• Title/Summary/Keyword: chemical elements

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A Study in Packing of Changran-Jeotgal -2. Shelf-life a Plastic Pouch racking of Changran-Jeotgal- (창란젓갈의 포장에 관한 연구 -2. 파우치 포장 젓갈의 품질유지기한-)

  • Yoon Ji Hye;Lee Won Dong;Lee Won Dong;Kang Ji Hee;Lee Myung Suk
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.1
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    • pp.15-20
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    • 2002
  • Quality variation of plastic pouch packing of Changran-Jeotgal produced by improved process and conventional process were investigated during storage at 10, 20 and $30^{\circ}C$, respectively. The kind of plastic pouch used in this study were polyethylene/nylon/linear low density polyethylene (PE/Ny), polyethylene terephthalatefpolyethyleneflinear low density polyethylene (PET) and low density polyethylene (PE). In the higher storage temperature, the faster increase of$ CO_2$, concentration and volume of pouch packing in all kinds of pouch. However, the highest value of pH, L-value, volatile basic nitrogen (VBN) and viable cell counts were shown in PE, the next was PET and PE/Ny, Overall, Changran-Jeotgal produced by improved process showed a little change of physical and chemical characteristics than conventional process. From above results, relationship between quality parameters were predicted pH, L-value, VBN and sensory score were highly correlated, therefore, these parameters is expected to uses as shelf-life indicated elements in cease of plastic pouch packaging.

A Study on Denitrification by Sulfur-Oxidizing Bacteria for the Industrial Wastewater Contain Fluoride and Nitrogen (불소.질소 함유 폐수의 황산화탈질에 관한 연구)

  • Cho, Nam-Chan;Moon, Jong-Han
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.10
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    • pp.774-781
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    • 2011
  • Nitric acid and hydrofluoric acid are used for acid pickling in zirconium alloy tubing manufacturing process. Nitrate and fluoride in the wastewater were treated by chemical coagulation and SOD (Sulfur Oxidation Denitrification) process. This study is investigated the effect of fluoride concentration and the optimal condition for SOD process. The limited fluoride concentration for SOD process was below 20 mg F-/L. The adjusted pH and alkalinity by NaOH and $NaHCO_3$ was shown to be more effective for removal of nitrate compared with using NaOH. Furthermore, the microbial activator mixed trace elements and ingredient for alkalinity did not only supplement with alkalinity but also enhance the growth and proliferation for sulfur-oxidizing bacteria. As a result, the inorganic industrial wastewater was successfully treated by the microbial activator in SOD process without continuous addition of seed sludge. Finally, SOD process was shown to remove nitrate in industrial wastewater and to contribute the microbial activator for activation of sulfur-oxidizing bacteria.

Prediction of chemical fertilizer consumption in relation to soil fertility improvement and various agriculturai technical factors (토양비옥도(土壤肥沃度) 증진(增進) 및 제(諸) 기술요인(技術要因)에 의(依)한 비료(肥料) 소비추세(消費趨勢) 전망(展望))

  • Ryu, In-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.9 no.3
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    • pp.183-199
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    • 1976
  • 1. The cultivated land in Korea has originally low fertility resulting in high dependence to fertilizers. 2. The total fertilizer requirement calculated by the Office of Rural Development (ORD) in 1976 was about 1,153 thousand mts, and the total amount of supply planned by the Ministry of Agriculture and Fishery was 1,010 thoushand mts which is close to the amount calculated by ORD. However, there is some gap between the amount of recommended (N, 11.6; $P_2O_5$: $K_2O$, 7.3kg/10a> and supply planned (N, 12.0; $P_2O_5$, 6.3; $K_2O$. 4.8kg/10a) fertilizers for each elements per unit area 3. For 15 years from 1960 to 1975 the fertilizer consumption of nitrogen was roughly increased from 200,000 mts to 500,000 mts; phosphorus, from 50,000 to 250,000 mts; potassium, from 10, 000 to 170,000 mts; accounting 2.5, 5, and 17 times of increase respectively. 4. The total fertilizer consumption for 5 years from 1967 to 1971 was about 100,000 mts and another 5years from 1971 to 1975 was 300,000 mts indicating three times increase. 5. The direct factors influenced to the increase of fertilizer consumption in recent years are 1) the dissemination of high yielding Tongil type rice varieties which are resistant to heavy fertilization 2) high price policy for agricaltural products 3) increased cultivation of vegetables:, fruits, and forages which require high level of fertilizers. The indirect factors are 1) dissemination of new improved agricultural techniques, 2, improvement of cultivated land conditions through irrigation system and land reform, 3) increased supply of silicate fertilizers, and 4) increase of farm income. 6. The percentage of total fertilizer consumption by rice (32%) and barley (25%) is about 57%. The ratio of total fertilizer consumption by vegetables and forages is expected to increase greatly. 7. Based on the increasing tendency of cultivated land and yield per unit area for last 10 years in each crop, total fertilizer consumptions in 1980, 1990, and 2000 year are estimated to 1,290,000, 1,580,000 and 1,870,000 mts respectively.

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The Effects of Barley Straw on the Eluviation of Components in the Submerged Paddy Soil (보릿짚시용(施用)이 논 토양성분(土壤成分)의 용탈(溶脫)에 미치는 영향(影響))

  • Suh, Jang-Sun;Kim, Kwang-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.21 no.4
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    • pp.409-415
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    • 1988
  • This study was carried out to investigate the effects of barley straw application on the eluviation of components in submerged paddy soil percolated. The chemical components of soil, percolated water and humus fraction were as follows. $NH{^+}_4$-N in percolated water and soil, $NO{^-}_3$- N in soil were not detected after prime tillering stage by absorption of rice plant. Phosphate was not affected by the application but a little amount was eluviated through a whole period. Eluviation phase of $Ca^{{+}{+}}$ was similar to $Mg^{{+}{+}}$ and the changes of $K^+$, $Na^+$ and $Cl^-$ were almost same patterns, whereas the amount of these eluviated elements in plot applied was higher than non-applied. In the plot applied, eluviation of $SO{^{-2}}_4$ was low during the tillering stage but high after heading stage, whereas the whole amount of eluviation was high during the tillering stage. Eluviation of iron in the plot applied was increased rapidly. Humus type was almost same as type B in the plot applied or not after harvest, and contents of humic acid was about 60 percent.

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Geochemical and Geochronological Studies on Metaigneous Rocks in the Gyemyeongsan Formation, Northwestern Okcheon Metamorphic Belt and their Tectonic Implication (옥천변성대 북서부 계명산층 내 변성화성암류의 지구화학 및 지구연대학적 연구와 그 지구조적 의의)

  • 박종길;김성원;오창환;김형식
    • The Journal of the Petrological Society of Korea
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    • v.12 no.4
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    • pp.155-169
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    • 2003
  • In the northwest Okcheon metamorphic belt, the metaigneous rocks in the Gyemyeongsan Formation have wider chemical ranges for major, trace and REE elements compared with metaigneous rocks in the Munjuri Formation and do not represent bimodal igneous activity which is characteristic for a continental rifting. The metaigneous rocks in the Munjuri Formation are regarded as products of single magmatic evolution, whereas those in the Gyemyeongsan Formation may be formed through multiple magmatic episodes. The felsic metavolcanic rocks in the Gyemyeongsan Formation show weaker Eu negative anomalies compared with those in the Munjuri Formation but those in both formations show similar degrees of enrichment from LREE to HREE. The metabasites in the Munjuri Formation do not show Eu anomalies but those in the Gyemyeongsan Formation show both positive and negative Eu anomalies(0.59

Applied Mineralogy for the Conservation of Dinosaur Tracks in the Goseong Interchange Area (35번 고속도로 고성 교차로 지역 공룡발자국의 보존을 위한 응용광물학적 연구)

  • Jeong Gi Young;Kim Soo Jin
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.3
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    • pp.189-199
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    • 2004
  • Cretaceous sedimentary rocks bearing dinosaur tracks in the Goseong interchange area were studied for their conservation and public display in the aspect of applied mineralogy. Black clay layers alternate with silt layers in the sedimentary rocks. The verical and horizontal fissures are commonly filled with calcite veinlets, supergenetic iron and manganese oxides. The rocks are composed of quartz, albite, K-feldspar, calcite, chlorite, illite, muscovite, and biotite, with minor apatite and rutile. Silt layers are relatively rich in calcite and albite, whereas clay layers are abundant in quartz, illite, and chlorite. Al, Fe, Mg, K, Ti, and P are enriched in the clay layers, while Ca, Na, and Mn in silt. Most of trace elements including V, Cr, Co, Ni, Cs, Zr, REE, Th, and U are enriched in clay layers. Inorganic carbon are present in silt layers as calcite, while organic carbon in black clay layers. The black clay layers were partly altered to yellow clay layers along the fissures, simultaneously with the decrease of organic carbon. Selective exfoliation of clay-rich black and yellow clay layers, calcite matrix of silt layers and calcite infillings of fissures are estimated as the major weakness potentially promoting chemical and physical degradation of the track-bearing rock specimens.

The Oxidation Study of Lead-Free Solder Alloys Using Electrochemical Reduction Analysis (전기화학적 환원 분석을 통한 무연 솔더 합금의 산화에 대한 연구)

  • Cho Sungil;Yu Jin;Kang Sung K.;Shih Da-Yuan
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.1 s.34
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    • pp.35-40
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    • 2005
  • The oxidation of pure Sn and Sn-0.7Cu, Sn-3.5Ag, Sn-lZn, and Sn-9Zn alloys at $150^{\circ}C$ was investigated. Both the chemical nature and the amount of oxides were characterized using electrochemical reduction analysis by measuring the electrolytic reduction potential and total transferred electrical charges. X-ray photoelectron spectroscopy (XPS) was also conducted to support the results of reduction analysis. The effect of Cu, Ag and Zn addition on surface oxidation of Sn alloys is reported. For Sn, Sn-0.7Cu and Sn-3.5Ag, SnO grew first and then the mixture of SnO and $SnO_2$ was found. $SnO_2$ grew predominantly for a long-time aging. For Zn containing Sn alloys, both ZnO and $SnO_2$ were formed. Zn promotes the formation of $SnO_2$. Sn oxide growth rate of Pb-free solder alloys was also discussed in terms of alloying elements.

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Characteristics of composition and surface morphology of soil particles influenced by inorganic acids with different acidity (산해리도가 다른 무기산에 의한 토양 입자 표면 특성)

  • Lee, Dong-Sung;Lee, Kyo-suk;Shin, Ji-Soo;Lee, Jae-Bong;Joo, Ri-Na;Lee, Myong-Youn;Min, Se-Won;Chung, Doug-Young
    • Korean Journal of Agricultural Science
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    • v.42 no.3
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    • pp.191-199
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    • 2015
  • We conducted this research to observe the changes of surface morphology and composition of clay minerals influenced by various concentrations of fluoric acid. Hydrofluoric acid (HA), a solution of hydrogen fluoride (HF) in water, is a colourless solution that is highly corrosive, capable of dissolving many materials, especially oxides. To do this, we treated several concentrations of HA on the ground soil samples collected from the agricultural experimental station located at Chungnam National University to observe the influence of fluoric acid on the changes of surface structures and elemental composition of clay particles. Generally, microscopic examination showed that the HA can not only attack an edge of clay particles but also start at any point where structural defects and weaknesses predisposed sites to acid. The orderly flake arrangement of clay minerals may reflect certain crystal symmetry elements. The ESEM-EDS results of element composition of clay particles influenced by HA indicated the changes of structures of clay minerals. It is also clear from the formation of etch figures and element composition of clay particles that the product layer at least partially dissolved or disintegrated in the presence of acid. Conclusively, the clay structures can be strongly influenced by concentrations of HA, resulting in changes of physical and chemical properties that can determine the behavior of solute transport as well as mobility of ions in soils.

Suitability Verification of Developed Nutrient Solution for Fertigation Culture of Cucumber (Cucumis sativus L.) (오이 관비재배용 개발 배양액의 적정성 검증)

  • Han, Suk-Kyo;Eun, Jong-Seon;Kim, Ho-Cheol;Lee, Yong-Beom;Bae, Jong-Hyang
    • Journal of Bio-Environment Control
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    • v.17 no.2
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    • pp.170-175
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    • 2008
  • To verify suitability of the developed nutrient solution for fertigation culture of cucumber, chemical changes of soil, growth characteristics and yield of cucumber as affected by conventional fertigation method (Control), the developed nutrient solution for fertigation culture (DNF) and Yamasaki cucumber recipe (YCR) were investigated. At 48 days after transplant, photosynthetic and transpiration rate of cucumber leaves were the highest in 3/2 strength of DNF and 1/2 strength of YCR, but not different with the Control, in the later growing period photosynthetic rate was the highest in 3/2 strength of DNF and YCR and was clearly different with the Control, transpiration rate was the highest in 3/2 strength of DNF and 1/2, 1 strengths of YCR. The growth and yield of cucumber, nutrient elements of cucumber leaves except for calcium were more in DNF and YCR than in the Control. Compared with pre-treated loam soil, pH of the soil was low and electric conductivity was high in all treatments, amounts of accumulated phosphorus, potassium, calcium, and magnesium were much in the higher concentrations per the kinds of nutrient solutions. From the above results, it was considered that the developed nutrient solution has suitability as nutrient solution for fertigation culture of cucumber.

UV-Vis and ED-XRF Analyses of Natural Black Colored Pearls from Freshwater Cultured Shells (UV-Vis와 ED-XRF를 이용한 자연 색상의 담수 흑 양식진주 분석)

  • Kim, Hea-Yeon;Park, Jong-Wan
    • The Korean Journal of Malacology
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    • v.24 no.3
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    • pp.243-251
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    • 2008
  • Analyses of UV-Vis spectrum and reflectance are useful tools to identify pearls of which color was naturally made or chemically changed. Contents of some trace elements of pearls by using ED-XRF may give us the information that the pearls were originated from marine shells or freshwater shells, and may give us whether the pearls were chemically treated or not. Three types of chemically untreated pearls, freshwater cultured, Akoya cultured and Tahitian cultured, were treated with silver nitrate. UV-Vis absorbance spectrum of Ag was changed after treatment, and reflectance of pearls was decreased. Absorbance of natural black colored Tahitian cultured pearls at 400, 500 and 700 nm was observed. Natural black colored freshwater cultured pearls showed two characteristic absorption patterns in UV-Vis spectra at 380-400, 480-500 nm. Unlike naturally black colored Tahitian cultured pearls, the absorption spectrum at 700 nm could not be found from black freshwater cultured pearls. Manganese was not detected in the pearls from marine shells, and strontium content of the pearls from marine cultured shells was higher than that from freshwater cultured shells. According to ED-XRF analysis, Ag contents of silver nitrate treated pearls increased as more time passed, because silver ion invaded to nacre layer of the pearls. Since Ag content of the black pearls known as untreated ranged under 0.1%, analysis of Ag content may used to distinguish the black pearls are treated or not in marketplace.

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