• Title/Summary/Keyword: chemical diversity

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The Variation in the Species Composition of the Soil Seed Bank in the Natural Flood Plain Vegetation along the Urban Reach of Han River, South Korea

  • Lee, Hyo-Hye-Mi;Marrs, Rob H.;Lee, Eun-Ju
    • Korean Journal of Ecology and Environment
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    • v.44 no.1
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    • pp.42-57
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    • 2011
  • We described the above-ground plant species composition and measured a range of soil physico-chemical properties and the composition and size of the soil seed bank in the remnant natural vegetations on the flood plains of the Han River within Seoul, South Korea. We used analysis of variance and multivariate analyses to analyse the data and S${\o}$rensen's similarity index to compare the composition of the vegetation and seed banks. The soils were circum-neutral and composed of mainly sand and silt fractions with a very limited clay component; a gradient based on sand/clay proportions was identified. The soil seed banks varied markedly between- and within-sites and had much greater species diversity than the above-ground vegetation. Two of the major dominants in the vegetation (Miscanthus saccariflorus and Phragmites australis) were found at very low densities in the seed bank. The site differences appeared to be correlated with the sand-clay gradient, suggesting that the soil properties differentially affected seed inputs into the soil, or that the processes than controlled sediment deposition during floods was also important in differentially affecting seed deposition. Lastly, there was relatively little similarity between the vegetation, dominated mainly by perennials, and the seed bank which contained a relatively large proportion of annuals and biennials. This result suggests that after disturbance caused by flooding there is the potential for many other species to colonize. This may impinge on the regeneration potential of the sites and cause concern for the future conservation of these important remnants of natural vegetation.

Soil Chemical Properties, Microbial Community and Ginseng Root Rot in Suppressive and Conducive Soil Related Injury to Continuously Cropped Ginseng (인삼 연작장해 유발토양과 억제토양의 화학성, 미생물상 및 뿌리썩음병 발생 특성)

  • Lee, Sung Woo;Lee, Seung Ho;Seo, Mun Won;Jang, In Bok;Kwon, Ra Yeong;Heo, Hye Ji
    • Korean Journal of Medicinal Crop Science
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    • v.28 no.2
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    • pp.142-151
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    • 2020
  • Background: Suppressive soil inhibits soil-borne diseases if pathogens are present, and ginseng does not show injury even if replanted in the same field. Methods and Results: Soil chemical properties and microbial community of soil were investigated in soil suppressive and conducive to ginseng root rot. Root rot disease in 2-year-old ginseng was tested by mixing conducive soil, with suppressive or sterilized suppressive soil. The root rot ratio in suppressive soil was 43.3% compared to 96.7% in conducive soil. Biological factors acted to inhibit the root rot because disease ratio was increased in the sterilized suppressive soil compared to that in non-suppressive soil. The suppressive soil had lower pH, nitrate nitrogen and sodium than the conducive soil. Dominat bacteria and fungi (more than 1.0%) were 3 and 17 species in conducive soil and 7 and 23 species in suppressive soil, respectively. The most predominant fungi were Pseudaleuria sp. HG936843 (28.70%) in conducive soil and Pseudogymnoascus roseus (7.52%) in suppressive soil. Conclusion: Microbial diversity was more abundant in the suppressive soil than in the conducive soil, and the proportion of pathogens (Nectriaceae sp.) causing root rot was significantly lower in the suppressive soil than in the conducive soil.

Six new dammarane-type triterpene saponins from Panax ginseng flower buds and their cytotoxicity

  • Li, Ke-Ke;Li, Sha-Sha;Xu, Fei;Gong, Xiao-Jie
    • Journal of Ginseng Research
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    • v.44 no.2
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    • pp.215-221
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    • 2020
  • Background: Panax ginseng has been used for a variety of medical purposes in eastern countries for more than two thousand years. From the extensive experiences accumulated in its long medication use history and the substantial strong evidence in modern research studies, we know that ginseng has various pharmacological activities, such as antitumor, antidiabetic, antioxidant, and cardiovascular system-protective effects. The active chemical constituents of ginseng, ginsenosides, are rich in structural diversity and exhibit a wide range of biological activities. Methods: Ginsenoside constituents from P. ginseng flower buds were isolated and purified by various chromatographic methods, and their structures were identified by spectroscopic analysis and comparison with the reported data. The 3-(4,5-dimethyl-2-thiazolyl)-2,5-diphenyl-2H- tetrazolium bromide method was used to test their cytotoxic effects on three human cancer cell lines. Results: Six ginsenosides, namely 6'-malonyl formyl ginsenoside F1 (1), 3β-acetoxyl ginsenoside F1 (2), ginsenoside Rh24 (6), ginsenoside Rh25 (7), 7β-hydroxyl ginsenoside Rd (8) and ginsenoside Rh26 (10) were isolated and elucidated as new compounds, together with four known compounds (3-5 and 9). In addition, the cytotoxicity of these isolated compounds was shown as half inhibitory concentration values, a tentative structure-activity relationship was also discussed based on the results of our bioassay. Conclusion: The study of chemical constituents was useful for the quality control of P. ginseng flower buds. The study on antitumor activities showed that new Compound 1 exhibited moderate cytotoxic activities against HL-60, MGC80-3 and Hep-G2 with half inhibitory concentration values of 16.74, 29.51 and 20.48 μM, respectively.

Changes of Soil Properties in Corn (Zea mays L.) Fields Treated with Compost and Liquid Fertilizer (가축분뇨 퇴.액비가 시용된 옥수수 밭토양 특성 변화)

  • Kim, Min-Kyeong;Kwon, Soon-Ik;Kang, Seong-Soo;Jung, Goo-Bok;Kang, Kee-Kyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.3
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    • pp.473-478
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    • 2011
  • A wide diversity of liquid fertilizers and composts produced from the livestock manure in Korea is commonly applied to agricultural lands as an alternative of chemical fertilizers. However, their effects on the crop production and environmental impacts are still vague. The current study was conducted to understand the effects of the pig manure-based liquid fertilizer on the growth of Zea mays L. and soil properties. Four different liquid fertilizers were treated to each cultivated upland plot located in Gyeong-gi province, Korea while no fertilizer (control A) and a chemical fertilizer (control B) were treated to separate plots for comparison. The liquid fertilizer treatment did not make a significant difference in the fresh weight of Zea mays L. compared to the controls. This is probably due to the nutrient residues carried over from the last year fertilization. Electric conductivity (EC) and organic matter contents in soils were increased right after the liquid fertilizer treatments compared to the controls. However, soil pH was maintained as the same as the level of control A. A long-term effect of the continuous treatment of the manure based liquid fertilizer will be carried out in the successive study.

STM Study of 2-Mercaptoethanol Self-Assembled Monolayer on Au(111)

  • Hyeon, Mun Seop;Lee, Chung Gyun
    • Bulletin of the Korean Chemical Society
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    • v.22 no.2
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    • pp.213-218
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    • 2001
  • Presented are the STM images of self-assembled monolayer of 2-mercaptoethanol on Au(111). Striped structures of ($6{\times}3_{\frac{1}{2}}$), ($5{\times}3_{\frac{1}{2}}$), ($4{\times}3_{\frac{1}{2}}$) and compact-($5{\times}3_{\frac{1}{2}}$) were observed after annealing at $80^{\circ}C.$ Analysis of the ordered structures revealed that the basic fundamental units of the ordered structures were three crystallographically non-equivalent ($3_{\frac{1}{2}}{\times}3_{\frac{1}{2}}$) $R30^{\circ}$ assemblies, and that the way of combination of the assemblies produced the four different structures. The($6{\times}3_{\frac{1}{2}}$) structure ( $\theta$ = 0.33) was composed of one ($3_{\frac{1}{2}}{\times}3_{\frac{1}{2}}$)$R30^{\circ}$ assembly, while the ($5{\times}3_{\frac{1}{2}}$) ( $\theta$ = 0.30) and ($4{\times}3_{\frac{1}{2}}$) ( $\theta$ = 0.38) structures were consisted of two ($3_{\frac{1}{2}}{\times}3_{\frac{1}{2}}$) $R30^{\circ}$ assemblies, separated by 5a and 4a, respectively. Furthermore, the compact-(5X 3½) structure ( $\theta$ = 0.50) was obtained by overlapping three ($3_{\frac{1}{2}}{\times}3_{\frac{1}{2}}$) $R30^{\circ}$ assemblies. In spite of the diversity in the adsorption structures, all the adsorption sites of 2-mercaptoethanol were fundamentally identical. On the other hand, the unannealed primitive SAM of 2-mercaptoethanol was characterized by two observations: a short-range order keeping the adsorbed molecules at approximately $3_{\frac{1}{2}}$ a and the small domains of the striped structures supporting that the observed surface structures on the annealed surface were the extension of the primitive layer of 2-mercaptoethanol. Comparing these observations with the already published structures of ethanthiol, it was concluded that the interaction between the hydroxyl groups of 2-mercaptoethanol might play a significant role in the adsorption step of 2-mercaptoethanol on Au(111) to organize the adsorption structures different from those of ethanthiol.

Exploring the Nature of Argumentation in Science Education (과학교육에서 논의의 본성 탐색)

  • Jung, Dojun;Nam, Jeonghee
    • Journal of the Korean Chemical Society
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    • v.66 no.1
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    • pp.50-60
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    • 2022
  • The purpose of this study is to explore the Nature of Argumentation in Science education (NAS). For this purpose, we collected previous studies conducted on the argumentation in science education, and then collected previous studies were analyzed to extract the overall characteristics of argumentation in science education. Based on the results, an expert review was conducted, then the nature of argumentation in science education was finally derived to a total of seven components: 'evidence based', 'linguistic interaction', 'context dependency', 'public decision-making', 'tentative agreement', 'methodological diversity', and 'enculturation of scientific culture'. Understanding the nature of argumentation in science education can promote the practice of argumentation in science learning. Therefore, further studies will be necessary to conduct research to expand and refine the nature of argumentation in science education in order to effectively practice it in science learning.

Complex organic molecules detected in twelve high mass star forming regions with ALMA

  • Baek, Giseon;Lee, Jeong-Eun;Hirota, Tomoya;Kim, Kee-Tae
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.37.3-38
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    • 2021
  • One of the key questions on star formation is how the organic molecules are synthesized and delivered to the planets and comets since they are the building blocks of prebiotic molecules such as amino acid, which is thought to contribute to bringing life on Earth. Recent astrochemical models and experiments have explained that complex organic molecules (COMs; molecules composed of six or more atoms) are produced on the dust grain mantles in cold and dense gas in prestellar cores. However, the chemical networks and the roles of physical conditions on chemistry are not still understood well. To address this question, hot (> 100 K) cores in high mass young stellar objects (M > 8 Msun) are great laboratories due to their strong emissions and larger samples than those of low-mass counterparts. In addition, CH3OH masers, which have been mostly found in high mass star forming regions, can provide constraints due to their very unique emerging mechanisms. We investigate twelve high mass star forming regions in ALMA band 6 observation. They are associated with 44/95 GHz Class I and 6.7 GHz Class II CH3OH masers, implying that the active accretion processes are ongoing. For these previously unresolved regions, 66 continuum peaks are detected. Among them, we found 28 cores emitting COMs and specified 10 cores associated with 6.7 GHz Class II CH3OH masers. The chemical diversity of COMs is found in cores in terms of richness and complexity; we identified up to 19 COMs including oxygen- and nitrogen-bearing molecules and their isotopologues in a core. Oxygen-bearing molecules appear to be abundant and more complex than nitrogen-bearing species. On the other hand, the COMs detection rate steeply grows with the gas column density, which can be attributed to the effective COMs formation in dense cores.

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Chemical signalling within the rumen microbiome

  • Katie Lawther;Fernanda Godoy Santos;Linda B Oyama;Sharon A Huws
    • Animal Bioscience
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    • v.37 no.2_spc
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    • pp.337-345
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    • 2024
  • Ruminants possess a specialized four-compartment forestomach, consisting of the reticulum, rumen, omasum, and abomasum. The rumen, the primary fermentative chamber, harbours a dynamic ecosystem comprising bacteria, protozoa, fungi, archaea, and bacteriophages. These microorganisms engage in diverse ecological interactions within the rumen microbiome, primarily benefiting the host animal by deriving energy from plant material breakdown. These interactions encompass symbiosis, such as mutualism and commensalism, as well as parasitism, predation, and competition. These ecological interactions are dependent on many factors, including the production of diverse molecules, such as those involved in quorum sensing (QS). QS is a density-dependent signalling mechanism involving the release of autoinducer (AIs) compounds, when cell density increases AIs bind to receptors causing the altered expression of certain genes. These AIs are classified as mainly being N-acyl-homoserine lactones (AHL; commonly used by Gram-negative bacteria) or autoinducer-2 based systems (AI-2; used by Gram-positive and Gram-negative bacteria); although other less common AI systems exist. Most of our understanding of QS at a gene-level comes from pure culture in vitro studies using bacterial pathogens, with much being unknown on a commensal bacterial and ecosystem level, especially in the context of the rumen microbiome. A small number of studies have explored QS in the rumen using 'omic' technologies, revealing a prevalence of AI-2 QS systems among rumen bacteria. Nevertheless, the implications of these signalling systems on gene regulation, rumen ecology, and ruminant characteristics are largely uncharted territory. Metatranscriptome data tracking the colonization of perennial ryegrass by rumen microbes suggest that these chemicals may influence transitions in bacterial diversity during colonization. The likelihood of undiscovered chemicals within the rumen microbial arsenal is high, with the identified chemicals representing only the tip of the iceberg. A comprehensive grasp of rumen microbial chemical signalling is crucial for addressing the challenges of food security and climate targets.

Study on the Optical Characteristics of the Green Phosphor for PDP Application (PDP용 녹색 형광체의 광 특성 개선에 관한 연구)

  • Han, Bo Yong;Yoo, Jae Soo
    • Korean Chemical Engineering Research
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    • v.47 no.2
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    • pp.150-156
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    • 2009
  • Plasma Display Panels(PDPs) require to have improved luminous efficiency, low manufacturing cost, and high image quality to compete with other flat display devices such as Liquid Crystal Displays(LCDs) and organic light-emitting diodes(OLEDs). In addition, the diversity of product line-up may be needed for high market share. In this paper, the optical characteristics of typical green phosphor for PDP application are reviewed and the problem-based solution will be proposed. We also shortly describe the principle of 3D-PDPs which are promising. Then, the requirement of green phosphor for 3D-PDP application is summarized and research achievement, as of now, is described. The typical problems of $Zn_2SiO_4:Mn$ phosphor, which is the most well-known, are the negatively charged surface property and the long decay time, which leads to unstable discharge in green cell and afterimage. These problems were solved by coating the phosphor surface with metallic oxide. It was found that $Al_2O_3$ would be the best material for $Zn_2SiO_4:Mn$ phosphor. It gives longevity as well as low operating voltage due to the charging effect in green cells. Also, new phosphors, $(Y,\;Gd)Al_3(BO_3)_4:Tb$ and $(Mg,\;Zn)Al_2O_4:Mn$ phosphor are proposed for increasing the luminance and reducing the decay time, which are capable to apply for 3D-PDP application.

Soil Physico-Chemical Properties and Characteristics of Microbial Distribution in the Continuous Cropped Field with Paeonia lactiflora (작약 연작재배지의 토양 이화학성 및 미생물 분포특성)

  • Park, Jun-Hong;Seo, Yeong-Jin;Choi, Seong-Yong;Zhang, Yong-Sun;Ha, Sang-Keun;Kim, Jang-Eok
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.5
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    • pp.841-846
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    • 2011
  • This study was conducted to obtain the information about injury caused by continuous cropping of peony (Paeonia lactiflora). Soil physico-chemical properties, characteristics of microbial distribution and diversities in the continuous cropped field with peony were analyzed. As the results, pH and organic matter content were higher in the continuous cropping soil than those in the first cropping soil. Bulk density was decreased but porosity was increased in the continuous cropping soil. As the cultivation period was lengthened in years, the populations of bacteria and actinomyces were gradually decreased, whereas fungal population was increased. It was shown that the metabolic diversity patterns of the microbial communities in the continuous cropping soil differed from that of the first cropping soil. These results indicate that deterioration of soil quality such as physico-chemical properties including a soil depth, bulk density, porosity and soil pH is related with a continuous cultivation periods, and also affect a microbial population, especially fungi.