• Journal of the Mineralogical Society of Korea
• /
• v.10 no.1
• /
• pp.33-44
• /
• 1997

The reaction path of water-gneiss in 200m borehole at the Soorichi site of Yugu Myeon, Chungnam was simulated by the EQ3NR/EQ6 program. Mineral composition of borehole core and fracture-filling minerals, and chemical composition of groundwater was published by authors. In this study, chemical evolution of groundwater and formation of secondary minerals in water-gneiss system was modelled on the basis of published results. The surface water was used as a starting solution for reaction. Input parameters for modelling such as mineral assemblage and their volume percent, chemical composition of mineral phases, water/rock ratio reactive surface area, dissolution rates of mineral phases were determined by experimental measurement and model fit. EQ6 modelling of the reaction path in water-gneiss system has been carried out by a flow-centered flow through open system which can be considered as a suitable option for fracture flow of groundwater. The modelling results show that reaction time of 133 years is required to reach equilibrium state in water-gneiss system, and evolution of present groundwater will continue to pH 9.45 and higher na ion concentration. The secondary minerals formed from equeous phase are kaolinite, smectite, saponite, muscovite, mesolite, celadonite, microcline and calcite with uincreasing time. Modeling results are comparatively well fitted to pH and chemical composition of borehole groudwater, secondary minerals identified and tritium age of groundwater. The EQ6 modelling results are dependent on reliability of input parameters: water-rock ratio, effective reaction surface area and dissolution rates of mineral phases, which are difficult parameters to be measured.

• Applied Chemistry for Engineering
• /
• v.34 no.2
• /
• pp.180-185
• /
• 2023

To improve the efficiency of water electrolysis, it is essential to develop an oxygen evolution reaction (OER) electrocatalyst with high performance and long-term stability, accelerating the reaction rate of OER. In this study, a hollow metal-organic framework (MOF)-derived ruthenium-cobalt oxide catalyst was developed to synthesize an efficient OER electrocatalyst. As the synthesized catalyst increases the surface exposure of ruthenium, a low overpotential (386 mV) was observed at a current density of 10 mA/cm² with a low Tafel slope. It is expected to be able to replace noble metal catalysts by showing higher mass activity and stability than commercial RuO₂ catalysts.

• Journal of Electrochemical Science and Technology
• /
• v.11 no.3
• /
• pp.220-237
• /
• 2020

Modern electrochemical energy devices involve generation and reduction of fuel gases through electrochemical reactions of water splitting, alcohol oxidation, oxygen reduction, etc. Initially, these processes were executed in the presence of noble metal-based catalyst that showed low overpotential and high current density. However, its high cost, unavailability, corrosion and related toxicity limited its application. The search for alternative with high stability, durability, and efficiency led scientists towards carbon nanoparticles supported catalysts which has high surface area, good electrical conductivity, tunable morphology, low cost, ease of synthesis and stability. Carbon nanoparticles are classified into two groups based on morphology, one and zero dimensional particles. Carbon nanoparticles at zero dimension, denoted as carbon dots, are less used carbon support compared to other forms. However, recently carbon dots with improved electronic properties have become popular as catalyst as well as catalyst support. This review focused on the recent advances in electrocatalytic activities of carbon dots. The mechanisms of common electrocatalytic reactions and the role of the catalysts are also discussed. The review also proposed future developments and other research directions to overcome current limitations.

• Proceedings of the Korean Society of Rheology Conference
• /
• 2001.06a
• /
• pp.11-14
• /
• 2001

Our study have aimed to identify the deformation and breakup mechanism of minor phase in polymer blends under uniaxial enlongational flow. Experimentally, we measured the transient elongational viscosity of PS/HDPE blends using the uniaxial elongational rheometer at two temperatures. And we observed the evolution of blend morphology with elongation time. Morphological change was observed by quenching the specimen after deformation. If the viscosity variation of PS was compared with that of HDPE at each temperature, PS showed larger temperature dependence than HDPE. At 155$^{\circ}C$, the dispersed phase of larger size were easily affected by affine deformation. The initial spherical shape changed to flat ellipsoid at first, then flat ellipsoid to bulbous shape, and bulbous to thin thread and its satellites. But dispersed phase of smaller size showed the change from sphere to ellipsoid. At 175$^{\circ}C$, the dispersed phase were mostly deformed from spherical shape to ellipsoid. As a result, the morphological change of dispersed phase in elongational deformation is affected by chain flexibility and viscosity ratio. We need to further study to make sure the mechanism of elongation of viscoelastic polymer blends.

• Korean Journal of Materials Research
• /
• v.30 no.12
• /
• pp.709-714
• /
• 2020

For zinc-air batteries, there are several limitations associated with zinc anodes. The self-discharge behavior of zinc-air batteries is a critical issue that is induced by corrosion reaction and hydrogen evolution reaction (HER) of zinc anodes. Aluminum and indium are effective additives for controlling the hydrogen evolution reaction as well as the corrosion reaction. To enhance the electrochemical performances of zinc-air batteries, mechanically alloyed Zn-Al and Zn-In materials with different compositions are successfully fabricated at 500rpm and 5h milling time. Investigated materials are characterized by X-ray diffractometer (XRD), field emission scanning electron microscope (FE-SEM), and energy dispersive spectrometer (EDS). Alloys are investigated for the application as novel anodes in zinc-air batteries. Especially, the material with 3 wt% of indium (ZI3) delivers 445.37 mAh/g and 408.52 mAh/g of specific discharge capacity with 1 h and 6 h storage, respectively. Also, it shows 91.72 % capacity retention and has the lowest value of corrosion current density among attempted materials.

• Rapid Communication in Photoscience
• /
• v.1 no.2
• /
• pp.42-42
• /
• 2012

• Journal of The Korean Astronomical Society
• /
• v.13 no.1
• /
• pp.9-14
• /
• 1980

The abundances of simple molecules are examined in terms of the time-dependent cloud evolution. The formation and destruction mechanisms of $H_2CO$ are reviewed. The average value of the fractional abundance of $H_2CO$ is derived to be in the range of $10^{-10}\;to\;5{\times}10^{-9}$. This is comparable to the observed values. The expected variations of the molecules formed from or destroyed by CO, CI, and $C^+$ whose abundances depend on the evolutionary state of the cloud are discussed.

• The Bulletin of The Korean Astronomical Society
• /
• v.40 no.2
• /
• pp.28.1-28.1
• /
• 2015

Open clusters are one of stellar systems consisting of a few hundreds to thousands of stars. The cluster members are, in general, believed to be a coeval stellar population at the same distance, and therefore they have almost the same properties in chemical composition and kinematics. Owing to these advantages, the clusters are utilized in many astronomy studies, such as the calibrations of distance and stellar age scales, assessments of stellar evolution theories, and the chemical evolution of the Galactic disk. Young open clusters are, inter alia, superb objects to study star formation process as most of stars are known to be formed in clusters. In this talk, I will review the uses of these young open clusters in star formation studies based on the ongoing work of our research group on the stellar initial mass function, an age spread problem, mass accretion rate of pre-main sequence stars, and a feedback of high-mass stars on surroundings.

• Korea-Australia Rheology Journal
• /
• v.13 no.2
• /
• pp.89-95
• /
• 2001

Effects of particulate size and frictional characteristics were examined on the melting behavior of PP(polypropylene) in a twin screw extruder. Powder and pellet types of PP were used and each component was blended with PE(polyethylene) wax and clay, respectively. It was observed that small size particulates, 1.e. powder systems exhibit accelerated melting behavior; and it was also found that the abrasive auditive acts as an effective agent for fast melting of PP powder. Retardation of melting due to the reduced friction was observed in both types of PP, contrary to the result found in a batch mixer. The tendency observed in variation of torque and exit temperature was explained in terms of frictional effect and length of compacted region formed during evolution of melting.

• Journal of The Korean Astronomical Society
• /
• v.40 no.4
• /
• pp.83-89
• /
• 2007

A new type of object called "Very Low Luminosity Objects (VeLLOs)" has been discovered by the Spitzer Space Telescope. VeLLOs might be substellar objects forming by accretion. However, some VeLLOs are associated with strong outflows, indicating the previous existence of massive accretion. The thermal history, which significantly affects the chemistry, between substellar objects with a continuous low accretion rate and objects in a quiescent phase after massive accretion (outburst) must be greatly different. In this study, the chemical evolution has been calculated in an episodic accretion model to show that CO and $N_2H^+$ have a relation different from starless cores or Class 0/I objects. Furthermore, the $CO_2$ ice feature at $15.2{\mu}m$ will be a good tracer of the thermal process in VeLLOs.