• Journal of the Korean Chemical Society
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• v.35 no.5
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• pp.553-559
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• 1991

The elution characteristics of rare earth elements in $NH^{4+}$ form cation exchange resin had been investigated. Elution were performed varing the loading amount, column diameter, column length and eluent pH. Analysing the chemical species contained in each effluent, elution mechanisms of rare earth elements and the separation of rare earth elements in monazite could be understood. The resolution values of adjacent rare earth elements were improved increasing rare earths adsorption amount wfith the same column within it's exchange capacity. With $NH^{4+}$ resin form, column length does not affect on the resolution values and retention time of rare earth elements and the rare earth-EDTA complex were not adsorbed on $NH^{4+}$ resin form. pH of eluent affected on the reactivities between rare earth elements and EDTA. Decreasing eluent pH, resolution values of adjacent rare earth elements were increased while increasing elution time.

• Journal of Photoscience
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• v.9 no.2
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• pp.460-462
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• 2002

Absorption spectra of biological specimens in the soft X-ray region have been presented with special reference to the XANES (X-ray absorption Near Edge Structure) of constituent elements. Absorption spectrum in this wavelength region is characterized by the absorption edges from which elemental content could be derived. In addition, XANES has a characteristic profile for chemical environment around the element such as chemical bond. Using the specific absorption peak we can assign not only the chemical bond but also molecules having such a chemical bond. In the present paper, absorption spectrum of DNA was measured in the wavelength range from 1.5nm to 5nm. Spectrum of Chinese Hamster Ovary (CHO) cells was compared with the DNA spectrum. XANES were distinct at the K absorption edges of major elements, C, N and O. In the spectrum of the cells prominent peaks at the L absorption edge of minor element Ca were also detectable. XANES profiles in small local areas in a cell could also be measured in combination with X-ray microscopy. These give information about local chemical environment in a cell. XANES at the phosphorus K absorption edge in a human HeLa cell was successfully obtained corresponding to a sharp and intensive XANES peak of DNA.

• Bulletin of the Korean Space Science Society
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• 2008.10a
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• pp.22.3-22.3
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• 2008

We present the results of the investigations of high dispersion spectra of two stars. These are the eclipsing binary RR Lyn, and $\rho$ Pup - the prototype of the group of pulsating variables. The spectra were obtained at 1.8 m Bohyuunsan observatory telescope, and 8.2 m VLT. We found the chemical composition. The both components of RR Lyn are Am stars (metallic line stars), but the abundance patterns of the components are not similar - the iron abundance and the abundances of other elements are surely different. For few elements the differences exceeds 1 dex. We found the abundances of 56 chemical elements in the atmosphere of $\rho$ Pup. This is one of the best stellar abundance patterns. It permits to investigate the role of the charge-exchange reactions in stellar atmospheres. These reactions can produce the abundance anomalies in the atmospheres of B-F type stars. These reactions can be one of the sources of galactic cosmic rays, and the reason of the braked rotation of A-F type chemically peculiar stars.

• Carbon letters
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• v.10 no.2
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• pp.123-130
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• 2009

Multi-elements doped $TiO_2$ was prepared as a new photocatalyst in order to decrease the band gap of $TiO_2$ by sol-gel process which can provide the large active sites of $TiO_2$. Multi-elements were doped by using a single precursor, tetraethylammonium tetrafluoroborate (TEATFB). By the benefit of large specific surface area of $TiO_2$ prepared by sol-gel process, catalysts showed initial fast removal of dye. The photoactivity showed that the doped catalysts significantly promote the light reactivity than undoped $TiO_2$. The commendable photoactivity of prepared catalysts is predominantly attributable to the doping of anions which may reduce the band gap.

• Bulletin of the Korean Chemical Society
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• v.29 no.7
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• pp.1391-1394
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• 2008

Polymer materials are very difficult to decompose for the purpose of chemical analysis. Nondestructive analysis without pretreatment provides a suitable solution that will overcome this obstacle. In this study, CRM candidate samples that contained toxic elements such as As, Cd, Cr and Zn in a polypropylene (PP) were analyzed using instrumental neutron activation analysis (INAA). The analytical results were obtained from ten samples selected by random sampling at two different concentration levels (low and high). Particular attention was paid to reducing analytical errors and evaluating the associated uncertainty.

• Bulletin of the Korean Chemical Society
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• v.6 no.1
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• pp.3-7
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• 1985

The general formulas for SCF atomic orbitals |5s > and |6p > have been derived separately by expressing the spherical harmonics part in terms of the coordinate($r_1,\;$r_2$) of the reference point, and by translating the exponential part, $r^4\;exp\;(-{\beta}r)$), in terms of $r_1,\;and\;r_2$ and the modified Bessel functions. Master formulas for overlap and dipole moment matrix elements are derived. The computed values of overlap and dipole moment matrix elements for hypothetical NO molecule are exactly in agreement with those for the previous methods.

• Journal of Astronomy and Space Sciences
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• v.37 no.3
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• pp.157-163
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• 2020

High resolution spectroscopic observation of V1719 Cyg were made at 1.8 meter telescope of Bohyunsan Optical Astronomy observatory in Korea. Spectral resolving power was R=45,000, signal to noise ratio S/N>100. The abundances of 28 chemical elements from carbon to dysprosium were found with the spectrum synthesis method. The abundances of oxygen, titanium, vanadium and elements with Z>30 are overabundant by 0.2-0.9 dex with respect to the solar values. Correlations of derived abundances with condensation temperatures and second ionization potentials of these elements are discussed. The possible influence of accretion from interstellar environment is not so strong as for ρ Pup and other stars with similar temperatures. The signs of accretion are absent. The comparison of chemical composition with solar system r- & s-process abundance patterns shows the enhancement of the photosphere by s-process elements.

• Journal of the Korean Chemical Society
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• v.31 no.1
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• pp.64-70
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• 1987

Rare earth elements including Y and Th in the monazite were separated and determined by X-ray fluorescence spectrometry. The matrix effects among the rare earth elements were simultaneously corrected by means of empirical coefficient method. The values of the coefficients were quite dependent on the number of the standards. However, the different set of coefficients led to the same results. The analytical results corrected by the present method agreed with those by the inductively coupled plasma spectrometry.

• Journal of Korean Society of Forest Science
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• v.94 no.2 s.159
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• pp.96-102
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• 2005

This study evaluated the chemical characteristics of rainfall and throughfall in Pinus koraiensis and Larix leptolepis forests. We analyzed pH, EC, and concentrations of cations and anions in rainfall, throughfall and stemflow collected from both forest types in the experimental forests of the central Korea. The concentrations of chemical elements were much higher in throughfall and stemflow than in rainfall for both forest types, and were significantly different among the seasons. Comparing the chemical elements between the P. koraiensis and L. leptolepis plantations, there were not significantly differences in throughfall, but the concentrations of almost elements of stemflow in P. koraiensis were almost lower than those in L. leptolepis. For seasonal inputs to the forest floor, more than half of the total input of $Ca^{2+}$, ${NO_3}^-$and ${SO_4}^{2-}$ was observed in spring. This suggests that air pollutants such as NOx and SOx accompanying calcium-rich aeolian Yellow Sand (Asian dust) from China could have an important influence on nutrient cycles in Korean forests.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.11a
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• pp.61-64
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• 2003

This study was conducted to investigate the chemical characteristics of $PM^{10}$ at Anmyeon-do during the periods from January 1998 to December 2001. The $PM^{10}$ samples ($PM^{10}$) were collected by High Volume Air sampler (HVAS). The measured items were mass concentration of $PM^{10}$ with the major ions ($Cl^{-}$, ${SO_{4}}^{2-}$, ${NO_3}^{-}$, ${Mg}^{2+}$, ${Ca}^{2+}$, ${K}^{+}$etc.) and metallic elements (AI, Fe, Mn, Cr, Zn, Pb etc.). The chemical analysis of major ion components were made by Ion Chromatography (DX-500) and that of metallic elements were made by Inductively Coupled Plasma Spectrometer (ICP-AES, ICP-Mass). The average mass concentration of $PM^{10}$ increased substantially during the heavy dust periods (Asian Dust cases). For water-soluble ions, concentrations of ${Ca}^{2+}$, ${SO_{4}}^{2-}$ and ${NO_3}^{-}$ were remarkably enhanced. Concentrations and mass fraction of crustal elements such as Na, Mg, Ca, Fe, Mn were highly elevated, but those of pollution-derived heavy metals were appreciably decreased. The factor analysis was conducted in order to make the large and diverse data set as manageable levels and to qualitatively examine the relationship between the variables.