• Title/Summary/Keyword: chemical filter

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Composting and trickling filter for treatment of olive mill waste

  • Li, Xinhua;Lin, Ching-Chieh;Sweeney, Daniel;Earl, Jessica;Hong, Andy
    • Advances in environmental research
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    • v.2 no.2
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    • pp.131-141
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    • 2013
  • Agricultural practice and improper waste disposal in developing regions have resulted in environmental degradation in land and waters, for which low-cost, proven solutions are needed. We demonstrate in the laboratory the applications of composting and trickling filter techniques to treat olive mill wastes that can be implemented in the West Bank and other regions of the world. To a pomace waste sample from a California mill, we amended with saw dust (wood carbon source) and baking soda ($NaHCO_3$ alkalinity) at weight ratios of waste/wood/$NaHCO_3$ at 70:27:1 and composted it for periods of 11 and 48 days; the compost was used as an additive to potting soil for transplanting. The pomace sample was also blended into slurry and introduced to a water-circulating pond and trickling filter system (P/TF) to examine any inhibitive effect of the pomace on biological removal of the organic waste. The results showed the compost-amended potting soil supported plant growth without noticeable stress over 34 days and the P/TF system removed BOD and COD by >90% from the waste liquid within 2 days, with a first-order rate constant of 1.9 $d^{-1}$ in the pond. An onsite treatment design is proposed that promises implementation for agricultural waste disposal in developing regions.

Preparation and Characterization of Cy3 Dye for LCD Color Filter (LCD Color Filter용 Cy3 염료의 제조 및 특성 연구)

  • Lee, Sang Dong;Hyun, Dong Kyoun;Jeong, Yeon Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.1
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    • pp.35-39
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    • 2016
  • In this research, we focused on the improvement of cy3 dye's characteristics for LCD color filter. Solubility and thermal stability are main characteristics of dyes for LCD color filter. We performed experiment to change counter cation of cy3 dyes with alkoxy substituent for these purposes. These cy3 dyes (1b~5b) were prepared through the synthetic procedure of three steps. The synthesized new cy3 dyes were charaterized by using NMR, FT-IR, UV/Vis spectroscopy, and TGA. These cy3 dyes showed purple color and maximum absorption wavelength (${\lambda}_{max}$) in the range of 578~590 nm in UV/Vis spectrum. We confirmed that solubility and thermal stability of cy3 dyes were dependent on the structure of counter cation. Cy3 dyes with alkoxy substituent have good solubility in organic solvents such as dichloromethane, methanol, and acetone. Especially, Cy3 dye with 4-nitrobenzyl counter cation (5b) gave excellent solubility characteristics.

Design of Aperiodic Multilayer Optical Filter Structure for using COVID-19 UV Sterilization (COVID-19의 UV 살균을 위한 비주기 다중층막 광학필터 구조의 설계)

  • Yeo, Jong-Bin
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.1
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    • pp.67-70
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    • 2022
  • In the present work, we have designed to optimize the optical filter structures of the 1-dimensional photonic quasicrystals (1D PQCs) characteristic for the COVID-19 UV sterilization. The simulator using MATLAB program and ourselves manufacturing calculation codes. After making the aperiodic (and complexed) multi-layer structure model, we establish the transfer matrix method (TMM) for model by the operator conversion. By the using the MATLAB, we derive a matrix for the designed complexed multi-layer structure by applying the equations to the model by obtaining the reflectance and transmittance from the matrix. We also prove the possibility of application in optical filter for UV sterilization.

Sampling Method for Individual Particle Analysis of Atmospheric Aerosol (개별입자 분석을 위한 대기에어로졸의 시료채취법)

  • Seong-Woo Cheon;Jeong-Ho Park
    • Journal of Environmental Science International
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    • v.33 no.2
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    • pp.113-119
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    • 2024
  • In this study, the most suitable sampling methods for the bimodal mass distribution characteristics and individual particle analysis of atmospheric aerosols were investigated. Samples collected in Quartz, Teflon, and Nuclepore filters were analyzed for individual particles using scanning electron microscopy with an energy-dispersive X-ray spectrometer (SEM/EDS). Then, the pore diameter of the filter and the collection flow rate were determined using the theoretical collection efficiency calculation formula for two-stage separation sample collection of coarse and fine particles. The Nuclepore filter was found to be the most suitable filter for identifying the physical and chemical characteristics of atmospheric aerosols since it was able to separate the sample and count the different sized particles better than either Quartz or Teflon. Nuclepore filters with 8.0 ㎛ and 0.4 ㎛ pores were connected in series and exposed to a flow rate of 16.7 L/min for two-stage separation sampling. The results show that it is possible to separate and collect both coarse and fine particles. We expect that the proposed methodology will be used for future individual particle analysis of atmospheric aerosols and related research.

Evaluation of the Impact of Filter Media Depth on Filtration Performance and Clogging Formation of a Stormwater Sand Filter (강우유출수 모래 필터의 여과기능 및 폐색 현상에 대한 필터 여재 깊이의 영향 평가)

  • Segismundo, Ezequiel Q.;Lee, Byung-Sik;Kim, Lee-Hyung;Koo, Bon-Hong
    • Journal of Korean Society on Water Environment
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    • v.32 no.1
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    • pp.36-45
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    • 2016
  • Sand filters are widely used in infiltration systems to manage polluted urban runoff. Clogging, which is mainly caused by the deposition of sediments on the filter media, reduces the filter system's infiltration capacity, which further limits its lifespan and function. The physical, chemical and biological clogging characteristics of sand filter, therefore, need to be known for effective design and maintenance. Physical clogging behavior and variations in the characteristics of sand filters according to different media depths are examined in this paper. The variations were observed from laboratory column infiltration tests conducted in a vertical flow and fluctuating head condition. It can be seen that an increase in filter media depth results in a high sediment removal performance; however, it leads to a shorter lifespan due to clogging. In the choice of filter media depth to be used in field applications, therefore, the purpose of facilities as well as maintenance costs need to be considered. At all filter media depth configurations, premature clogging occurred because sediments of 100~250 μm clogged the top 15% of filter media depth. Thus, scrapping the top 15% of filter media may be suggested as the first operational maintenance process for the infiltration system.

Removal of NOx from Graphene based Photocatalyst Ceramic Filter (그래핀 기반 광촉매 담지 세라믹필터에서 질소산화물(NOx)의 제거)

  • Kim, Yong-Seok;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.600-605
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    • 2022
  • In this study, nitrogen oxide (NOx) removal experiments were performed using a graphene based ceramic filter coated with a V2O5-WO3-TiO2 catalyst. Graphene oxide (GO) was prepared by Hummer's method using graphite, and the reduced graphene oxide was produced by reducing with hydrazine (N2H4). Vanadium (V), Tungsten (W), and Titanium (Ti) were coated by the sol-gel method, and then a metal oxide-supported filter was prepared through a calcination process at 350 ℃. A NOx removal efficiency test was performed for the catalytic ceramic filters with UV light in a humid condition. When graphene oxide (GO) and reduced graphene oxide (rGO) were present on the filter, the NOx removal efficiency was superior to that of the conventional ceramic filter. Most likely, this is due to an improvement in the adsorption properties of NOx molecules on graphene coated surfaces. As the concentration of graphene increased, higher NOx removal efficiency was confirmed.

Comparisons of Regeneration Methods Using Physical and Chemical Treatment for Phosphate Removal Restoration of Filter Media (여재의 인 제거기능 회복을 위한 물리화학적 재사용 방안 비교)

  • Kim, Ji Ah;Choi, I Song;Oh, Jong Min;Kim, Won Jae;Park, Jae Roh
    • Ecology and Resilient Infrastructure
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    • v.3 no.3
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    • pp.201-206
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    • 2016
  • The purpose of this study is to find the regeneration method of filter media using physical and chemical treatment for restoration of phosphorus adsorption ability. The filtration material used in this study is called Adphos. In an experiment of heating treatment, re-used filter media is heated to a high temperature before the adsorption test. The results show that the $PO{_4}^{3-}-P$ adsorption capacity is in the range of 0.0021 - 0.0030 mg/g and the removal efficiency is in the range of 26.1 - 39.4%. In the experiment of acid or basic treatment, re-used filter media is exposed to a different pH condition before the adsorption test. The results show that the $PO_4^{3-}-P$ adsorption capacity is in the range of 0.0010 - 0.0066 mg/g and the removal efficiency is in the range of 15.8 - 87.1% after the acid treatments which have pH values of 1 - 5. However, after the basic treatments which have pH values of 8 - 11, the results show that the $PO{_4}^{3-}-P$ adsorption capacity is in the range of 0.0018 - 0.0034 mg/g and the removal efficiency is in the range of 26.7 - 48.0%. In an experiment of chemical treatment using NaCl, re-used filter media was exposed to a different NaCl concentration before the adsorption test. The results show that the $PO{_4}^{3-}-P$ adsorption capacity is in the range of 0.0036 - 0.0050 mg/g and the removal efficiency is in the range of 50.5 - 71.1%. In conclusion, chemical treatment using NaCl shows a high recovery probability of phosphorus adsorption ability of filter media.

Survival of Microorganisms on Antimicrobial Filters and the Removal Efficiency of Bioaerosols in an Environmental Chamber

  • Kim, Sung Yeon;Kim, Misoon;Lee, Sunghee;Lee, JungEun;Ko, GwangPyo
    • Journal of Microbiology and Biotechnology
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    • v.22 no.9
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    • pp.1288-1295
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    • 2012
  • Exposure to bioaerosols causes various adverse health effects including infectious and respiratory diseases, and hypersensitivity. Controlling exposure to bioaerosols is important for disease control and prevention. In this study, we evaluated the efficacies of various functional filters coated with antimicrobial chemicals in deactivating representative microorganisms on filters or as bioaerosols. Tested functional filters were coated with different chemicals that included (i) Ginkgo and sumac, (ii) Ag-apatite and guanidine phosphate, (iii) $SiO_2$, ZnO, and $Al_2O_3$, and (iv) zeolite. To evaluate the filters, we used a model ventilation system (1) to evaluate the removal efficiency of bacteria (Escherichia coli and Legionella pneumophila), bacterial spores (Bacillus subtilis spore), and viruses (MS2 bacteriophage) on various functional filters, and (2) to characterize the removal efficiency of these bioaerosols. All experiments were performed at a constant temperature of $25^{\circ}C$ and humidity of 50%. Most bacteria (excluding B. subtilis) rapidly decreased on the functional filter. Therefore, we confirmed that functional filters have antimicrobial effects. Additionally, we evaluated the removal efficiency of various bioaerosols by these filters. We used a six-jet collision nebulizer to generate microbial aerosols and introduced it into the environmental chamber. We then measured the removal efficiency of functional filters with and without a medium-efficiency filter. Most bioaerosol concentrations did not significantly decrease by the functional filter only but decreased by a combination of functional and medium-efficiency filter. In conclusion, functional filters could facilitate biological removal of various bioaerosols, but physical removal of these by functional was minimal. Proper use of chemical-coated filter materials could reduce exposure to these agents.

Studies on the Characterization of Cellulase Produced by Trichoderma viride QM 9414 (Trichoderma viride QM 9414가 생산하는 Cellulase 특성에 관한 연구)

  • 윤은숙;이혜정
    • The Korean Journal of Food And Nutrition
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    • v.3 no.1
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    • pp.57-68
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    • 1990
  • In order to obtain the fundamental informations on cellulase of Trichoderma viride QM 9414 for its production and utilization, some physico-chemical properties of the enzyme were reviewed. When T. viride QM 9414 was cultured on wheat bran medium, filter paper-disintegrating and carboxymethyl cellulose-saccharifying activity were increased with the cell growth, and thereafter CMC-saccharifying activity was kept on almost the same leved while filter-paper disintegrating activity was decreased sharply. And B-glucosidase was formed maximally on the late stationary phase of growth. The crude cellulase of cell-free extracts was purified by (NH4)2SO4 fractionation, Sephadex-G 200 column chromatography and DEAE Sephadex A-50 column chromatography. Filter paper-disintegrating, CMC-saccharifying and B-glucosidase activity were purified 10-fold, 47-fold and 38-fold, respectively. The crude enzyme was proved to be a complex of three different enzyme proteins which were showing filter paper-disintegrating, CMC-saccharifying and B-glucosidase activity. The optimal pH of the three enzyme components was alike pH 4.0, and the optimal temperature for CMC-saccharifying, filter paper-disintegrating and B-glucosidase activity were 4$0^{\circ}C$, 45$^{\circ}C$ and 5$0^{\circ}C$ respectively. The Km and Vmax values of CMC saccharifying activity for CMC were 0.485% and 3.10, and the Km and Vmax vallues of B-glucosidase for PNPG were 0.944$\times$10-3M and 0.097, respectively. The Km and Vmax values of filter paper-disintegrating activity for Avicel were determined to be 0.09% and 0.178, respectively. B-Glucosidase activity was competitively inhibited by glucose, and the Ki value for this enzyme was 3.54$\times$10-3M, CMC saccharifying activity was found to be greatly inhibited by cellobiose.

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Channels Packed with Porous Media to Improve Water Quality for Irrigation Reservoirs (관개용 저수지 수질개선을 위한 접촉산화수로)

  • Park, Byung-Heun;Jang, Jung-Ryul;Kim, Young-Kyeong;Lee, Kwang-Sik;Kwun, Soon-Kuk
    • Korean Journal of Environmental Agriculture
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    • v.19 no.2
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    • pp.122-127
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    • 2000
  • A stream purification system was applied to the upper reaches of the Masan Reservoir to improve the water quality. This system consisted of two channels which were constructed on both sides of the stream, one side packed with crushed gravels and the other with plastic filter media. The system operated under low pollutant concentrations and high hydraulic loadings during a dry season to avoid clogging of the filter media. Removal rate and efficiency of chemical oxygen demand (COD) in the channel packed with crushed gravel were $14.8g/m^3/d$ and 11.5%, and for the channel with plastic filter media, $50.1g/m^3/d$ and 13.5%, respectively. Removal efficiencies of total phosphorus (T-P) were 6.6% (gravel) and 10.0% (plastic media). These results indicated plastic filter media having relatively high specific surface areas were more efficient than crushed gravels in removing pollutants. However, due to low influent water quality during dry season, the removal efficiencies were low. The proportion of nitrate nitrogen to total nitrogen (T-N) of the inflow was high but, as the system operated under aerobic condition, nitrate nitrogen could not denitrified. Accordingly, total nitrogen was not attenuated with this system. To improve the reservoir water quality effectively, this system should be able to treat the storm runoff containing higher pollutant loadings. When the filter materials are clogged by the storm runoff instead of backwashing, it would be more efficient to replace them, Therefore, the use of natural materials which are light, easily obtaining and replaceable, and have high specific surface areas is recommended.

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