• Title/Summary/Keyword: chemical filter

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Carbon dioxide (CO2) concentrations and activated carbon fiber filters in passenger vehicles in urban areas of Jeonju, Korea

  • Kim, Hong Gun;Yu, Yunhua;Yang, Xiaoping;Ryu, Seung Kon
    • Carbon letters
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    • v.26
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    • pp.74-80
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    • 2018
  • The South Korean Ministry of the Environment has revised the laws relating to the management of interior air quality for multiple use facilities, and recommends maintaining carbon dioxide ($CO_2$) concentration in passenger vehicles below 1000 ppm during operation in urban areas of large cities. However, the interior $CO_2$ concentration of passenger vehicles can rapidly increase and exceed 5000 ppm within 30 min, as observed when two passengers are traveling in urban areas of the South Korean city of Jeonju with the air conditioner blower turned off and the actuator mode set to internal circulation mode. With four passengers, $CO_2$ concentration can reach up to 6000 ppm within 10 min. To counter this, when the actuator is set to external mode, $CO_2$ concentration can be maintained below 1000 ppm, even after a long period of running time. As part of the air conditioning system, alkali-treated activated carbon fiber filters are considered to be far superior to the commercial non-woven filters or combination filters currently commonly in use.

Fabrication and Characterization of Porous Nickel Membrane for High Precision Gas Filter by In-situ Reduction/Sintering Process (In-situ 환원/소결법을 이용한 다공성 니켈 멤브레인 가스필터의 제조 및 평가)

  • Kim, Nam-Hoon;Song, Han-Bok;Choi, Sung-Churl;Choa, Yong-Ho
    • Journal of Powder Materials
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    • v.16 no.4
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    • pp.262-267
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    • 2009
  • Disk type porous nickel membrane was fabricated by in-situ reduction/sintering process using compacted NiO/PMMA (PMMA; Polymethyl methacrylate) mixture at $800^{\circ}C$ in hydrogen atmosphere. The porosity (49$\sim$58%) of these membrane was investigated as an amount of PMMA additive. The thermal decomposition and reduction behavior of NiO/PMMA were analyzed by TG/DTA in hydrogen atmosphere and the activation energy for the hydrogen reduction of NiO and thermal degradation of PMMA was calculated as 61.1 kJ/mol, evaluated by Kissinger method. Finally, the filtering performance and pressure drop were measured by particle counting system.

Study on the Paper Chromatography. Ⅰ. Capillary Ascending of Liguids (Paper Chromatography 에 關한 硏究 (第 1 報) 毛細管 上昇에 關하여 (基一))

  • Young Jae Hyun;Choi Qui Won
    • Journal of the Korean Chemical Society
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    • v.3 no.1
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    • pp.23-27
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    • 1954
  • The relation between the height of ascending solvents and its velocity were studied with strips of Toyo No. 50 filter paper. The filter paper strip of 3cm width and cat 30 cm length is hooked down or fixed between two sheets of glass plates inside a cylinder containing the solvent, in which the lower end of the strip is dipped. As the solvents, acetone, hydrochloric acid, water or mixtures of these are used. For short time intervals, Ostwald's folmula $h = Kt^n$ was found to be most suitable to express the relation between the height of the solvent front, h, and time, t. For longer time intervals, results will be discussed in the next paper. The mean values of the constant m in the above formula for pure acetone and pure water were 0.44 and 0.485, respectively, and that of K were 0.05 and 2.4, respectively. The time interval whose the above formula applies, for each solvent was 2 hours for the former, and a half hour for the later, respectively. The movement of solutes, such as $Cu^{++}$ and $Fe^{++}$ showed that the Rf values of solutes become constant values after a long periods; e.g., ca. 6 hours with 10N-HCl-Acetone (1 : 9) solvent.

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Reduction of Ambiguity in Phosphorylation-site Localization in Large-scale Phosphopeptide Profiling by Data Filter using Unique Mass Class Information

  • Madar, Inamul Hasan;Back, Seunghoon;Mun, Dong-Gi;Kim, Hokeun;Jung, Jae Hun;Kim, Kwang Pyo;Lee, Sang-Won
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.845-850
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    • 2014
  • The rapid development of shotgun proteomics is paving the way for extensive proteome profiling, while providing extensive information on various post translational modifications (PTMs) that occur to a proteome of interest. For example, the current phosphoproteomic methods can yield more than 10,000 phosphopeptides identified from a proteome sample. Despite these developments, it remains a challenging issue to pinpoint the true phosphorylation sites, especially when multiple sites are possible for phosphorylation in the peptides. We developed the Phospho-UMC filter, which is a simple method of localizing the site of phosphorylation using unique mass classes (UMCs) information to differentiate phosphopeptides with different phosphorylation sites and increase the confidence in phosphorylation site localization. The method was applied to large scale phosphopeptide profiling data and was demonstrated to be effective in the reducing ambiguity associated with the tandem mass spectrometric data analysis of phosphopeptides.

Pore Structure Modification and Characterization of Porous Cordierite with Chemical Vapor Infiltration (CVI) SiC Whisker (화학증착 탄화규소 휘스커에 의한 다공성 코디어라이트의 기공구조 개질 및 특성평가)

  • Kim, Ik-Whan;Kim, Jun-Gyu;Lee, Hwan-Sup;Choi, Doo-Jin
    • Journal of the Korean Ceramic Society
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    • v.45 no.2
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    • pp.132-137
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    • 2008
  • The main purpose of this study is enhancing the filtering efficiency, performance and durability of filter by growing SiC whiskers on cordierite honeycomb substrate. The experiment was performed by Chemical Vapor Infiltration (CVI) in order to control pore morphology of substrate. Increasing the mechanical strength of porous substrate is one of important issues. The formation of "networking structure" in the pore of porous substrate increased mechanical strength. The high pressure gas injection to the specimen showed that a little of whiskers were separated from substrate but additional film coating enhanced the stability of whisker at high pressure gas injection. Particle trap test was performed. More nano-particle was trapped by whisker growth at the pore of substrate. Therefore it is expected that the porous cordierite which deposited the SiC whisker will be the promising material for the application as filter trapping the nano-particles.

Langmuir-Blodgett Films of Perfluoroalkyl Monomaleate Copolymers on Porous Substrate

  • Hyein Jeong;Burm-Jong Lee;Young-Soo Kwon
    • Bulletin of the Korean Chemical Society
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    • v.15 no.8
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    • pp.650-654
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    • 1994
  • Stable polyion-complexed polymeric monolayers were prepared by spreading perfluoroalkyl monomaleate copolymers, $C_2F_8MA-VE_2$ and $C_2F_8MA-VE_3$, on a aqueous poly(allylamine) subphase. The monolayer properties have been studied by the surface pressure-area (${\pi}$-A) isotherms. The $C_2F_8MA-VE_3$ containing longer oligoethyleneglycol pendant showed more expanded monolayer phase than the $C_2F_8MA-VE_2$. The polyion-complexed monolayers were transferable on various substrates, and the resulting Langmuir-Blodgett (LB) films were characterized by FT-IR spectroscopy and scanning electron microscopy (SEM). Two-dimensional crosslinking to form a polymer network was achieved by amide formation through heat treatment under vacuum with concurrent removal of perfluoroalkyl tails. SEM observation of this film on a porous membrane filter showed that the four layer film was sufficiently stable to cover the filter pore size of 0.1 ${\mu}$m. The $C_2F_8MA-VE_3$ revealed better covering capability than the $C_2F_8MA-VE_2$. Immersion of this film in water or in benzene did not cause any change in its appearance and in Fl-IR spectra.

Entropy, enthalpy, and gibbs free energy variations of 133Cs via CO2-activated carbon filter and ferric ferrocyanide hybrid composites

  • Lee, Joon Hyuk;Suh, Dong Hack
    • Nuclear Engineering and Technology
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    • v.53 no.11
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    • pp.3711-3716
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    • 2021
  • The addition of ferric ferrocyanide (Prussian blue; PB) to adsorbents could enhance the adsorption performance of 133Cs. Toward this goal, we present a heterogeneously integrated carbonaceous material platform consisting of PB in direct contact with CO2-activated carbon filters (PB-CACF). The resulted sample retains 24.39% more PB than vice versa probed by the ultraviolet-visible spectrometer. We leverage this effect to capture 133Cs in the aqueous environment via the increase in ionic strength and micropores. We note that the amount of PB was likely to be the key factor for 133Cs adsorption compared with specific surface characteristics. The revealed adsorption capacity of PB-CACF was 21.69% higher than the bare support. The adsorption characteristics were feasible and spontaneous. Positive values of 𝜟Ho and 𝜟So show the endothermic nature and increased randomness. Based on the concept of capturing hazardous materials via hazardous materials, our work will be of interest within the relevant academia for collecting radionuclides in a sufficient manner.

Near Infrared Shielding Properties of Quaternary Tungsten Bronze Nanoparticle Na0.11Cs0.22WO3

  • Moon, Kyunghwan;Cho, Jin-Ju;Lee, Ye-Bin;Yoo, Pil J.;Bark, Chung Wung;Park, Juhyun
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.731-734
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    • 2013
  • Reduced tungsten bronze nanoparticles of ternary and quaternary compounds were prepared by adding sodium and cesium to crystal structures of tungsten trioxides ($Na_xCs_{0.33-x}WO_3$, x = 0, 0.11) while maintaining the overall alkali metal fraction at 0.33, in an attempt to control near infrared (NIR) shielding property in the particular wavelength range of 780 to 1200 nm. The structure and composition analysis of the quaternary compound, $Na_{0.11}Cs_{0.22}WO_3$, revealed that 93.1% of the hexagonal phase was formed, suggesting that both alkali metals were mainly inserted in hexagonal channel. The NIR shielding property for $Na_{0.11}Cs_{0.22}WO_3$ was remarkable, as this material demonstrated efficient transmittance of visible light up to 780 nm and enhancement in NIR shielding because of the blue-shifted absorption maximum in comparison to $Cs_{0.33}WO_3$.

Design and Development of Integrated Recirculating Aquaculture System (순환 여과식 양식 시스템의 설계 및 개발)

  • SUH Kuen-Hack;KIM Byong-Jin;JEON Im Gi
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.1
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    • pp.70-76
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    • 2001
  • An integrated recirculating aquaculture system suitable to our country's situation was designes and developed, The integrated recirculating aquaculture system consisting of a double drain type rearing tank of the $2.5 m^3$, a sedimentation tank for removal of settleable solids, a floating bead filter for the removal of suspended solids, a foam separator for removal of fine particles and a rotating biological contactor for the nitrification was designed and manufactured. The integrated recirculating aquaculture system was stocked with nile tilapia (Oreochromis niloticus) at $2\%$ rearing density for 2 weeks. Feed coefficient was 1.4 and average daily growth rate was $0.64\%$ in the system for 2 weeks.

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Use of tar color additives as a light filter to enhance growth and lipid production by the microalga Nannochloropsis gaditana

  • Shin, Won-Sub;Jung, Simon MoonGeun;Cho, Chang-Ho;Woo, Do-Wook;Kim, Woong;Kwon, Jong-Hee
    • Environmental Engineering Research
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    • v.23 no.2
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    • pp.205-209
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    • 2018
  • The spectral composition of light can affect the growth and biochemical composition of photosynthetic microalgae. This study examined the use of light filtering through a solution of soluble colored additives, a cost-effective method to alter the light spectrum, on the growth and lipid production of an oleaginous microalga, Nannochloropsis gaditana (N. gaditana). Cells were photoautotrophically cultivated under a white light emitting diode (LED) alone (control) or under a white LED that passed through a solution of red and yellow color additive (4:1 ratio) that blocked light below 600 nm. The specific growth rate was significantly greater under filtered light than white light ($0.2672d^{-1}$ vs. $0.1930d^{-1}$). Growth under filtered light also increased the fatty acid methyl ester (FAME) yield by 22.4% and FAME productivity by 80.0%, relative to the white light control. In addition, the content of saturated fatty acids was greater under filtered light, so the biodiesel products had better stability. These results show that passing white light through an inexpensive color filter can simultaneously enhance cellular growth and lipid productivity of N. gaditana. This approach of optimizing the light spectrum may be applicable to other species of microalgae.