• 제목/요약/키워드: chemical damage

검색결과 1,204건 처리시간 0.028초

할로겐 플라즈마에 의한 Ge2Sb2Te5 식각 데미지 연구 (Investigation of Ge2Sb2Te5 Etching Damage by Halogen Plasmas)

  • 장윤창;유찬영;유상원;권지원;김곤호
    • 반도체디스플레이기술학회지
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    • 제18권4호
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    • pp.35-39
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    • 2019
  • Effect of Ge2Sb2Te5 (GST) chalcogen composition on plasma induced damage was investigated by using Ar ions and F radicals. Experiments were carried out with three different modes; the physical etching, the chemical etching, and the ion-enhanced chemical etching mode. For the physical etching by Ar ions, the sputtering yield was obtained according to ion bombarding energy and there was no change in GST composition ratio. In the plasma mode, the lowest etch rate was measured at the same applied power and there was also no plasma induced damage. In the ion-enhanced chemical etching conditions irradiated with high energy ions and F halogen radicals, the GST composition ratio was changed according to the density of F radicals, resulting in higher roughness of the etched surface. The change of GST composition ratio in halogen plasma is caused by the volatility difference of GST-halogen compounds with high energy ions over than the activation energy of surface reactions.

Pozzolanic properties of trachyte and rhyolite and their effects on alkali-silica reaction

  • Baki, Vahiddin Alperen;Nayir, Safa;Erdogdu, Sakir;Ustabas, Ilker
    • Advances in concrete construction
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    • 제11권4호
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    • pp.299-306
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    • 2021
  • The alkali-silica reaction (ASR) is a highly complex chemical reaction which causes damage to concrete and thus adversely affects the durability and service life. Significant damage can occur in concrete structures due to cracking because of the chemical reactions taking place. Various mineral and chemical additives have been used so far to mitigate ASR and/or to reduce its adverse effects. In this study, ground trachyte and rhyolite provided from Rize-Çağrankaya region, Turkey, were used to investigate their effectiveness in controlling ASR-induced damage by substituting them with cement at certain ratios. In this context, initially the possible use of trachyte and rhyolite as pozzolanas was determined in accordance with BS EN 450-1 and TS 25 standards by considering their pozzolanic activities and then their effectiveness in mitigating the ASR was evaluated as per ASTM C 1567-13. In experimental study, blends of trachyte and rhyolite were prepared by substituting them by cement at 25%, 35%, and 50% percentage. Totally 7 mixes were prepared and three samples of 25×25×285 mm mortar bars were prepared from each batch. The length changes of the mortar bars were determined at the end of 3, 7, 14 and 28 days of exposure. SEM, along with XRD analyses were performed to examine and elementally determine the ASR products that have been formed. The results obtained have shown that ground trachyte and rhyolite used in this study can be used as pozzolanas in concrete and they can also significantly mitigate ASR-induced damage as the substitution ratio increases.

GIS를 활용한 고속도로 염화수소 가스 누출 시나리오 기반 리스크 평가 (Risk Assessment Based on Highway Hydrogen Chloride Gas Leakage Scenario Using GIS)

  • 김구윤;이재준;윤홍식
    • 대한원격탐사학회지
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    • 제37권3호
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    • pp.591-601
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    • 2021
  • 국내의 화학 산업이 지속적으로 발전이 이루어짐에 따라 화학물질의 취급량과 운송량은 매년 증가하고 있다. 우리나라 도로 화물운송은 90%이상을 차지하고 있으며, 화학물질 운송도 대부분 도로를 통해 이루어지고 있다. 이러한 화학물질 운송차량들은 사고가 발생하게 되면 대형사고로 이어질 수 있다. 운송차량은 1차 피해인 교통사고뿐만 아니라 2차 피해인 환경 피해 요인들인 수질오염, 토양오염 등을 발생시킬 가능성이 높다. 본 연구는 반포IC와 서초IC 구간을 연구지역으로 설정하여 염화수소 가스 누출에 대한 시나리오를 작성하여, ALOHA 프로그램을 사용하여 예측거리를 측정하고 거리에 따라 염화수소 가스가 도달한 시간을 분석하였다. 또한 GIS를 이용해 시간별로 발생한 피해 영역에 대해서 인구밀도를 이용한 리스크 평가를 수행하였다. 이를 통해 피해 영역에 대해서 예방·대응 방안의 필요성을 제시하였다.

야생동물에 의한 농작물 피해 사례 (Two Case Studies on Wild Animals Damage and Its Countermeasure)

  • 박덕병;이민수;채종현
    • 농촌지도와개발
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    • 제15권1호
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    • pp.113-144
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    • 2008
  • The objective of this study aims to explore the situation of damage from wild animals in Korea. Through case study on two villages in Injae, Kangwon province and Cheongyang, Chungnam province. This overview summarises the current issues and trends in wild animals damage through two case studies. We found that there are not only to get economic damage but also not to be able to sleep to protect their farm land from animal invading. We suggest to develop physical and chemical instruments not to access their plants in farmland and to increase central and local government's damage repayments.

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Chronological Switch from Translesion Synthesis to Homology-Dependent Gap Repair In Vivo

  • Fujii, Shingo;Isogawa, Asako;Fuchs, Robert P.
    • Toxicological Research
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    • 제34권4호
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    • pp.297-302
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    • 2018
  • Cells are constantly exposed to endogenous and exogenous chemical and physical agents that damage their genome by forming DNA lesions. These lesions interfere with the normal functions of DNA such as transcription and replication, and need to be either repaired or tolerated. DNA lesions are accurately removed via various repair pathways. In contrast, tolerance mechanisms do not remove lesions but only allow replication to proceed despite the presence of unrepaired lesions. Cells possess two major tolerance strategies, namely translesion synthesis (TLS), which is an error-prone strategy and an accurate strategy based on homologous recombination (homology-dependent gap repair [HDGR]). Thus, the mutation frequency reflects the relative extent to which the two tolerance pathways operate in vivo. In the present paper, we review the present understanding of the mechanisms of TLS and HDGR and propose a novel and comprehensive view of the way both strategies interact and are regulated in vivo.

세척시 알칼리에 의한 면섬유의 손상에 관한 연구 (A Study on Alkaline Degradation of Cotton Fabric in Washing)

  • 박선경;김성련
    • 한국염색가공학회지
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    • 제4권2호
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    • pp.69-75
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    • 1992
  • This study was carried out to compare the effect of caustic soda with the effect of caustic potash on cotton fabric. Instead of caustic potash, sodium carbonate similar in chemical composition to caustic potash was used. The damage of cotton cellulose by repeated washing in various alkaline solutions at 8$0^{\circ}C$, 60 rpm was examined. The damage of cotton cellulose by the variation of copper number, carboxyl content, degree of polymerization and retained tensile strength was estimated. The results obtained at this study are as follows; 1. The damage of cotton by caustic soda was severer than caustic potash. The retained tensile strength at 50 washing cycle in caustic soda was 59% and in sodium carbonate was 80%. 2. By adding soap to caustic soda, the damage of cotton fabric decreased because contact area between fabric and air diminished by foam. 3. Detergency of EMPA 101 in caustic soda was lower than sodium carbonate. Consequently, using caustic soda that damage fabric severely and have lower detergency for caustic potash is unreasonable.

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철도노반 보강용 지오그리드의 크리프 및 손상이 장기 인장강도에 미치는 영향평가 (Assessments of the Combined Effect of Installation Damage and Creep on the Long-Term Design Strength of Geogrid for Railroad Reinforcement)

  • 이도희;박태순;조삼덕;이광우
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2004년도 추계학술대회 논문집
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    • pp.1156-1161
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    • 2004
  • The factors affecting the long-term design strength of geogrid for railroad reinforcement can be classified into factors on creep deformation, installation damage, temperature, chemical degradation, biological degradation. Especially, creep deformation and installation damage are considered as main factors to determine the long-term design strength of geogrid. This paper describes the results of a series of experimental study, which are carried out to assess the combined effect of installation damage and creep deformation for the long-term design strength of geogrid reinforcement. In this study, a series of field tests are carried out to assess installation damage of a various geogrids according to different fill materials, and then creep tests are conducted to assess the creep properties of both undamaged and damaged geogrids.

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Adaptive Responses of Escherichia coli for Oxidative and Protein Damage Using Bioluminescence Reporters

  • Min, Ji-Ho;Gu, Man-Bock
    • Journal of Microbiology and Biotechnology
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    • 제14권3호
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    • pp.466-469
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    • 2004
  • The recombinant bioluminescent Escherichia coli strains, DPD2511 and TV 1061 containing the katG and grpE promoters, respectively, from Vibrio fischeri fused to luxCDABE, were used to detect the adaptive and repair responses to oxidative damage caused by hydrogen peroxide $(H_2O_2)$, and protein damage due to phenol. The response ratio, represented as the bioluminescence induced in subsequent inductions of DPD2511 and TV1061 with the mother cells previously induced by each chemical, i.e., $H_2O_2$ and phenol during the previous induction stage, decreased suddenly compared with the ratio of the control culture of each strain, meaning there is a possible adaptive response to stress caused by chemicals. Protein damage due to phenol was completely repaired by the second culturing after the initial induction, as was oxidative damage caused by $H_2O_2$ which was also rapidly repaired, as detected by the recovery of bioluminescence level. This result suggests that E. coli promptly adapt and repair oxidative and protein damage by $H_2O_2$ and phenol completely.