• Title/Summary/Keyword: chemical regime

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Simulation Study of NOx Dispersion from Power Plant Stack Gas (화력발전소 배출가스 중 질소산화물의 확산에 관한 연구)

  • Park, Mi-Jeong;Jo, Young-Min;Sung, Doo-Yong;Kim, Mi-Jeong;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.3
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    • pp.540-550
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    • 2013
  • Various efforts have been explored to save the cost in many industrial fields. In order to recover the residual thermal energy from the flue gas, an extreme high efficiency heat exchanger is planning to install at a power plant. The gas temperature will be reduced to $40^{\circ}C$ from $115^{\circ}C$. Thus gas buoyancy decreases, and dispersion of nitrogen oxides is expected to deteriorate as increasing relative humidity. In this study, the conversion of nitrogen monoxide to nitrogen dioxide and dispersion regime are investigated through computational modeling. Nitrogen dioxide which indicates 0.1 ppm at 85 m from the ground could be propagated to 620 m at $115^{\circ}C$ of the flue gas, whilst when cooled down to $40^{\circ}C$, it expands up to 750 m. The ground level influence area showed more expansion of dispersion, approximately to 930 m.

Numerical study on extinction and acoustic response of diluted hydrogen-air diffusion flames with detailed and reduced chemistry (상세 및 축소 반응 메커니즘을 이용한 희석된 수소-공기 확산화염의 소염과 음향파 응답 특성에 관한 수치해석)

  • Son, Chae-Hun;Jeong, Seok-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.11
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    • pp.1527-1537
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    • 1997
  • Extinction characteristics and acoustic response of hydrogen-air diffusion flames at various pressures are numerically studied by employing counterflow diffusion flame as a model flamelet in turbulent flames in combustion chambers. The numerical results show that extinction strain rate increases linearly with pressure and then decreases, and increases again at high pressures. Thus, flames are classified into three pressure regimes. Such nonmonotonic behavior is caused by the change in chemical kinetic behavior as pressure rises. The investigation of acoustic-pressure response in each regime, for better understanding of combustion instability, shows different characteristics depending on pressure. At low pressures, pressure-rise causes the increase in flame temperature and chain branching/recombination reaction rates, resulting in increased heat release. Therefore, amplification in pressure oscillation is predicted. Similar phenomena are predicted at high pressures. At moderate pressures, weak amplification is predicted since flame temperature and chain branching reaction rate decreases as pressure rises. This acoustic response can be predicted properly only with detailed chemistry or proper reduced chemistry.

High rate deposition and mechanical properties of SiOx film on PET and PC polymers by PECVD with the dual frequencies UHF and HF at low temperature

  • Jin, Su-B.;Choi, Yoon-S.;Choi, In-S.;Han, Jeon-G.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.180-180
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    • 2010
  • The design and implementation of high rate deposition process and anti-scratch property of silicon oxide film by PECVD with UHF power were investigated according to the effect of UHF input power with HF bias. New regime of high rate deposition of SiOx films by hybrid plasma process was investigated. The dissociation of OMCTS (C8H24Si4O4) precursor was controlled by plasma processes. SiOx films were deposited on polyethylene terephthalate (PET) and polycarbonate substrate by plasma enhanced chemical vapor deposition (PECVD) using OMCTS with oxygen carrier gas. As the input energy increased, the deposition rate of SiOx film increased. The plasma diagnostics were performed by optical emission spectrometry. The deposition rate was characterized by alpha-step. The mechanical properties of the coatings were examined by nano-indenter and pencil hardness, respectively. The deposition rate of the SiOx films could be controlled by the appropriate intensity of excited neutrals, ionized atoms and UHF input power with HF bias at room temperature, as well as the dissociation of OMCTS.

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Structural Changes during Oxidation Process of Anisotopic Mesophase Carbon Fibers(II)-Surface Texture Observation by Scanning Electron Microscopy (산화반응에 의한 이방성 메조페이스 탄소섬유의 구조 변화(II)-주사전자현미경을 이용한 표면구조 관찰)

  • Roh, J.S.
    • Korean Journal of Materials Research
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    • v.13 no.12
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    • pp.831-838
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    • 2003
  • Anisotropic mesophase carbon fiber(AMCFs) was exposed to isothermal oxidation in air and $CO_2$atmosphere, and burn-off rates have measured by TGA. The microstructure changes of oxidized carbon fibers, were observed by SEM. It was observed that oxidation rate in the air is over 100 times faster than that in $CO_2$atmosphere. The activation energy obtained in air was about 43.4 Kcal/mole in the temperature range of $600∼800^{\circ}C$, and in $CO_2$was about 55.2 Kcal/mole in the temperature range of $950∼1200^{\circ}C$. Therefore, the oxidation reaction in both atmospheres was under chemical reaction regime in the above temperature ranges. It was shown that the oxidation of the AMCFs is initiated at the end of fibers at high temperature($1100^{\circ}C$) with developing the large pores, and the small pores are developed on the fiber surface at low temperature($900^{\circ}C$). In conclusion, the oxidation of the AMCFs is progressed through the imperfection.

Longitudinal and Vertical Variations of Long-term Water Quality along with Annual Patterns in Daecheong Reservoir

  • Lee, Sang-Jae;Shin, Jae-Ki;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.43 no.2
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    • pp.199-211
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    • 2010
  • The objectives for this study were to evaluate spatial and temporal characteristics of water quality, based on long-term water quality monitoring data during 1993~2008. We found that physico-chemical and ecological conditions in the Daecheong Reservoir (DR) were modified by the construction of upper dam (i.e., Yongdam Reservoir). total phosphorus (TP), Secchi depth (SD), and chlorophyll-a (CHL) in the DR showed significant longitudinal decreases along the headwater-to-the downlake, indicating a large spatial variation, and this gradient was more intensified during the high-flow season (monsoon). Nutrient-rich water containing high nitrogen and phosphorus in the monsoon season (July~August) passed through the reservoir as a density current in the metalimnetic depth, and also high suspended solids increased in the metalimnetic depth, especially during the monsoon. According to the deviation analysis of Trophic State Index (TSI), >50% of TSI (CHL)-TSI (SD) and TSI (CHL)-TSI (TP) values were negatives, so that inorganic suspended solids (non-votatile solids) influenced the underwater light regime against phytoplankton growth. Also, ratios of CHL:TP after the dam construction evidently increased, compared to the values before the upper dam constructions, indicating a greater yield of phytoplankton in the unit phosphorus. Overall data showed that ecological and functional changes in Daecheong Reservoir occurred after the construction of upper dam (Yongdam Reservoir).

The evolution characteristics of incipient soot particles in ethylene/air inverse diffusion flame (에틸렌/공기 역확산 화염에서의 초기 매연 입자의 성장 특성)

  • Oh, Kwang-Chul;Lee, Uen-Do;Shin, Hyun-Dong;Lee, Eui-Ju
    • Journal of the Korean Society of Combustion
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    • v.9 no.2
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    • pp.38-44
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    • 2004
  • The evolution of incipient soot particles has been examined by high resolution electron microscopy (HRTEM) and elemental analyzer in ethylene-air inverse diffusion flames. Laser Induced Incandescence(LII) and laser scattering methods were introduced for examining the soot volume fraction and morphological properties in combustion generated soot qualitatively. Soot particles, collected by thermophoretic sampling, were analyzed by using HRTEM to examine the nano structure of precursor particles. HRTEM micrographs apparently reveal a transformation of condensed phase of semitransparent tar-like material into precursor particles with relatively distinct boundary and crystalline which looks like regular layer structures. During this evolution histories, C/H analysis was also performed to estimate the chemical evolution of precursor particles. The changes of C/H ratio of soot particles with respect to residence time can be divided into two parts: one is a very slowly increasing regime where tar-like materials are transformed into precursor particles (inception process) the other is an increasing region with constant rate where surface growth affects the increase of C/H ratio dominantly (surface growth process). These results provide a clear picture of a transition to mature soot from precursor materials.

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Bifurcation analysis of over-consolidated clays in different stress paths and drainage conditions

  • Sun, De'an;Chen, Liwen;Zhang, Junran;Zhou, Annan
    • Geomechanics and Engineering
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    • v.9 no.5
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    • pp.669-685
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    • 2015
  • A three-dimensional elastoplastic constitutive model, also known as a UH model (Yao et al. 2009), was developed to describe the stress-strain relationship for normally consolidated and over-consolidated soils. In this paper, an acoustic tensor and discriminator of bifurcation for the UH model are derived for the strain localization of saturated clays under undrained and fully and partially drained conditions. Analytical analysis is performed to illustrate the points of bifurcation for the UH model with different three-dimensional stress paths. Numerical analyses of cubic specimens for the bifurcation of saturated clays under undrained and fully and partially drained conditions are conducted using ABAQUS with the UH model. Analytical and numerical analyses show the similar bifurcation behaviour of overconsolidated clays in three-dimensional stress states and various drainage conditions. The results of analytical and numerical analyses show that (1) the occurrence of bifurcation is dependent on the stress path and drainage condition; and (2) bifurcation can appear in either a strain-hardening or strain-softening regime.

Investigation of Temperature-Dependent Microscopic Morphological Variation of PEEK Powder for a 3D Printer using Dissipative Particle and Molecular Dynamics Simulations (소산입자동역학과 분자동역학을 이용한 3D 프린터용 PEEK 분말에 대한 온도에 따른 미시적 구조변화에 대한 연구)

  • Kim, Namwon;Yi, Taeil
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.5
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    • pp.117-122
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    • 2018
  • 3D printing technology and its applications have grown rapidly in academia and industry. We consider a 3D printing system designed for the selective laser sintering (SLS) method, which is one of the powder bed fusion (PBF) techniques to build up the final product by layering sintered powder slices. Thermal distortion of printing products is a critical challenge in 3D printing. This study investigates temperature-dependent conformational behaviors of 3D printed samples of sintered poly-ether-ether-ketone (PEEK) powders using molecular dynamics simulations. The wear and chemical resistance properties of PEEK are understood, as it is a well-known biocompatible material used for implants. However, studies on physical phenomena at nanoscale in PEEK are rarely published in public. We simulate dissipative particle dynamics to elucidate how a cavity regime forms in PEEK at different system temperatures. We demonstrate how PEEK structures deform subject to the system temperature distribution.

The Identification of Limiting Nutrients Using Algal Bioassay Experiments (ABEs) in Boryeong Reservoir after the Construction of Water Tunnel

  • Ku, Yeonah;Lim, Byung Jin;Yoon, Jo-Hee;Lee, Sang-Jae;An, Kwang-Guk
    • Korean Journal of Environmental Biology
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    • v.36 no.4
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    • pp.558-566
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    • 2018
  • The objective of the study was to determine nutrition regime and limitation in the Boryeng Reservoir where there's a water tunnel between Geum River and the reservoir. Evaluation was conducted through in situ algal bioassay experiments (in situ ABEs) using the cubitainer setting in the reservoirs. For in situ ABEs, we compared and analyzed variations in chlorophyll-a (CHL-a) and phosphorus concentrations in Boryeong Reservoir before and after the water tunnel construction. We then analyzed the nutrient effects on the reservoir. Analysis for nitrogen and phosphorus was done in the three locations of the reservoir and two locations of the ABEs. The in situ ABEs results showed that phosphorous and Nitrogen, the primary limiting nutrient regulating the algal biomass was not limited in the system. The treatments of phosphorus or simultaneous treatments of N+P showed greater algal growth than in the control of nitrate-treatments, indicating a phosphorus deficiency on the phytoplankton growth in the system. The water from the Geum River had 5 times higher total phosphorus (TP) than the water in the reservoir. Efficient management is required as pumping of the river water from Geum River may accelerate the eutrophication of the reservoir.

Effects of Simulated Acid Rain on Growth and Contents of Chemical Substances in Needles of Pinus koraiensis Seedlings and on Chemical Properties of the Tested Soil (인공산성우(人工酸性雨)가 잣나무 유묘(幼苗)의 생장(生長), 엽내함유성분(葉內含有成分) 및 토양(土壤)의 화학적(化學的) 성질(性質)에 미치는 영향(影響))

  • Cheong, Yong Moon
    • Journal of Korean Society of Forest Science
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    • v.76 no.1
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    • pp.33-40
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    • 1987
  • Simulated acid rain (pH 4.0, pH 2.0) containing sulfuric and nitric acid in the ratio of 60:40 (chemical equivalent basis) diluted with underground water, and underground water (pH 6.5) as control were treated on potted Pines koraiensis seeds during the growing season (May 1 to August 31) in 1985. The regime of artificial acid rain, in terms of spray frequency and amount per plot, was simulated on the basis of climatological data averaged for 30 years of records. The seedling growth, contents of chemical substances in needles and chemical properties of the tested soil were compared among the various pH levels of acid rain on October 31, 1985. Following results were obtained. 1. With decreasing pH levels of acid rain, S and $K_2O$ contents in leaf tissue were increased, but MgO and $P_2O_5$ contents were decreased. 2. Soil pH was dropped, and exchangeable aluminum content in the tested soil was dramatically increased as the pH levels of acid rain decreased. 3. Exchangeable calcium, magnesium, potassium contents, and base saturation degree of the soil were significantly decreased with decreasing pH levels of acid rain. 4. Sulfate concentrations in the soil were significantly increased as rain pH decreased, but total nitrogen and available phosphate contents were not influenced by acid rain.

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