• Title/Summary/Keyword: chemical diversity

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Study on free and bond glycerines in Biodiesel from PKO(Palm Kernel Oil) and coconut oil (PKO 및 코코넛유래 바이오디젤 중 글리세린함량 분석 방법 개선 연구)

  • Lee, Don-Min;Park, Chun-Kyu;Ha, Jong-Han;Lee, Bong-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.2
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    • pp.348-361
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    • 2015
  • To reduce the effects of greenhouse gas (GHG) emissions, the government has announced the special platform of technologies as parts of an effort to minimize global climate change, and the government distributed biodiesel since 2006 as the further efforts. Although there are some debates about some quality specifications and unbalanced of source (44% from palm oil), more than 400kton/year of biodiesel was produced in 2013. Moreover the amounts will be increased when the RFS is activated. To solve the unbalanced situation and to achieve the diversity of feeds, it is essential that many researches should be considered. Especially, free and bond glycerines are one of the important properties seriously affected to the combustion system in vehicle & cold properties. Previous method (KS M 2412) couldn't cover the biodiesel derived from lauric oil($C_{12:0}$) such as PKO (Palm Kernel Oil), Coconut oil because those compositions are lighter than other conventional biodiesel sources. In this study, we review the existed method and figure out the factors should improve to analysis the glycerine from PKO and Coconut oil biodiesel. Modifying the analysis conditions to enhance the resolution and change the internal standards to avoid the overlapped- peaks between Capric acid ME ($C_{10:0}$) and standard#1(1,2,4-butantriol). From this revised method, we could solve the restrictions of previous methods. And check the possibility of new method to analyze the glycerine in biodiesel regardless of sources.

A Study on the oxidation characteristics of micro-algal bio diesel derived from Dunaliella tertiolecta LB999 (Dunaliella tertiolecta LB999 유래 바이오디젤의 산화특성 연구)

  • Lee, Don-Min;Lee, Mi-Eun;Ha, Jong-Han;Ryu, Jin-Young;Choi, Chang-Yong;Shim, Sang-Hyuk;Lim, Sang-Min;Lee, Choul-Gyun;Lee, Bong-Hee
    • Journal of Marine Bioscience and Biotechnology
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    • v.7 no.1
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    • pp.1-10
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    • 2015
  • Bio diesel has advantages to reduce GHG(Greenhouse Gas) compare with the fossil fuel by using oil comes from plant/animal sources and even waste such as used cook oil. The diversity of energy feeds brings the positive effects to secure the national energy mix. In this circumstance, micro-algae is one of the prospective source, though some technical barriers. We analyzed the bio diesel which was derived from Dunaliella tertiolecta LB999 through the BD100 quality specifications designated by the law. From that result, it is revealed that the oxidation stability is one of the properties to be improved. In order to find the reason for low oxidation stability, we analyzed the oxidation tendency of each FAME components through some methods(EN 14111, EN14112, EN16091). In this study, we could find the higher double bond FAME portion, the more oxidative property(C18:1${\ll}C18:3$) in bio diesel and main unsaturated FAME group is acted as the key component deciding the bio diesel's oxidation stability. It is proved experimentally that C18:3 FAME are oxidized easily under the modified accelerated oxidation test. We also figure out low molecular weight hydrocarbon and FAME were founded as a result of thermal degradation. Some alcohol and aldehydes were also made by FAME oxidation. In conclusion, it is necessary to find the way to improve the micro-algal bio diesel's oxidation stability.

Restoration planning of the Seoul Metropolitan area, Korea toward eco-city

  • Lee, Chang Seok
    • Proceedings of the Korea Society of Environmental Biology Conference
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    • 2003.06a
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    • pp.1-5
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    • 2003
  • In order to prepare a basis for ecological restoration of the Seoul Metropolitan area, ecological diagnoses on soil physico-chemical properties and vegetation structure were carried out. Land use patterns, actual vegetation, and biotope patterns were also investigated based on aerial photograph interpretation and field checks. I formulated landscape elements overlaying those data and evaluated the ecological value of each element. Soil pollution was evaluated by analyzing soil samples collected in each grid on the mesh map, divided by 2km $\times$ 2km intervals. Soil samples were collected in forests or grasslands escaped from direct human interference. Soil pollution evaluated from pH, and SO$_4$, Ca, Mg, and Al contents of soil was more severe in the urban outskirts than in the urban center. Those soil environmental factors showed significant correlation with each other. Vegetation in the urban area was different in species composition from that in suburban areas and showed lower diversity compared with that in the suburban areas. Successional process investigated by population structure of major species also showed a difference. That is, successional trend was normal in suburban areas, but that in urban areas showed a retrogressive pattern. The landscape ecological map of Seoul indicates that the urban center lacks vegetation and greenery space is restricted in urban outskirts. Such an uneven distribution of vegetation has caused a specific urban climate and thereby contributed to aggravation of air and soil pollution, furthermore causing vegetation decline. From this result, it was estimated that such uneven distribution of vegetation functioned as a trigger factor to deteriorate the urban environment. I suggested, therefore, a restoration plan based on landscape ecological principles, which emphasizes connectivity and even distribution of green areas throughout the whole area of the Seoul to solve this complex environmental problem. In this restoration plan, first of all, I decided the priority order for connection of the fragmented greenery spaces based on the distances from the core reserves comprised of green belt and rivers, which play roles as habitats of wildlife as well as for improvement of urban environment. Next, I prepared methods to restore each landscape element included in the paths of green network to be constructed in the future on the bases of such preferential order. Rivers and roads, which hold good connectivity, were chosen as elements to play important roles in constructing green network by linking the fragmented greenery spaces.

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The Quality of Water and Distribution of Vegetation According to Land Use Pattern (토지이용패턴에 따른 하천수질과 식생분포)

  • Oh, Young-Ju;Kang, Byoung-Wha;Kim, Byoung-Woo;Kim, Sung-Pil;Han, Min-Su;Kim, Jin-Ho;Na, Young-Eun
    • Korean Journal of Environmental Agriculture
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    • v.25 no.1
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    • pp.34-39
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    • 2006
  • The land use pattern, water quality and vegetation were investigated in the six tributaries, including Hanggeumcheon and Satancheon of the Namhan hydrosphere, Iksancheon, Jeonjucheon and Gosancheon of the Mankyung hydrosphere as well as Jongeupcheon of the Dongjin hydrosphere. Forest and farmland area were extensive in Hanggeumcheon, Satancheon and Gosancheon. Farmland and livestock area were wide in Iksancheon. Jeonjucheon were occupied with broad urban. Industrial and urban area were extensive in Jongeupcheon. The loading amounts of biochemical oxygen demand (BOD), total nitrogen (T-N), total phosphorus (T-P) of Iksancheon and chemical oxygen demand (COD) of Jeonjucheon were determined to be very high, respectively. The quality of water in Hanggeumcheon, Satancheon and Gosancheon were determined to be good quality. The species diversity was lower in the down stream than in the upper stream except for the Gosancheon. Life form of plane were mostly perennial plane in the upper stream and annual plants in the down stream of rivers. It was estimated that there is high level of disturbance in the down stream of rivers. The quality of water was significantly correlated with farmland and forest area. In conclusion, human impact, such as farmland and housing lot exerted an influence on the disturbance of down stream and the water quality of rivers.

Metal Corrosion Mechanism by Sulfate-reducing and Iron-oxidizing Bacteria in Saline System and its Optimal Inactivation (염수계 철산화균 및 황환원균에 의한 금속 부식 및 최적 제어 방안)

  • Sung, Eun-Hae;Han, Ji-Sun;Kim, Chang-Gyun
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.8
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    • pp.798-807
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    • 2008
  • Due to economic impairment derived from metal corrosion of pumping station installed around coastal area, it was needed for related cause-effect to be investigated for understanding practical corrosion behavior and providing proper control. This research was thus carried out to determine whether the microbe can influence on metal corrosion along with its control in the laboratory. For this study, groundwater was sampled from the underground pump station(i.e. I Gas Station) where corrosion was observed. Microbial diversity on the samples were then obtained by 16S rDNA methods. From this, microbial populations showing corrosion behaviors against metals were reported as Leptothrix sp.(Iron oxidizing) and Desulfovibrio sp.(Sulfur reducing) Iron oxidizing bacteria were dominantly participating in the corrosion of iron, while sulfate reducing bacteria were more preferably producing precipitate of iron. In case of galvanized steel and stainless steel, iron oxidizing bacteria not only enhanced the corrosion, but also generated its scale of precipitate. Sulfate reducing bacteria had zinc steel corroded greater extent than that of iron oxidizing bacteria. In the inactivation test, chlorine or UV exposure could efficiently control bacterial growth. However as the inactivation intensity being increased beyond a threshold level, corrosion rate was unlikely escalated due to augmented chemical effect. It is decided that microbial corrosion could be differently taken place depending upon type of microbes or materials, although they were highly correlated. It could be efficiently retarded by given disinfection practices.

Benthic Marine Algal Flora and Community Structure of Yongho-dong Area in Pusan, Korea (부산 용호동 일대의 저서 해조상 및 군집구조)

  • NAM Ki Wan;KIM Young Sik
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.3
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    • pp.374-384
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    • 1999
  • Benthic marine algal flora and community structure of Yongho-dong area in Pusan, Korea were investigated seasonally in intertidal and subtidal zones by a quadrat method along 5 transect lines from July 1996 to April 1997. In this area, a total of 99 species including 3 blue-green, 13 green, 26 brown and 57 red algae was found. Among them, 33 taxa, together with dominant Ulva pertusa and Corallina pilulifera, occurred throughout the year. Enteromorpha spp. and Ulva spp. vertically distributed in upper and middle zone, while Simphyocladia latiuscula, Chondria crassicaulis, Corallina pilulifera and Sargassum sup. in lower zones. Biomass per unit area exhibited a wide range of variation, from 1,241 g/$m^2$(spring) to 1,648 g/$m^2$(summer) in fresh weight. Maximum and minimum species diversity were recorded in spring and autumn, respectively. Results of the UPGAM cluster analysis suggest that the examined 5 sites can be divided into two groups, sites exposed to open sea (transects 1, 2, 3) and comparatively sheltered sites (transects 4, 5) faced with the Pusan Harbor. The former group is represented by large brown algae, Sargassum and Hizikia, while Ulva pertusa and Lomentaria species are mainly found in the latter group. A calcareous alga, Corallina pilulifera occurred dominantly in both groups throughout the year. In conclusion, number of species in this area was remarkably reduced as compared to the previous data. This result may suggest probably more change of algal vegetation in future, considering the physical and chemical pollutions loaded in the coastal marine environment of this area.

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The Study on Evaluating Value for Developing Traditional Agriculture Technology (고농서에 나타난 전통농업기술의 개발가치 평가)

  • Rhee, Sang Young;Kim, Mi Heui;Choi, Jai Ung
    • Journal of Agricultural Extension & Community Development
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    • v.21 no.3
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    • pp.243-269
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    • 2014
  • Traditional agriculture technology is absolutely valuable not only to preserve biological diversity but construct an eco-friendly agricultural system. As the awareness of food safety has been growing, traditional technologies in the past agriculture literatures have obtained more attention sine chemical or synthesized fertilizer and agricultural pesticide were not used in these traditional agriculture ways. This study aims to evaluate development values on six kinds of agriculture literatures published before initial 1970s using Delphi technique and Correspondence analysis. The domains of assesment are include livestock sanitation, breeding management, feeding program and an extra part which 261 traditional agriculture technologies were first extracted from. From these technologies, livestock experts deducted 228 items and selected items more than 3.0 from all three areas including usefulness, scientific characteristic and economical efficiency utilizing Delphi technique.: 35 items from usefulness, 31 items from scientific characteristic, and 18 items from economical efficiency. The 23 technology items were finalized after adding five modern feasibility items recommended by experts to 18 items gaining more than 3.0 in at least three areas. The agriculture technologies were categorized into four areas where were analyzed using Correspondence analysis. The results revealed that 'sustainable farming technology', 'scientific character verification', ' modernized technology development', and 'intellectual property right' were placed closely one another except 'economy efficiency'. The result implicated that scientific verification and economy efficiency should be considered in order to sustain traditional agriculture technology into a modernized way and to protect intellectual property right of these technologies.

Long-term Changes of Fish Ecological Characteristics on the Gwanpyeong Stream Development and the Necropsy-based Health Assessments (관평천 개발에 따른 장기간 어류 생태적 특성 변화 및 해부학적 건강도 평가)

  • Oh, Ja Yun;Lee, Sang-Jae;An, Kwang-Guk
    • Korean Journal of Environment and Ecology
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    • v.34 no.4
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    • pp.282-293
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    • 2020
  • This study investigated a long-term variation trend of water quality, fish compositions, and ecological health conditions in the Gwanpyeong stream located in the nearby Daejeon metropolitan city to understand the impact of urban development projects on the aquatic ecosystem. The sampling was made in four surveys (2009, 2010, 2016, 2019) before and after urbanization. The urban development was conducted in 2008, resulting in the stream's ecological disturbance, and the stream restoration was conducted in 2012. Thus, stream monitoring was conducted to analyze the ecological trends before and after the restoration. The multi-metric models for Fish Assessment Index(FAI) and necropsy-based Health Assessment Index(HAI) were applied in the fish community and organ-level, respectively, to assess the ecological health of the stream. Minimum turbidity and chlorophyll-a(Chl-a) occurred in the mid-stream(St. 2), and this was probably due to rapid current velocity in the riffle zone. We collected 18 fish species, and the dominant species was Zacco platypus (40.6%). In 2016 immediately after the stream restoration, the relative proportions of sensitive species and insectivore species were the highest along with highest values in the species diversity and species richness index, resulting in the best condition in the ecological health, based on FAI model values. However, the ecological health, based on the FAI, became worse in the latest survey conducted in 2019. The analysis of the HAI model based on the organ-level approach showed skin erosion in the fish of upper stream, kidney defects in downstream, and the liver and gill defects observed in all sites, indicating that the anatomical health was also affected.

Development of Roundup Ready Bentgrass for the Control of Poa annua (새포아풀 방제를 위한 Roundup Ready Bentgrass의 개발)

  • Christians, Nick E.;Lee, Jeong-Ho
    • Asian Journal of Turfgrass Science
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    • v.20 no.1
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    • pp.77-82
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    • 2006
  • Annual bluegrass(Poa annua L.) is a problem weed that is very difficult to control on golf courses. There are some reasons that make Poa annua such a difficult weed to be controled. One of these reasons is this plant's ability to reproduce its seed even under stressful conditions. Another reason is its adaptation to low mowing heights. Above all things, the greatest competitive advantage of Poa annua is its genetic diversity. Generally, Poa annua is a bunch type and annual type cool-season grass, but some types act as weak perennials and have stolons. There has been much research on controlling annual bluegrass in golf course turf with chemical and cultural techniques. This research has been conducted for more than 85 years. There has been some progress in controlling some types of Poa annua, but these methods have not been successful on every biotype. Among all of the techniques, Roundup ready creeping bentgrass has the most promise of controlling the diverse types of Poa annua. Roundup ready bentgrass is capable of tolerating the effects of Roundup(glyphosate) while it kills other plants including Poa annua. By using this new technology, we can make Poa annua free greens, tees, and fairways.

Effect of phosphorus application on appearance of algal water bloom and rice yield in rice-barley double cropping system

  • Hwang, Jae-Bok;Bae, Hee-Soo;Park, Tae-Seon;Choi, In-Bae
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.233-233
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    • 2017
  • Algal communities are important to maintain the aquatic ecosystems function. Algae have short life cycles, they respond quickly to environmental change and their diversity and density can indicate and the quality of their habitat. The bloom forms before the rice seedings have emerged, it may present a physical barrier that prevents the seedlings from penetrating the floodwater. Wind may also move the algal bloom, pushing the young plants beneath the surface. Another harmful action develops when the water dries up and the algae form a layer at the bottom of the field. The layer envelops the seedlings, which are not yet deeply rooted, and drag them to the surface when the water is let in again. Soil utilization pattern can be the mail facter affecting soil physico-chemical properties, especially in soil phosphorus (P). Solid content of the algae culture solution increased with the increase in the nitrogen rather the phosphors concentration. Phosphoric acid was treated with conventional treatments (100-0%, before transplanting time-tillering stage), 50-50%, 0-100%, and un-treated. The herbicide was treated on the 7 DAT (day after transplanting). Green algae samples were collected 20 DAT. Total phosphoric acid was the highest at 0.06 in 50-50% treatment in 20 DAT. The amount of green algae was about twice (9.8 mg/20ml) that of un-treated. Total number of green algae was 54 species(Green algae 35 species, Euglena 9 species, Stone wheel 10 species). Among the phosphoric acid treatment methods, the number of occurrences of green algae were the highest with 39 species in 0-100%, followed by 50-50%, 28 species, conventional treatments, 22 species, non-treatment, 18 species, respectively. Rice Yield was not significantly different by phosphoric treatment time, but slightly higher than un-treated. The maximal algal biomass was observed about 2weeks or 1 month after transplanting; the subsequent decrease of the biomass was related to the consumption by grazers and to a deficient light under the rice canopy. Maximal algal growth was observed just before tillering. To estimate the suitable method of phosphorus application in puddled-soil drill seeding of rice, available phosphorus appearance of algal water bloom, and rice yield were investigated in paddy soil of rice-barley double cropping system.

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