• Title/Summary/Keyword: chemical recycle

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Continuous Production of Succinic Acid Using an External Membrane Cell Recycle System

  • Kim, Moon-Il;Kim, Nag-Jong;Shang, Longan;Chang, Yong-Keun;Lee, Sang-Yup;Chang, Ho-Nam
    • Journal of Microbiology and Biotechnology
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    • v.19 no.11
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    • pp.1369-1373
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    • 2009
  • Succinic acid was produced by continuous fermentation of Actinobacillus succinogenes sp. 130Z in an external membrane cell recycle reactor to improve viable cell concentration and productivity. Using this system, cell concentration increased to 16.4 g/l at the dilution rate $0.2\;h^{-1}$, up to 3 times higher than that of batch culture, and the volumetric productivity of succinic acid increased up to 6.63 g/l/h at the dilution rate $0.5\;h^{-1}$, 5 times higher than that of batch fermentation. However, in the continuous culture using a high dilution rate, operational problems including severe membrane fouling and contamination by lactic acid producer were observed. Another succinic acid producer, Mannheimia succiniciproducens MBEL55E, was also utilized in this system, and the cell concentration and productivity of succinic acid at the dilution rate of $0.3\;h^{-1}$ were found to be above 3 and 2.3 times higher, respectively, compared with those obtained at the dilution rate of $0.1\;h^{-1}$. These observations give a deep insight into the process design for a continuous succinic acid production by microorganisms.

Behavior of Soluble Microbial Products by the Internal Recycle Rate in MBR Process (MBR공정에서 내부 반송비에 따른 생물대사성분의 거동)

  • Lee, Won-Bae;Cha, Gi-Cheol;Jeong, Tae-Young;Kim, Dong-Jin;Yoo, Ik-Keun
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.602-608
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    • 2005
  • A laboratory-scale experiment was conducted to investigate control of soluble microbial products (SMP) by the internal recycle rate in the submerged membrane separation activated sludge process. The internal recycle rate of the reactor RUN 1 and RUN 2 were 100 % and 200 %, respectively. SMP concentration was rapidly accumulated in the reactor (RUN 1). The variation of accumulated SMP concentration was related to the denitrification rate at the beginning experiment however SMP concentration decreased without correlatively to the denitrification rate during long operation time. The microbial kinetic model was rapidly presented in the both microbial growth and extinction in the reactor (RUN 1). In the SMP kinetic model, Internal recycle rate is the lower, value of UAP and BAP which SMP matter were presented low. The study about development of kinetic model is relatively well adjusted to the experiment exception SMP. In the future, SMP formation equation must be thought that continually research is necessary.

Change of Sludge-Recycle Ratio for the Bio-gas Production Improvement and Minimization with Two-Stage Anaerobic Digestion (2단 혐기성소화공정에서 반송변화를 통한 Bio-gas 생산량 증대 및 감량화)

  • Lee, Tae-Woo;Yang, Hae-Young;Do, Choong-Ho
    • Journal of the Korean Society of Industry Convergence
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    • v.15 no.3
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    • pp.83-86
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    • 2012
  • This study have cross checked the change of internal sludge-recycle in Full-scale Anaerobic-Digestion, and researched about not only the improvement of Bio-gas production from the digested sludge but also the efficient method of sludge minimization. Ultimate aim of the study is to reduce the amount of sludge by the improved efficiency of contact with the organic-matter and the microbes in Anaerobic-Digestion. The sludge-recycle fluidized sludge layer and raised the activity of the sludge, The sludge-recycle ratio of optimum was 500%, VS and COD removal ratio respectively appeared with 67.8% and 70.4%. Through these result of this study, it may be positive view to treat waste sludge by the sludge-recycle ratio in terms of minimization and circulation of resources.

A Study on the Hypochlorination Reaction for Improvement of Epichlorohlydrin Production Process : Reduction of Side Reacion (ECH 생산공정 개선을 위한 Hypochlorination 반응에 관한 연구 : 부반응 억제)

  • Lee, Chul Haeng;Jeon, Sang Jun;Lee, Tai-yong;Wong, Won Hi;Yun, Chang Han;Kim, Young Sub;Cho, Byong Nam;Kim, Yeon Seok
    • Clean Technology
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    • v.9 no.1
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    • pp.29-35
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    • 2003
  • The methods for improving epichlorohydrin process was investigated by carrying out experiments on hypochlorination reaction, from which dichlorohydrin is produced by reacting with allyl chloride and chlorine. As the recycle water from PVC plant was used instead of industrial water for reaction, the effect of recycle water on the reaction yield was studied. It was shown from this experiment that the recycle water rarely affected on the ratio between products. TCPA, which was almost of byproducts, could be removed before purification process using "extractant A". This could prevent additional side reaction by TCPA and reduced energy to separate it in purification part. The change of product yield was observed as the chlorine gas addition decreases which reacted with allyl chloride. It seems that the yield of major products didn't change almost, but the byproducts showed rather reduced trend with decreasing chlorine gas.

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The Effect of Mass Transfer on the Cure Properties of the Urea Resin Moulding Compounds Under the Drying Process (건조 공정 중 요소 수지 성형재료의 경화 특성에 대한 물질전달 효과)

  • Kim, Sang Yeul;Choi, Il Gon;Kim, Byoung Chul
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.681-686
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    • 2002
  • In the industrial field, the theory of drying process is different from the practical application, and it is effective to reduce energy by recirculation of the heat of exhausting gas. But the study of this field may not be performed still. The cure properties of the urea resin moulding compounds was investigated according to drying temperature, drying time, recycle rate of exhausting gas and moulding temperature in the process of drying and moulding. We obtained the following results; water content of material decreases with increasing drying time and drying temperature, and the rate of drying also decreases with increasing recycle rate of exhausting gas. Specially, The cure fluidity of the urea resin moulding compounds decreases, with increasing drying temperature, recycle rate of exhausting gas and moulding temperature. And the correlation equations on water content and cure fluidity of the urea resin moulding material were obtained through a regression analysis of experimental data.

Trend for Waste Plastic Recycling Technology by Patent Analysis (특허분석(特許分析)에 의한 폐플라스틱 재활용(再活用) 기술(技術) 동향(動向))

  • Kim, Tae-Hyun;Rhee, Kang-In;Kim, Yu-Ri
    • Resources Recycling
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    • v.19 no.2
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    • pp.63-72
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    • 2010
  • The patents were searched to investigate the trend of recycling technologies about plastic waste. Database was collected from WIPS site and the range of the search was limited to patents opened in U.S.A (US), European Union (EU), Japan (JP) and Korea (KR) to september 2009. In this paper, 4,795 patents were selected by investigation abstracts and the trend of the recycling technologies relating to waste plastic were investigated through the analyzing by the years, countries, companies. The patents were occupied 65% by Japan and the most of the patents were about chemical recycling. In the case of Korea, material recycling was major in the patents of waste plastic recycling.

Simultaneous Nitrification and Dennrincation of Recirculating Aquaculture Water by Biofilter Reactor (생물막 여과 반응기를 이용한 양어장 순환수의 동시 질산화 및 탈질산화 반응)

  • Lee, Min-Gyu;Suh, Kuen-Hack;Oh, Yung-Hee
    • Journal of Environmental Science International
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    • v.6 no.4
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    • pp.409-415
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    • 1997
  • In order to Investigate the possibility as a simple technique of wastewater treatment for recirculating aquaculture system, the experiment by a biofilter unfit was carried out. The high and stable removal efficiency of nitrogen could be obtained by selecting the optimum recycle ratio and DO concentration. It was found that the proper combination of nitrifacation and denitrfication step in the reactor would be required for increasing the removal efficiency. The extent of nitrogen removal gradually decreased UO the rise of re- cycle ratio since the depression of denitrificatlon by the lack of hydrogen donor. The depression of nitrogen removal was overcome by increasing the CIN ratio In the wastewater. The extent of phosphorus removal was increased slightly with the increase of DO concentration and recycle ratio, but high removal efficiency was not observed. However, the extent of COD removal was not affected by recycle ratio and DO concentration and showed the stable removal of above 90%.

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A Study on the Technique to Manufacture Recycled Cement from Cementitious Powders for Complete Recycling of Concrete Structures (콘크리트 구조물의 완전순환이용을 위한 폐콘크리트계 미분말의 재생시멘트 활용 기술 연구)

  • Park, Cha-Won;An, Jae-Cheol;Gang, Byeong-Hui
    • Journal of the Korea Institute of Building Construction
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    • v.4 no.3
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    • pp.143-151
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    • 2004
  • The purpose of this study is development of technique to use cementitious powder as recycle cement produced from deteriorated Concrete waste which has a large quantity of calcium carbonate. Therefore, after having theoretical consideration based on the properties of high-heated concrete and concerning about neutralization of Concrete, we analysis chemical properties of ingredients of cementitious powder. After making origin cement paste, then processing the accelarated carbonation, we consider the properties of hydration and chemical properties of cementitious powder under various temperature conditions. As a result of the thermal analysis, the $CaCO_3$ content of cementitious powder would affect decision of heat temperature to recover its hydrated ability because $CaCO_3$ content is increased when neutralization is progressed. And as a result of XRD analysis, in case of origin powder of non-neutralized paste, CaO peak is found at $700^{\circ}C$. but, heat temperature to generate CaO would increase when the content of neutralized ingredients is increased. Finally, recycle cement heated at $700^{\circ}C$ 120min. shows the best compressive strength when the content of neutralized ingredients in recycle cement is less then 50%.

Internal Recycle Distribution and Heat Transfer Effect for Optimal Design of Dividing Wall Distillation Columns (분리벽형 증류탑의 최적 설계를 위한 내부 순환량 분포와 전열 특성 연구)

  • 정성오;이기홍;이문용
    • Journal of Institute of Control, Robotics and Systems
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    • v.9 no.3
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    • pp.236-241
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    • 2003
  • This paper addresses the optimal design of dividing wall distillation column which is rapidly applied in a variety of chemical processes over recent several years because of its high energy saving efficiency. A general dividing wall column model which can cope with the heat transfer through the dividing wall is developed using rigorous computer simulation. Based on the simulation model, the effects of the internal recycle flow distribution around the dividing wall and the heat transfer across the dividing wall on overall system performance are investigated. An improved column design method is suggested to utilize the heat transfer through the wall. The suggested method is compared with the existing method via simulation study in which the proposed design shows improved energy saving result.