• Title/Summary/Keyword: chemical image

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A Characteristics on the Ancient Glass Beads Excavated from the Site of Hapgang-ri in Sejong, Korea (세종 합강리 유적 출토 고대 유리구슬의 특성 연구)

  • kim, Eun a;Kim, Gyu Ho;Kang, Ji Won;Yun, Cheon Su
    • Journal of Conservation Science
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    • v.36 no.5
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    • pp.405-420
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    • 2020
  • A convergence research was conducted on glass beads excavated at the ruins of Hapgang-ri, Sejong, using the archeology and conservation approach. The period of appearance of Jugu Towangmyo in the ruins of Hapgang-ri can be estimated to begin in the late 2nd century; for Jugu Towangmyo No. 15, the period spans from the late 2nd to early 3rd century. Form, color, and manufacturing techniques of complete glass beads were examined, and the cross-sections and chemical composition of 16 samples were observed. Based on these analyses, the glass beads were divided into blue, purple, and red colors. The blue-colored beads could be further sub-divided based on their gloss and brightness; in contrast, the red-colored beads were highly uniform with regard to these parameters. Based on the stripe and bubble arrangement on the surface of the glass beads, their drawing technique was identified. Traces of heat treatment or polishing were observed at the ends of the beads. According to their chemical composition, the 16 samples were classified into 3 potash glass and 13 soda glass groups; in the latter, the properties of the stabilizers were divided according to the blue and red bead colors. The stabilizers of the red beads are unique in that they allow the distinction among beads excavated in other areas in South Korea owing to their compositional differences. Colorants in blue- and red-colored beads are cobalt (containing MnO), and copper and iron, respectively.

Simulation of Energy Resolution of Time of Flight System for Measuring Positron-annihilation induced Auger Electrons (양전자 소멸 Auger 전자 에너지 측정을 위한 Time of Flight의 분해도 향상에 관한 이론적 연구)

  • Kim, J.H.;Yang, T.K.;Lee, C.Y.;Lee, B.C.
    • Journal of the Korean Vacuum Society
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    • v.17 no.4
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    • pp.311-316
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    • 2008
  • Since the presence of the chemical impurities and defect at surfaces and interfaces greatly influence the properties of various semiconductor devices, an unambiguous chemical characterization of the metal and semiconductor surfaces become more important in the view of the miniaturization of the devices toward nano scale. Among the various conventional surface characterization tools, Electron-induced Auger Electron Spectroscopy (EAES), X-ray Photoelectron Spectroscopy (XPS) and Secondary Electron Ion Mass Spectroscopy (SIMS) are being used for the identification of the surface chemical impurities. Recently, a novel surface characterizaion technique, Positron-annihilation induced Auger Electron Spectroscopy (PAES) is introduced to provide a unique method for the analysis of the elemental composition of the top-most atomic layer. In PAES, monoenergetic positron of a few eV are implanted to the surface under study and these positrons become thermalized near the surface. A fraction of the thermalized positron trapped at the surface state annihilate with the neighboring core-level electrons, creating core-hole excitations, which initiate the Auger process with the emission of Auger electrons almost simultaneously with the emission of annihilating gamma-rays. The energy of electrons is generally determined by employing ExB energy selector, which shows a poor resolution of $6{\sim}10eV$. In this paper, time-of-flight system is employed to measure the electrons energy with an enhanced energy resolution. The experimental result is compared with simulation results in the case of both linear (with retarding tube) and reflected TOF systems.

A Characteristic Analysis of Glass Beads in Geumgwan Gaya, Korea (I) (금관가야 유리구슬의 특성 분석 (I))

  • Kim, Eun A;Lee, Je Hyun;Kim, Gyu Ho
    • Journal of Conservation Science
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    • v.37 no.3
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    • pp.232-244
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    • 2021
  • This study examined the physical attributes and heat treatment characteristics of glass beads excavated from the Gimhae area, which is the location of Geumgwan Gaya. This enabled classification of surface characteristics of the beads based on the investigation of the color, size, and shape. The glass beads were classified into eight color systems, with purplish-blue beads as the representative color. Bead size was categorized into three types depending on the outer diameter and how it increased over time. Bead shapes were categorized as round, tubular, or doughnut-shaped based on the inner diameter and length, with round being the typical shape. According to the degree of heat treatment, there are three types of cross-section for glass beads that are manufactured by the drawing technique, most of which are the HT-III type. In addition, it is estimated that the heat treatment technology has more considerable effects than other methods. Through non-destructive analysis, the chemical composition was obtained and categorized as flux, stabilizer, and colorant. Analysis confirmed the presence of 63 and 9 pieces in the potash and soda glass groups, respectively. Overall findings from the study highlighted a correlation between the chemical composition and the external factors such as color, size, shape, and manufacturing technology of glass beads recovered from Geumgwan Gaya, revealing characteristics related to that time and region.

An Analysis on the Usability of Unmanned Aerial Vehicle(UAV) Image to Identify Water Quality Characteristics in Agricultural Streams (농업지역 소하천의 수질 특성 파악을 위한 UAV 영상 활용 가능성 분석)

  • Kim, Seoung-Hyeon;Moon, Byung-Hyun;Song, Bong-Geun;Park, Kyung-Hun
    • Journal of the Korean Association of Geographic Information Studies
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    • v.22 no.3
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    • pp.10-20
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    • 2019
  • Irregular rainfall caused by climate change, in combination with non-point pollution, can cause water systems worldwide to suffer from frequent eutrophication and algal blooms. This type of water pollution is more common in agricultural prone to water system inflow of non-point pollution. Therefore, in this study, the correlation between Unmanned Aerial Vehicle(UAV) multi-spectral images and total phosphorus, total nitrogen, and chlorophyll-a with indirect association of algal blooms, was analyzed to identify the usability of UAV image to identify water quality characteristics in agricultural streams. The analysis the vegetation index Normalized Differences Index (NDVI), the Normalized Differences Red Edge(NDRE), and the Chlorophyll Index Red Edge(CIRE) for the detection of multi-spectral images and algal blooms collected from the target regions Yang cheon and Hamyang Wicheon. The analysis of the correlation between image values and water quality analysis values for the water sampling points, total phosphorus at a significance level of 0.05 was correlated with the CIRE(0.66), and chlorophyll-a showed correlation with Blue(-0.67), Green(-0.66), NDVI(0.75), NDRE (0.67), CIRE(0.74). Total nitrogen was correlated with the Red(-0.64), Red edge (-0.64) and Near-Infrared Ray(NIR)(-0.72) wavelength at the significance level of 0.05. The results of this study confirmed a significant correlations between multi-spectral images collected through UAV and the factors responsible for water pollution, In the case of the vegetation index used for the detection of algal bloom, the possibility of identification of not only chlorophyll-a but also total phosphorus was confirmed. This data will be used as a meaningful data for counterplan such as selecting non-point pollution apprehensive area in agricultural area.

A Comparative study of Middle School Students' Images and Perceptions of Scientist, Technician and Engineer (과학자, 기술자, 공학자에 대한 중학생들의 이미지와 인식 비교)

  • Kim, Hyeon-Yeong;Park, Soo-Kyeong;Kim, Young-Min
    • Journal of The Korean Association For Science Education
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    • v.32 no.1
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    • pp.64-81
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    • 2012
  • The purpose of this study was to analyse middle school students' images and perceptions about scientist, technician and engineer and to compare the images of male students with those of female students. Fralick et al.(2009)'s "Draw a scientist at work and draw an engineer at work" was modified and administered to 110 middle school 3rd grade students (43 male students, 67 female students) from 5 middle schools. They drew the figures at work and took explanation of what the person was doing in a drawing. The results of this study were as follows; First, the representative image of scientist was the man with glasses and lab gown performing the chemical experiment. There were no significant differences between the male students and female students in terms of the scientist images. Second, the representative image of technician was the man who was fixing a car and working with his hands. The technicians were illustrated as working with tools such as wrench, hammer and so on. There were no significant differences between the male students and female students in terms of the technician images. Third, the students involved in this study frequently perceived male engineers as working indoors. But perceptions about performance of engineers were significantly different between male students and female students. A majority of male students recognized that engineers should design, invent and create the products, however many female students perceived the engineers as car mechanics. Fourth, the students perceived differently the scientists' task compared with the technicians', but they had difficulty in distinguishing the scientists' task from the engineers' task.

Comparison of In-Phase and Opposed-Phase FMPSPGR Images in Breath-hold T1-weighted MR IMaging of Liver (호흡정지 T1 강조 간 자기공명영상에서 동위상 역위상 FMPSPGR 영상의 비교)

  • 김명진;김만득;정재준;이종태;유형식
    • Investigative Magnetic Resonance Imaging
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    • v.1 no.1
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    • pp.142-147
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    • 1997
  • Purpose: To compare the effectiveness of the in-phase (IP) sequence and the opposed-phase (Op) sequence in the detection of focal hepatic lesions in the single breath-hold hepatic MR imaging with fast gradient T1-weighted pulse sequences. Materials and Methods: IP and OP T1-weighted breath-hold imaging was performed using fast gradient echo sequences in 45 patients referred for known focal hepatic lesions, in which 78 lesions were detected. Three blind readers independently reviewed the images for lesion detectability. The signal-to-noise ratio (SNR) of the liver, the lesion-to-liver contrast-to-noise ratio (CNR) and the liver-to-spleen CNR were also compared. A consensus was reached by three readers to determine which sequence is better in image quality. Results: On OP images, 61(78%), 61(78%), and 63(89%) lesions were correctly identified for reader 1, 2 and 3, respectively. On IP images, 66(85%), 65(83%), and 65(93%) lesions were detected for each reader, respectively. When two image sets were combined, 71(91 %), 69(88 %), and 76(97%) lesions respectively were detected for each reader. In cases of hepatocellular carcinoma, liver-to-Iesion CNR was greater on the OP images(p (0.05), but in other lesions significant difference was not demonstrated. Liver-to-spleen CNR was higher on OP images(p ( 0.1), but the SNR of the liver was higher on the IP images. Conclusion: Use of both IP and OP imaging can be helpful to avoid erroneous missing of some focal hepatic lesions.

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Preparation and Characteristic of Size Controlled Platy Silver by Polyol Process with $PdCl_2$ ($PdCl_2$ 첨가 폴리올공정(工程)을 이용(利用)한 판상 은(銀) 분말(粉末) 제조(製造) 및 특성(特性))

  • Shin, Gi-Wung;Ahn, Jong-Gwan;Kim, Dong-Jin;Cho, Sung-Wook;Ahn, Jea-Woo
    • Resources Recycling
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    • v.19 no.5
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    • pp.58-67
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    • 2010
  • Platy silver powders with varied size and thickness were prepared by polyol process with $PdCl_2$ in ethylene glycol and characterized its properties and investigated the effects of reaction time, $NH_4OH$, PVP(poly-vinylpyrrolidone) and $PdCl_2$. The characteristics of the products were verified by scanning electron microscopy(SEM), high resolution transmitted electron microscopy(HR-TEM), X-ray diffraction(XRD) and particle size analyzer(PSA) and image analyzer. Platy silver powder was prepared about $5.5\;{\mu}m$ of size and $0.2\;{\mu}m$ at 120minute. It was found that the size of powders increased by the increasing of $NH_4OH$ and $PdCl_2$ concentrations, and the thickness of powders was decreased by increasing of PVP concentration.

Analysis of Surface Temperature Characteristics by Land Surface Fabrics Using UAV TIR Images (UAV 열적외 영상을 활용한 피복재질별 표면온도 특성 분석)

  • SONG, Bong-Geun;KIM, Gyeong-Ah;SEO, Kyeong-Ho;LEE, Seung-Won;PARK, Kyung-Hun
    • Journal of the Korean Association of Geographic Information Studies
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    • v.21 no.3
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    • pp.162-175
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    • 2018
  • The purpose of this study was to analyze the surface temperature of surface fabrics using UAV TIR images, to mitigate problems in the thermal environment of urban areas. Surface temperature values derived from UAV images were compared with those measured in-situ during the similar period as when the images were taken. The difference in the in-situ measured and UAV image derived surface temperatures is the highest for gray colored concrete roof fabrics, at $17^{\circ}C$, and urethane fabrics show the lowest difference, at $0.3^{\circ}C$. The experiment power of the scatter plot of in-situ measured and UAV image derived surface temperatures was 63.75%, indicating that the correlation between the two is high. The surface fabrics with high temperature are metal roofs($48.9^{\circ}C$), urethane($43.4^{\circ}C$), and gray colored concrete roofs($42.9^{\circ}C$), and those with low temperature are barren land($30.2^{\circ}C$), area with trees and lawns($30.2^{\circ}C$), and white colored concrete roofs($34.9^{\circ}C$). These results show that accurate analysis of the thermal characteristics of surface fabrics is possible using UAV images. In future, it will be necessary to increase the usability of UAV images via comparison with in-situ data and linkage to satellite imagery.

Hydraulic Conductivity and Microscopic Analysis of Fly Ash Liner (플라이애쉬 혼합차수재의 투수특성과 미세구조 분석)

  • Jeong, Mun-Gyeong;Seo, Gyeong-Won;Lee, Yong-Su
    • Geotechnical Engineering
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    • v.14 no.1
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    • pp.109-126
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    • 1998
  • The use of fly ash as a contaminant barrier material was studied. Mixing ratio of fly ash to bentonite to meet the requirements for landfill liners was determined. The hydraulic behavior exhibited by the fly ash-bentonite liner and the effects of CaO were investigated through hydraulic conductivity tests under various conditions and microscopic analyses including XRD, SEM, helium porosimetry, and image analysis. The hydraulic conductivity of compacted fly ash decreased with the addition of bentonite, which was due mainly to the expanding of bentonite and partly to the filling of voids by chemical reaction products among constituents of the artificial liner. Because of insufficient CaO content, and rich in content but low-reactive $SiO_2$ contained in the fly ashes used, pozzolanic reaction and resulting effects in the artificial liner were not significant. The reactions among constituting materials and their resulting effects on hydraulic conductivity were controlled not by the apparent amounts of each constituent, but by reaction activities of the materials in the artificial liner.

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Effect of Calcination Temperatures on the Structure and Electrochemical Characterization of Li(Ni0.5Mn0.3Co0.2)O2 as Cathode Material by Supercritical Hydrothermal Synthesis Method (초임계 수열법으로 합성한 Li(Ni0.5Mn0.3Co0.2)O2 양극 활물질의 소성 온도영향에 따른 구조 및 전기화학적 특성)

  • Choo, Soyeon;Beom, YunGyeong;Kim, Sungsu;Han, Kyooseung
    • Journal of the Korean Electrochemical Society
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    • v.16 no.3
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    • pp.151-156
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    • 2013
  • As the cathode material for li-ion battery, $LiNi_{0.5}Mn_{0.3}Co_{0.2}O_2$ were synthesized by supercritical hydrothermal method and calcined $850^{\circ}C$ and $900^{\circ}C$ for 10hrs in air. The effect of temperature in the heat treatment on the powder and its performance were studied of xray diffraction pattern, SEM-image, physical properties and electrochemical behaviors. As a result, calcined at $900^{\circ}C$ material particle size more increase than calcined at $850^{\circ}C$ material, especially shows excellent electrochemical performance with initial reversible specific capacity of 163.84 mAh/g (0.1C/2.0-4.3V), 186.87 mAh/g (0.1C/2.0-4.5V) and good capacity retention of 91.49% (0.2C/2.0-4.3V) and 90.36% (0.2C/2.0-4.5V) after 50th charge/discharge cycle.