여 실시하였다. 투여 농도 증가에 따른 염색체이상의 빈도가 증가하는 양상이 나타나지 않았다. 48시간의 투여군에서는 8단계의 농도(0.078, 0.156, 0.313, 0.625, 1.25, 2.5, 5, 10 mM)로 투여하여 실시하였는데 투여 농도 증가에 따른 염색체이상의 빈도가 증가하는 양상이 나타나지 않았다. 배수체의 염색체이상은 직접법에서 관찰되지 않았다. 대사활성화법을 이용하여 6시간 시험물질을 투여한 시험에 있어서는 8단계의 용량단계(0.078, 0.156, 0.313, 0.625, 1.25, 2.5, 5, 10mM)를 설정하였는데 투여 농도가 증가함에 따른 염색체이상빈도의 증가양상이 관찰되지 않았다. 이상의 결과를 종합할 때 본 시험물질은 본 시험 조건하에서 CHO-K1세포에서 대사활성화를 시켰을 때 염색체이상을 유발하지 않는 것으로 판단된다.

• Journal of the Korea Safety Management & Science
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• v.16 no.3
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• pp.63-70
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• 2014

There has been an increase in fire/explosion accidents caused by chemical substances used in new small/medium sized construction, reconstruction, or extension sites. There is vast room for improvement, especially in safety training, safety inspection, and selection of countermeasures because training, technicality, and management systems regarding fire/explosion risks in small/medium sized construction sites are very immature in most cases. The purpose of this study is to propose a differentiated technical, educational, and management application plan for preventative management of fire/explosion accidents caused by chemical substances used in small/medium sized construction sites.

• Journal of the Korean Society of Safety
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• v.31 no.4
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• pp.27-34
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• 2016

Process Safety Management (PSM) system was introduced since 1996 and it makes voluntarily organizing and managing chemical accident prevention system by company itself that contributes to reduce the chemical accidents. However, large or small scaled chemical accidents had occurred frequently in these days. This trend is brought up the necessity to analyze and improve PSM system. In this study, it was conducted by the questionnaire survey and workshop for prevention of major industrial accidents in PSM sites in order to collect extensive opinions from all walks of life and identify overall operation condition. It was proposed to establish improvement plan of implementing condition assessment in PSM system. By results of the study, company's voluntary safety management will be induced by improved PSM system and management plan and it expects to prevent the major industrial accidents.

• Journal of Environmental Health Sciences
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• v.31 no.5 s.86
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• pp.365-371
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• 2005

This study was peformed to explore the current situation of university environmental health and safety (EHS) system and evaluate the effects of such system on university EHS practices. Essential elements for the university EHS system were identified based on the representative examples of foreign universities, and Hey were incorporated into a questionnaire, which was used in this study. Among the academic institutions we surveyed in this study, 89% of the universities employed health and safety manager, and 65% kept departments. However, less than 50% of universities maintained EHS policies, maintained health and established safety committees within the university headquarters, and held health and safety meetings on regular basis. Several basic requirements such as chemical hygiene program and laboratory safety training program lacked in many universities. Some basic surveillance was performed in many universities, however, only few universities carried out surveillance on biological safety, medical examination, and chemical exposure monitoring. EHS system had significant influence on university EHS program (p<0.05). Performances of EHS activities were influenced by presence of EHS policies, and university health and safety committees.

• Journal of the Korean Institute of Gas
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• v.22 no.3
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• pp.38-44
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• 2018

Ammonia is used primarily as a refrigerant in refrigeration facility and SCR of a plant, and is frequently involved in leakage accidents. This study was conducted by selecting ammonia, a material with a wide influence range when evaluated, as a material with higher vapor pressure and lighter than air. In this study, the influence ranges were computed using KORA(Korea Off-site Risk Assessment supporting tool) with four different environmental factors : ground roughness, sealing, operating temperature, pressure, and leakage hole size. As a result, the difference in the influence range of ground roughness is approximately 4.62 times, while the ammonia storage tank shows a difference in the reduction rate of 0.64 when sealed. The extent of impact increased with increasing leakage depending on storage temperature and pressure, and when storing higher than the saturation vapor pressure, the impact range showed an average growth rate of 3.45 % per 0.1 Mpa($45^{\circ}C$). The influence ranges based on the size of the leakage holes is shown to be proportional to the area of the leakage zone.

• Korean Chemical Engineering Research
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• v.49 no.1
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• pp.41-46
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• 2011

We investigated experimentally the properties of dust explosion through lycopodium particle clouds in a duct to provide the fundamental knowledge. Propagating dust flames in the vertical duct of 120 cm height and 12 cm square cross-section were observed by digital video camera and flame front is visualized using by PIV(Particle Image Velocimetry) system. As the result, when the same average dust concentration existed in the vertical duct, downward flame propagation was faster than the upward flame propagation, its rate increased with dust concentration in 300g/$m^3$. Post flames were caused by the ignition of unburned particles which flowed into the rear region of flame from passage between flame and duct wall, and they generated regardless of duct condition. Also, it was found that appearance frequency of post flames during dust flame propagations increased with the increase of dust concentration.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.1
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• pp.38-47
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• 2011

This study focused on health risk assessment via multi-routes of As exposure to establish a target cleanup level (TCL) in abandoned mines. Soil, ground water, and rice samples were collected near ten abandoned mines in November 2009. The As contaminations measured in all samples were used for determining the probabilistic health risk by Monte-Carlo simulation techniques. The human exposure to As compound was attributed to ground water ingestion. Cancer risk probability (R) via ground water and rice intake exceeded the acceptable risk range of $10^{-6}{\sim}10^{-4}$ in all selected mines. In particular, the MB mine showed the higher R value than other mines. The non-carcinogenic effects, estimated by comparing the average As exposure with corresponding reference dose were determined by hazard quotient (HQ) values, which were less than 1.0 via ground water and rice intake in SD, NS, and MB mines. This implied that the non-carcinogenic toxic effects, due to this exposure pathway had a greater possibility to occur than those in other mines. Besides, hazard index (HI) values, representing overall toxic effects by summed the HQ values were also greater than 1.0 in SD, NS, JA, and IA mines. This revealed that non-carcinogenic toxic effects were generally occurred. The As contaminants in all selected mines exceeded the TCL values for target cancer risk ($10^{-6}$) through ground water ingestion and rice intake. However, the As level in soil was greater than TCL value for target cancer risk via inadvertent soil ingestion pathway, except for KK mine. In TCL values for target hazard quotient (THQ), the As contaminants in soil did not exceed such TCL value. On the contrary, the As levels in ground water and polished rice in SD, NS, IA, and MB mines were also beyond the TCL values via ground water and rice intake. This study concluded that the health risks through ground water and rice intake were greater than those though soil inadvertent ingestion and dermal contact. In addition, it suggests that the abandoned mines to exceed the risk-based TCL values are carefully necessary to monitor for soil remediation.

• Journal of Environmental Health Sciences
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• v.44 no.2
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• pp.160-168
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• 2018

Objectives: The purposes of the study were to investigate hazardous pollutant emissions changes among group 1 carcinogens. The emissions characteristics were compared with national cancer registration statistics. Methods: A survey of group 1 carcinogen hazardous pollutant emissions (trichloroethylene, benzene, vinyl chloride, formaldehyde, 1,3-butadiene, ethylene oxide, chromium and its compounds, 3,3'-dichloro-4,4-diaminodiphenylmethane, chloromethyl methyl ether, arsenic and its compounds, cadmium and its compounds, o-toluidine) was conducted through a homepage for 2001-2015. The emission of hazardous chemicals and the cancer trend analysis for 2001-2015 were performed using the Korean statistical information service through its homepage as a reference. Results: Emissions of more than 95% of the substances listed as group 1 carcinogens over the last five years were made up of trichloroethylene, benzene, vinyl chloride, formaldehyde, 1,3-butadiene, and ethylene oxide. As a result of the comparison of emission results and cancer incidence rates, carcinogen pollutant emissions showed a tendency to decrease continuously. In addition, the incidence of cancer tended to increase, but showed a tendency to decrease from 2012. Conclusion: The results indicate hazardous pollutant emissions have continued to increase. However, no association between emissions and health effects was shown and more research is needed.

• Korean Journal of Soil Science and Fertilizer
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• v.49 no.6
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• pp.651-654
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• 2016

A number of accidents relating to highly toxic hydrogen fluoride (HF) or hydrofluoric acid (HA) release have occurred over fast few decades in Korea. Thus, this study was conducted to investigate the fluoride (F) concentrations in paddy soil and brown rice from 2 different areas where the soils were exposed to HF and HA. In the first case, the HF leakage accident that occurred in 2012 affected the surrounding soils and crops and consequently, crops (rice) affected by HF were unavailable for forage even though F did not accumulate in the soil. For example, at the time of accident, F concentrations in brown rice samples were $33.0-1,395mg\;kg^{-1}$, while F concentrations in soil samples were $155-295mg\;kg^{-1}$ which were less than the Korean standard guideline values of $400mg\;kg^{-1}$. However, after a year, F concentrations in brown rice were observed below the detection limit ($1mg\;kg^{-1}$), although F concentrations in soils were similar with those in 2012. Also, large amounts of wastewater discharges containing HA occurred in 2013 and some agricultural soils exceeded the Korean standard guideline values for F ($400mg\;kg^{-1}$), but soil-plant F transfer was not observed. In conclusion, it was observed that soil to plant transfer of F is unlikely although HF and HA as gas or liquid form can cause direct damage to plants.