• Title/Summary/Keyword: chemical index of alteration

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Relationship between Wetness Index and Weathering degree of Rocks in Woogak Mounyain, Koheung-gun, Jeonnam-do (전남 고흥군 우각산 일대의 습윤지수와 암석의 풍화정도와의 상관관계)

  • Kim, Sung-Wook;Kim, Guk-Lac;Han, Ji-Young;Yoon, Won-Seop;Kim, Choon-Sik;Kim, In-Soo
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.882-889
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    • 2004
  • Wetness index obtained from topography data of Woogak Mountain was compared with chemical alteration index(CAI), clay minerall contents of rock, and magnetic susceptibility changes of outcrops, and they show a close interrelationship. It is shown that the wetness index can be used as a quantitative indicator of the weathering degree of rocks. Moreover, wetness index simulate quantitatively the hydrologic condition of the local area. Therefore, it is anticipated that wetness index can be used as the data that calculate the weathering speed of rock and weathering grade in the study of weathering sensitivity of rock.

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Chemical Weathering Trend of Granitic Rock by evaluated with CIA in Southern Korea (화학적 풍화지수(CIA)로 본 한반도 중남부 화강암류의 화학적 풍화 경향성)

  • KIM, Young-Rae
    • Journal of The Geomorphological Association of Korea
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    • v.18 no.3
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    • pp.53-64
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    • 2011
  • Grus weathering mantles are widely distributed in Southern Korean Peninsula and are considered to be results of chemical weathering related to palaeoclimate milieu. This paper attempts to address this issue by CIA(chemical index of alteration). The climatic approach to the formation of grus mantles offers limited explanation of field occurrences, as these materials are widespread across climatic zones, from the humid tropics to cool temperate areas, although rates of grusification are likely to be influenced by climatic parameters. CIA values for granitoid weathering mantles in S. Korea are 50, which is the same of unweathered granitic rocks. Grus mantles in Korean peninsula show very low level in chemical alteration by CIA.

Correlation between Water Values and Chemical Index of Alteration (CIA) in Rocks (퇴적암에서 수분값과 화학적 풍화지수(CIA) 간의 상관관계)

  • Park, Kyunggun;Shin, Jaeryul
    • Journal of the Korean Geographical Society
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    • v.50 no.5
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    • pp.505-514
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    • 2015
  • This study analyzes a correlation between water content values and chemical index of alteration (CIA) for coarse sedimentary rocks of Mt. Cheonsaeng in Gumi-si, Kyeongsangbuk-do. Through measurement of various water values of 20 samples including water content rate, water absorption rate and equipment measuring we comparatively analyzed the values with CIA of the samples obtained by X-ray fluorescence. As a result of analysis water content rate and water absorption rate in a sedimentary rock are likely to be higher when matrix is psephitic and less compact. Furthermore the higher water content rate is, the higher CIA is due to increase of $SiO_2$ and $Al_2O_3$ and decrease of CaO and $Na_2O$ derived by chemical weathering of felspar. This correlation between water content rate and CIA represents a similar result with previous studies targeting granite.

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Effects of Sterilizing Methods on the Content of Index .Constituents of Herbal Medicines (품질 보증을 위한 멸균법이 수종 생약의 지표성분 함량에 미치는 영향)

  • Jeong, Choon-Sik;Cho, So-Yean;Lee, Yong-Soo
    • YAKHAK HOEJI
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    • v.50 no.6
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    • pp.415-420
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    • 2006
  • The purpose of this study was to develop the best methods to sterilize herbal medicines which is frequently used and known to have high susceptibility to microbial contamination. We used dry heat, gamma irradiation and alcohol gas treatment for sterilization, and evaluated these methods in terms of the followings; i) the efficacy of sterilization, and ii) the chemical alteration of index constituents of herbal medicines. Treatment with dry heat effectively eliminated the contaminated microorganisms, and did not significantly alter the content of berberine chloride, paeoniflorin and amygdalin in Phellodendron Bark, Peony Root and Apricot Kernel, respectively: However it seriously changed the color and morphology which are essential criteria to estimate a measure of quality of herbal medicines. Treatment with gamma irradiation showed a strong sterilizing effect, and no alteration of the content of index constituents, color and morphology: Alcohol gas treatment resulted in similar effects as those in gamma irradiation. Collectively; these results suggest that treatment with gamma irradiation or alcohol gas may be useful methods for sterilizing herbal medicines without a decrease in their microbial quality.

Chemical Weathering Index of Clastic Sedimentary Rocks in Korea (국내 쇄설성 퇴적암의 화학적 풍화지수 고찰)

  • Kim, Sung-Wook;Choi, Eun-Kyoung;Kim, Jong-Woo;Kim, Tae-Hyung;Lee, Kyu-Hwan
    • The Journal of Engineering Geology
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    • v.27 no.1
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    • pp.67-79
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    • 2017
  • Evaluation of the weathering index using the quantitative element composition of rocks is very effective in predicting the degree of weathering of rocks and the secondary weathering residuals. While the process of weathering varies according to the types of rocks, the study of weathering in Korea is concentrated on acidic igneous rocks. This study calculated the weathering indices using whole rock analysis (X-ray fluorescence analysis) of sandstone, mudstone, and shale belonging to clastic sedimentary rocks. The statistical significance of the indices was examined based on the correlation of the calculated weathering indices. Clastic sedimentary rocks showed higher significance of Wp, CIA, CIW and PIA weathering index indicating weathering of feldspar. Chemical Index of alteration (CIA) has the advantage of predicting weathering pathway and clay mineral production, but it is effective to consider chemical index of weathering index (CIW) simultaneously to improve accuracy. In order to reduce uncertainties due to carbonate rocks and to estimate the accurate weathering index, rock samples with high CaO content should be excluded from the evaluation of weathering index.

A study on the change of chemical composition of sediment particles of terrace deposits - A case of fine sediments at Jeongdongjin area - (단구 퇴적층의 화학 조성 변화에 대한 연구 - 정동진 단구의 세립 물질을 사례로 -)

  • Kim, Jong Yeon
    • Journal of The Geomorphological Association of Korea
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    • v.23 no.2
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    • pp.29-45
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    • 2016
  • Chemical composition of fine sediments from Jeongdongjin area are analyzed with XRF method. The results are compared with previously reported results of sandstones of the nearest Simgok port. The weight percentage of $SiO_2$ of the samples are far lower than those of sandstones of Simgok. It is supposed to be happened by the selective elution of $SiO_2$ from the sediment layer of coastal terrace, as there's no evidence of selective input or precipitation of other elements from outside. As a result of chemical alteration or weathering of sediment at coastal terrace, weight percentage of $Al_2O_3$ and $Fe_2O_3$ of samples show far higher values than those of Simgok sandstone. In addition, the relative portion of $Al_2O_3$ and $Fe_2O_3$ are decreased to upward within outcrop of terrace sediment layers. It could be caused by the chemical weathering progress with time. However Chemical Index of alteration(CIA) of sediment samples are no larger than 90 and it could be interpreted that it would take over 100ka for total weathering of sediment in this area. Meanwhile the ratio of $SiO_2/Al2O_3$ of terrace sediment showed as 3.48~6.0 and it is far smaller than those of Simgok sandstones(23.9~49.0). The ratio of $SiO_2/Fe_2O_3$ of terrace sediment(19.19~55.85) showed similar pattern with $SiO_2/Al2O_3$ (Simgok sanstone: 119.6~601.8). The ratios have a weak trend of decreasing upwards within the outcrop, there also a huge difference in value among the samples. Chemical composition of reddish brown and gray layers which suspected as the result of psudogleization reveals that reddish brown parts have higher concentration of $Fe_2O_3$ than other parts, while there was no significant difference in concentration of $Al_2O_3$ and CaO.

Comparison of Physicochemical Characteristics of Topsoil and Subsoil for Soil Conservation and Management (토양 보전 및 관리를 위한 표토와 심토의 물리화학적 특성 비교)

  • Lee, So-Jin;Choo, Chang-Oh;Kim, Jong-Tae;Jeong, Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.31 no.4
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    • pp.731-739
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    • 2021
  • This research aimed to analyze the characteristics of topsoil for soil conservation and promote the process of turning subsoil into topsoil. The physicochemical characteristics of topsoil and subsoil of different types of soil were compared, and their quantitative differences were examined. 204 soil samples were collected from a total of 102 areas according to rock types. These samples were tested to measure grain size, water content, and unit weight, along with XRF and XRD analyses. The topsoil and subsoil of the soil samples were also analyzed. The results of this research showed that the topsoil and subsoil had different physical characteristics, and that the chemical alteration index of the topsoil was higher than that of the subsoil. This would imply that the topsoil was high in clay minerals since it was directly affected by weathering more than the subsoil. In particular, vermiculite, one of the final products generated from weathering, was common in the topsoil.

Chemical Weathering Trend of Granitic Rock in Hwangtohyun, Korea (한반도 서부 황토현 일대 적색토의 화학적 풍화 경향)

  • Kim, Young-Rae
    • Journal of the Korean association of regional geographers
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    • v.18 no.1
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    • pp.17-26
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    • 2012
  • In Hwangtohyun, meaning 'red soil pass', reddish surface mantles is widespread. Other granitic hills, exceptionally Naju and Youngam area, in Korean peninsula don't commonly have that color. This paper attempts to address this issue by CIA(chemical index of alteration). CIA data and A-CN-K diagram provide crucial insights into the changes in the relative contributions of chemical physical weathering in difference of grus regolith and saprolite. CaO and $Na_2O$ show strong depletion and $K_2O$ is progressive loss. In grus regolith, weathering trends are (sub)parallel to the CN-A join of the A-CN-K diagram, but the sample's composition plot ever closer to the A-K join in saprolite. The difference of weathering trend obtained using CIA data corresponds closely with the visual interpretation of soil color and texture.

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Chemical Weathering Trend and Rubefaction of Granitic Hills in Naju, Southern Korea (한반도 남서부 나주 일대 화강암 구릉대의 적색화와 화학적 풍화 경향)

  • Kim, Young Rae
    • Journal of The Geomorphological Association of Korea
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    • v.19 no.1
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    • pp.57-68
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    • 2012
  • Red saprolites are appeared in granitic hills in Naju, Southern Korean Peninsula. These red saprolites were analyzed for their geochemistry, including CIA, A-CN-K and A-CNK-FM ternary plots, to understand the chemical weathering trend and rubefaction of the saprolites. These saprolites were compared with kaolinitic saprolites of Guadalquivir Basin in Spain formed under paleo-humid tropical conditions. Chemical Index of Alteration(CIA) value for Naju in Korea is 80, and 87 in Guadalquivir, suggesting moderate and strong weathering in both. Relative to kaolinitic saprolite of Guadalquivir in Spain, red saprolites in Naju are commonly weak loss of CaO, $Na_2O$, especially in $K_2O$. The A-CNK-FM ternary plots of Naju saprolites relative to Kaolinitic saprolites of Guadalquivir shows weak chemical alteration owing to slow removal of $K_2O$, but high mafic constituents, $Fe_2O_3$ and MgO, for most of the samples. In the saprolites of Naju, mafic oxides, $Fe_2O_3$ and MgO, become enriched because of the fast and massive removal of CaO, $Na_2O$ and $K_2O$ relative to other elements, resulting in rubefaction of the surface layer of the saprolites, so more redness than kaolinitic saprolites of Guadalquivir. It is found that the rubefaction of the saprolites is not necessarily proportional to chemical weathering intensity.

Weathering Properties in Deposits of Fluvial Terrace at Bukhan River, Central Korea (북한강 하안단구 퇴적층의 풍화 특성)

  • 이광률
    • Journal of the Korean Geographical Society
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    • v.39 no.3
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    • pp.425-443
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    • 2004
  • Fluvial terraces is poorly developed along Bukhan River in Central Korea. Altitude from riverbed of T1 terraces are 18-29m, T2 terraces 2539m, respectively. Rubification index of T2 is 0.66, T1 is 0.54, and thickness of gravel weathering rind on gneiss of T2 are 14.0mm, granites of T2 are $\infty$, gneiss of T1 are 5.0mm and granites of T2 are 8.0mm, because weathering in deposits of T2 terraces, older than T1, is severer than T1 terraces. Since deposits in T2 have more active and longer weathering than T1, SiO$_2$/Al$_2$O$_3$ is 3.32 in T2 and 4.06 in T1, and SiO$_2$/R$_2$O$_3$ is 2.64 in T2 and 3.19 in T1. CIA(Chemical Index of Alteration) is 87.85% in T2 and 85.88% in T1. Kaolinite and halloysite are founded in deposits of T2 indicating high weathering, and are founded gibbsite made tv eluviation of kaolinite. However, deposits of T1 have no kaolinite, and are found plagioclase, weak mineral in weathering process. Comparing to previous researches by estimated age as altitude from riverbed, rubification index, thickness of gravel weathering rind, element contents and mineral composition, forming age of T2 terraces in Bukhan River are estimated in marine oxygen isotope stage 6 (130-190ka), and T1 terraces are marine oxygen isotope stage 4(59-74ka).