• Title/Summary/Keyword: chemical elements

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Preparation and Dissolution Properties of the Eco-glass Fertilizer containing Trace Elements

  • Lee Hoi Kwan;Hwang Sheng Jean;Kang Won Ho
    • Proceedings of the KAIS Fall Conference
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    • 2004.11a
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    • pp.96-98
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    • 2004
  • At the previous papers, we showed that K2O-CaO-P2O5 glasses had a solubility in air so that they could be used for glass fertilizer. In this work, we fabricated the Eco-glass fertilizer containing trace elements such as B, Mg, Zn, Fe, Cu, Co, and Mo by a melt-quenching process and the dissolution properties of these glasses were investigated with pH meter and ICP analyzer. In case of the glasses containing the trace elements, effect of trace elements on the dissolutions is not obvious and ignorant the stability of mother glass. Also, the dissolution amounts of each trace elements depend on the mother glass composition and the quantity of each trace element, and mother glasses determined the dissolving velocity of chemical elements.

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Variation of Chemical Elements due to Hydrothermal Alteration of Kyungju Pyrophyllite Deposits (경주납석광상의 열수변질작용에 따른 원소함량의 변화)

  • Lee, Jae Yeong;Choi, Wook Jin;Kim, Jong Gun;Kim, Sang Wook
    • Economic and Environmental Geology
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    • v.27 no.1
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    • pp.1-9
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    • 1994
  • The Kyungju pyrophyllite deposits were formed by the hydrothermal alteration of andesitic rocks, which were intruded by Cretaceous granite mass. The major minerals are pyrophyllite, kaolinite and chlorite. The deposits may be zoned outward into pyrophyllite zone, silicified pyrophyllite zone and weakly altered zone (propyrilite zone) according to mineral assemblages. Chemical compositions vary in close relation with the mineralogical assemblages: $Al_2O_3$ content is high due to pyrophyllitization at the deposits and altered zones in comparison to andesitic country rocks, while the contents of $Na_2O$, CaO and MgO are generally low due to leaching during the alteration. This variation of chemical elements may be applicable in the geochemical exploration of pyrophyllite deposits.

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Theoretically-based and practice-oriented formulations for the floor spectra evaluation

  • Abbati, Stefania Degli;Cattari, Serena;Lagomarsino, Sergio
    • Earthquakes and Structures
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    • v.15 no.5
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    • pp.565-581
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    • 2018
  • This paper proposes a new analytical formulation for computing the seismic input at various levels of a structure in terms of floor response spectra. The approach, which neglects the dynamic interaction between primary structure and secondary element, is particularly useful for the seismic assessment of secondary and non-structural elements. The proposed formulation has a robust theoretical basis and it is based on few meaningful dynamic parameters of the main building. The method has been validated in the linear and nonlinear behavior of the main building through results coming from both experimental tests (available in literature) and parametric numerical analyses. The conditions, for which the Floor Spectrum Approach and its simplified assumptions are valid, have been derived in terms of specific interval ratios between the mass of the secondary element and the participant mass of the main structure. Finally, a practice-oriented formulation has been derived, which could be easily implementable also at code level.

Chemical Abundances of 93 Planet Host stars

  • Kang, Won-Seok;Lee, Sang-Gak;Kim, Kang-Min
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.2
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    • pp.78.1-78.1
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    • 2010
  • We obtained the spectra of 93 Planet host stars and 73 normal field stars in F, G, K type using BOES at BOAO. We measured the equivalent width of Fe and 13 elements lines using the automatic EW measurement program, TAME(Tools for Automatic Measurement of Equivalent-widths) and estimated the abundances by synth and abfind driver of MOOG code. Since the absence of planets in the normal field stars cannot be "completely" proved, this work focused on the chemical abundances and planet properties of planet host stars, which have the massive planets close to the parent star relatively. We carried out an investigation for the difference of abundances between stars with "Hot Jupiter" and normal field stars with no known planets. We examined the chemical composition of 12 elements, such as Na, Mg, Al, Si, Ca, Sc, Ti, V, Cr, Mn, Co, and Ni by EW measurements, and the S abundances were estimated using synthetic spectrum.

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A QCM-based Sensor System for Detecting NO2 and SO2 (QCM기반 NO2와 SO2 감지용 센서시스템)

  • Hwang, Min-Jin;Shim, Wang Geun;Moon, Hee
    • Korean Chemical Engineering Research
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    • v.51 no.2
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    • pp.285-291
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    • 2013
  • The effects of sensing materials, coating methods, diluent gases, and temperature have been studied in detail to make a quartz crystal microbalance based adsorption sensor system for detecting gases. In particular, sensor elements for detecting $NO_2$ and $SO_2$, that are known as major air pollutants, have been prepared by coating two different polymers, polypyrrole and poly(3,4-ethylenedioxythiophene). The sensor elements prepared in this work have high sensitivity and selectivity for $NO_2$ and $SO_2$ at ppm level concentrations. It was proven that the sensing characteristics and response rate of the sensing elements are highly dependent on the coating method and the loading mass of sensing materials.

Chemical Transformation of Individual Asian Dust Particles Estimated by the Novel Double Detector System of Micro-PIXE

  • Ma, Chang-Jin
    • Asian Journal of Atmospheric Environment
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    • v.4 no.2
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    • pp.106-114
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    • 2010
  • By the application of novel double detector system of micro-PIXE that can detect light elements (Z<14), we made an attempt to provide a thorough discussion on the aging processes of Asian dust (hereafter called "AD") particle by reaction with sea-slat. The elemental spectra and maps obtained from the microbeam radiation of micro-PIXE to individual AD particles were useful for fractionating AD particles into both internally and externally mixed particles. A spatial distribution of elements in a minute domain of single particle obtained by scanning the microbeam irradiation enabled us not only to estimate the chemical mixing state of individual AD particles but also to presume their aging processes in both ambient air and cloud. By calculating the normalized micro-PIXE net count of elements, it was possible to classify individual AD particles into three distinct groups (i.e., (1) Aging type 1: AD particle coated by the gaseous Cl evaporated by the reaction between artificial acids and sea salt; (2) Aging type 2: AD particle mixed with sea salt but no additional reaction with artificial acids; and (3) Non-aged type) A relatively high transformation rate (63.3-75.9%) was shown in large particles (greater than $5.1\;{\mu}m$ in diameter).

Chemical Composition of RR Lyn - an Eclipsing Binary System with Am and λ Boo Type Components

  • Jeong, Yeuncheol;Yushchenko, Alexander V.;Doikov, Dmytry N.;Gopka, Vira F.;Yushchenko, Volodymyr O.
    • Journal of Astronomy and Space Sciences
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    • v.34 no.2
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    • pp.75-82
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    • 2017
  • High-resolution spectroscopic observations of the eclipsing binary system RR Lyn were made using the 1.8 m telescope at the Bohuynsan Optical Astronomical Observatory in Korea. The spectral resolving power was R = 82,000, with a signal to noise ratio of S/N > 150. We found the effective temperatures and surface gravities of the primary and secondary components to be equal to $T_{eff}$ = 7,920 & 7,210 K and log(g) = 3.80 & 4.16, respectively. The abundances of 34 and 17 different chemical elements were found in the atmospheric components. Correlations between the derived abundances with condensation temperatures and the second ionization potentials of these elements are discussed. The primary component is a typical metallic line star with the abundances of light and iron group elements close to solar values, while elements with atomic numbers Z > 30 are overabundant by 0.5-1.5 dex with respect to solar values. The secondary component is a ${\lambda}$ Boo type star. In this type of stars, CNO abundances are close to solar values, while the abundance pattern shows a negative correlation with condensation temperatures.

X-RAY FLUORESCENCE IN RESEARCH ON THE CULTURAL HERITAGE

  • Cechak, Tomas;Kopecka, Ivana;Musilek, Ladislav
    • Journal of Radiation Protection and Research
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    • v.26 no.3
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    • pp.321-326
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    • 2001
  • Radionuclide X-ray fluorescence analysis is a method, which has many advantages for analysing various historic artefacts, as it is relatively cheap, sensitive and non-destructive, and it allows measurements in-situ. However, this analysis has also certain limitations especially concerning sensitivity to chemical elements only, irrespective of the compounds or chemical forms in which these elements have been bonded. In addition, light elements emitting very soft X-rays cannot be measured, and in order to detect a wide range of elements, it is necessary to carry out repeated measurements with different radiation sources. Despite these limitations, valuable information can be obtained about the composition of historic materials and data about the origin and age of these artefacts can be derived. Analyses of wall paintings, ancient metal sculptures or other objects of art provide the basis for historic considerations documented in our results for some objects belonging to the Czech cultural heritage. The results are promising. Thus it is expected that our laboratory will expand its work into more fields of the fine and applied arts.

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A Study on the Determination of Rare Earth Elements by Inductively Coupled Plasma Spectrometry (Inductively Coupled Plasma 법을 이용한 희토류원소의 분석에 관한 연구)

  • Beom Suk Choi;Sun Tae Kim;Young Man Kim;Chong Wook Lee
    • Journal of the Korean Chemical Society
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    • v.29 no.4
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    • pp.382-389
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    • 1985
  • The effect of plasma operational parameters for the determination of rare earth elements(REE) by means of inductively coupled plasma(ICP) spectrometry was investigated. While the increase in the flow rate of carrier gas argon enhanced the sensitivity and lowered the detection limit, significant ionization interferences were observed. The decrease in RF power increased the signal to background ratio. The observation point showing the lowest ionization interference was slightly higher than the position where the spatial profile of the analyte reached the maximum. The detection limits of the spectral lines commonly used for the determination of REE were measured and the spectral lines relatively free from spectral interferences were chosen.

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Preparation of Fluorescence Particles by Spray Pyrolysis (분무열분해법에의한 형광체 입자의 제조)

  • Kang, Yun-Chan;Jung, Kyeong-Youl;Park, Seung-Bin
    • Korean Chemical Engineering Research
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    • v.44 no.3
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    • pp.235-242
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    • 2006
  • Spray pyrosysis is a process to prepare particles and films by evaporating and decomposing droplets of precursor solutions in the order of 1-10 micrometer in diameter. Key elements of the spray pyrolysis process include precursor, solvent, droplet generator, and reactor. Various combination of these 4 elements produces wide range of particles and films. In general. the current status of the spray pyrolysis technology is not quite promising for commercial success. However, this process will be feasible to produce multicomponent functional materials of controlled morphology. In this paper, current status of the spray pyrolysis technology is introduced with the emphasis of production of fluorescence particles.