• 제목/요약/키워드: chemical concentrations

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土壤微生物劑處理가 가을배추의 收量에 미치는 影響 (Effect of Soil Microorganisms on Chinese Cabbage(Brassica Campestris L) Yield in Fall Cropping)

  • 김경제
    • 한국유기농업학회지
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    • 제7권2호
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    • pp.107-114
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    • 1999
  • 몇가지 土壤微生物劑의 處理가 배추의 收量과 土壤 및 植物體의 化學成分, 그리고 微生物相에 미치는 影響을 調査하였다. 모든 微生物劑 處理區에서 無處理에 비하여 收量이 增加하였고, 糖度 또한 增加하여 微生物劑의 處理가 배추의 收量뿐만 아니라 品質의 向上에도 매우 效果的이라고 思料되었다. 植物體의 化學成分을 調査한 結果, MPK+Compost 處理區에서 Fe와 Zn 含量이 매우 높았으나 有意性은 없었고, 다른 成分들은 處理區間에서 差異가 없었다. 土壤의 化學成分에서는 Tomi 處理區에서 K와 Mg의 含量이 높았으나, 다른 處理區에서는 差異가 없었다. 土壤의 微生物相을 調査한 結果, 總細菌數에서는 Tomi 處理區가 가장 높았고 Husk+Palma 및 MPK+Husk+Palma 處理區에서도 높게 나타났다. Bacillus는 MPK+Husk+Palma 處理區가 가장 높았고 Husk+Palma와 Tomi 處理區에서도 몹시 增加되었다. Actinomycetes와 fungi에서도 Tomi 處理區가 매우 增加하였으나, 다른 處理區間에는 差異가 없었고, psedomonas에서도 各 處理間에 差異가 없었다.

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습식 화학 공정에 의한 태양전지로부터 고순도 실리콘 회수 및 이를 이용한 태양전지 재제조 (Photovoltaic Performance of Crystalline Silicon Recovered from Solar Cell Using Various Chemical Concentrations in a Multi-Stage Process)

  • 노민호;이준규;안영수;여정구;이진석;강기환;조철희
    • 한국재료학회지
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    • 제29권11호
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    • pp.697-702
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    • 2019
  • In this study, using a wet chemical process, we evaluate the effectiveness of different solution concentrations in removing layers from a solar cell, which is necessary for recovery of high-purity silicon. A 4-step wet etching process is applied to a 6-inch back surface field(BSF) solar cell. The metal electrode is removed in the first and second steps of the process, and the anti-reflection coating(ARC) is removed in the third step. In the fourth step, high purity silicon is recovered by simultaneously removing the emitter and the BSF layer from the solar cell. It is confirmed by inductively coupled plasma mass spectroscopy(ICP-MS) and secondary ion mass spectroscopy(SIMS) analyses that the effectiveness of layer removal increases with increasing chemical concentrations. The purity of silicon recovered through the process, using the optimal concentration for each process, is analyzed using inductively coupled plasma atomic emission spectroscopy(ICP-AES). In addition, the silicon wafer is recovered through optimum etching conditions for silicon recovery, and the solar cell is remanufactured using this recovered silicon wafer. The efficiency of the remanufactured solar cell is very similar to that of a commercial wafer-based solar cell, and sufficient for use in the PV industry.

공동주택 내의 기계환기 설비에 따른 라돈농도 평가 (Evaluation of Radon Concentration according to Mechanical Ventilation Systems in Apartments)

  • 최지원;홍형진;이정섭;유주희;박보람;김가현;윤성원;이철민
    • 한국환경보건학회지
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    • 제47권4호
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    • pp.330-338
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    • 2021
  • Background: This study was conducted to provide background information for the proper management of radon contamination in apartments using mechanical ventilation facilities in residential environments. Objectives: To this end, this study compared and evaluated changes in radon concentrations based on different operating intensities of mechanical ventilation with or without natural ventilation. Methods: For the continuous measurement of radon concentrations, an RAD7 instrument was installed in four apartments equipped with a ventilation system. The measurements were done for comparison of ventilation types and different ventilation intensities ("high", "middle", "low"). Results: The results confirmed that both mechanical and natural ventilation sufficiently reduced the radon concentration in the apartments. In particular, mechanical ventilation at "high" intensity was the most effective. Natural ventilation combined with mechanical ventilation and then natural ventilation alone were the second and the third most effective, respectively. Conclusions: When using ventilation to reduce indoor radon concentrations, it is most effective to operate mechanical ventilation ("high") or natural ventilation and mechanical ventilation at the same time. In cases where mechanical ventilation is available alone, it is recommended to operate it at a minimum of "middle" intensity.

Prediction of Arsenic Uptake by Rice in the Paddy Fields Vulnerable to Arsenic Contamination

  • Lee, Seul;Kang, Dae-Won;Kim, Hyuck-Soo;Yoo, Ji-Hyock;Park, Sang-Won;Oh, Kyeong-Seok;Cho, Il Kyu;Moon, Byeong-Churl;Kim, Won-Il
    • 한국토양비료학회지
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    • 제50권2호
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    • pp.115-126
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    • 2017
  • There is an increasing concern over arsenic (As) contamination in rice. This study was conducted to develope a prediction model for As uptake by rice based on the physico-chemical properties of soil. Soil and brown rice samples were collected from 46 sites in paddy fields near three different areas of closed mines and industrial complexes. Total As concentration, soil pH, Al oxide, available phosphorus (avail-P), organic matter (OM) content, and clay content in the soil samples were determined. Also, 1.0 N HCl, 1.0 M $NH_4NO_3$, 0.01 M $Ca(NO_3)_2$, and Mehlich 3 extractable-As in the soils were measured as phytoavailable As concentration in soil. Total As concentration in brown rice samples was also determined. Relationships among As concentrations in brown rice, total As concentrations in soils, and selected soil properties were as follows: As concentration in brown rice was negatively correlated with soil pH value, where as it was positively correlated with Al oxide concentration, avail-P concentration, and OM content in soil. In addition, the concentration of As in brown rice was statistically correlated only with 1.0 N HCl-extractable As in soil. Also, using multiple stepwise regression analysis, a modelling equation was created to predict As concentration in brown rice as affected by selected soil properties including soil As concentration. Prediction of As uptake by rice was delineated by the model [As in brown rice = 0.352 + $0.00109^*$ HCl extractable As in soil + $0.00002^*$ Al oxide + $0.0097^*$ OM + $0.00061^*$ avail-P - $0.0332^*$ soil pH] ($R=0.714^{***}$). The concentrations of As in brown rice estimated by the modelling equation were statistically acceptable because normalized mean error (NME) and normalized root mean square error (NRMSE) values were -0.055 and 0.2229, respectively, when compared with measured As concentration in the plant.

회귀곡선을 이용한 단시간 노출에 대한 AEGL의 적용 (Apply AEGL for Short Time Exposure Using Regression Curve)

  • 이현진;정태준;이향직;정창모;고재욱
    • 한국가스학회지
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    • 제21권5호
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    • pp.77-82
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    • 2017
  • 노후화 된 공정설비와 공장의 규모 확대 등 유해화학물질 사용량이 증가하고 있으며, 2013년부터 지속적으로 누출에 의한 사고가 발생하는 것을 확인할 수 있다. 장외영향평가에서 누출에 대한 끝점 농도는 ERPG 2로 나타내며, 안전보건공단의 가이드에서 시간에 따라 7분 미만에서 10분의 AEGL 2, 7분 이상 25분 미만일 때는 30분의 AEGL 2값을 사용한다. 기준이 되는 끝점 농도가 시간에 따라 모호하게 사용되고 있어, 사고 발생 시 문제를 야기할 것으로 생각이 된다. 이에 본 연구에서 회귀곡선을 통해 1~10분 사이의 AEGL 값을 도출하고, 동 시간의 Probit function의 0% Lethality 데이터와 비교하였으며, AEGL 결과 값을 사용하여 보다 명확한 시간에 따른 독성누출 평가에 활용될 것으로 생각된다.

비모수검정을 이용한 논침투수 수질의 평가 (Evaluation of Percolated Water Quality of Paddy Fields Using Nonparametric Test)

  • 오승영;김진수;오광영
    • 한국농공학회논문집
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    • 제47권2호
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    • pp.99-110
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    • 2005
  • Characteristics of concentrations of total nitrogen (TN), total phosphorus (TP), and chemical oxygen demand (COD) pollutant in percolated water at four paddy field sites (Soro, Odong, Munui, and Boeun) were investigated by a nonparametric test. Percolation rate measurement and percolated water sampling were taken during irrigation periods at $5{\sim}10$ day intervals. The normality of percolation rate and pollutant concentrations were examined using histogram, boxplot, and the Kolmogorov-Smirnov (K-S) test. Pollutant concentrations in percolated water showed positively skewed distribution. The median concentrations of pollutant were 1.91 mg/L for TN, 0.021 mg/L for TP, and 6.6 mg/L for COD, which were lower than its arithmetic mean concentrations by $35\%$ for TN, $36\%$ for TP, and $13\%$ for COD. The median concentrations of TN and TP differed significantly among sample sites according to the Kruskal-Wallis test. However, median concentrations were not significantly different among month except for TN and TP of Soro and COD of Odong. The percolation load of pollutants during irrigation periods in the study area were estimated at $3.12{\sim}7.75\;kg/ha$ for TN, $0.033{\sim}0.155\;kg/ha$ for TP, and 10.7 kg/ha for COD, which were much lower than respective values reported in Japan.

국내 대기 중 독성 휘발성 유기화합물의 오염 특성(II) -계절 및 지역적 변동 (Characteristics of Atmospheric Concentrations of Toxic Volatile Organic Compounds in Korea (II) - Seasonal and Locational Variations)

  • 백성옥;김배갑;박상곤
    • Environmental Analysis Health and Toxicology
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    • 제17권3호
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    • pp.207-217
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    • 2002
  • This study was designed to investigate the characteristics of atmospheric concentrations of toxic volatile organic compounds (VOCs) in Korea. Target compounds included 1,3-butadiene, aromatics such as BTEX, and a number of carbonyl compounds. In this paper, as the second part of the study, the seasonal and locational concentrations of atmospheric VOCs were evaluated. Sampling was conducted seasonally at seven sampling sites. each of them representing a large urban area (commercial and residential), a small urban area (commercial and residential), an industrial area (a site within the complex and a residential), and a background place in Korea. In general, higher concentrations were found in the petro-chemical industrial site than other sites, while VOCs measured in commercial (heavy -traffic) sites were higher than residential sites. Seasonality of VOCs concentrations were not so much clear as other combustion related pollutants such as sulfur dioxide, indicating that the VOCs are emitted from a variety of sources, not only vehicle exhaust and point sources but fugitive emissions. Except the industrial site, the concentrations of VOCs measured in this study do not reveal any serious pollution status, since the levels did not exceed any existing ambient standards in the U.K. and/or Japan. However, the increasing number of petrol -powered vehicles and the rapid industrialization in Korea may result in the increased levels of VOCs concentrations in many large urban areas in the near future, if there is no appropriate programme implemented for the control of these compounds.

Comparison of Chemical Compositions of Size-segregated Atmospheric Aerosols between Asian Dust and Non-Asian Dust Periods at Background Area of Korea

  • Kim, Won-Hyung;Song, Jung-Min;Ko, Hee-Jung;Kim, Jin Seog;Lee, Joung Hae;Kang, Chang-Hee
    • Bulletin of the Korean Chemical Society
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    • 제33권11호
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    • pp.3651-3656
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    • 2012
  • The size-segregated atmospheric aerosols have been collected at 1100 m site of Mt. Halla in Jeju, a background area in Korea, using 8-stage cascade impact air sampler during Asian dust and non-Asian dust storm periods. Their ionic and elemental species were analyzed, in order to examine the pollution characteristics and composition change between Asian dust and non-Asian dust periods. The major ionic species such as nss-$SO_4{^{2-}}$, $NH_4{^+}$, and $K^+$ were predominantly distributed in the fine particles (below $2.1{\mu}m$ diameter), and besides the $NO_3{^-}$ was distributed more in coarse particle fraction than fine particle. On the other hand, the typical soil and marine species i.e., nss-$Ca^{2+}$, $Na^+$, $Cl^-$, and $Mg^{2+}$, were mostly existed in the coarse particles (over $2.1{\mu}m$ diameter). As well in the elemental analysis of aerosols, the major soil-originated Al, Fe, Ca, and others showed prominently high concentrations in the coarse particle fraction, whereas the anthropogenic S and Pb were relatively high in the fine particle fraction. From the comparison of aerosol compositions between Asian dust and non-Asian dust periods, the concentrations of the soil-originated species such as nss-$Ca^{2+}$, Al, Ca, Fe, Ti, Mn, Ba, Sr have increased as 2.7-4.2 times during the Asian dust periods. Meanwhile the concentrations of nss-$SO_4{^{2-}}$ and $NO_3{^-}$ have increased as 1.4 and 2.0 times, and on the contrary $NH_4{^+}$ concentrations have a little bit decreased during the Asian dust periods. Especially the concentrations of both soil-originated ionic and elemental species increased noticeably in the coarse particle mode during the dust storm periods.

대구지역 공중위생법 규제대상시설의 실내공기중 입자상 오염물질의 계절별 및 지점별 농도분포 특성 (Seasonal and Locational Concentrations of Particulate Air Pollutants in Indoor Air of Public Facilities in Taegu Area)

  • 백성옥;송희봉
    • 한국대기환경학회지
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    • 제14권3호
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    • pp.163-176
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    • 1998
  • In this study, airborne particle samples were obtained to determine the concentrations of particulate air pollutants in indoor and outdoor air of public facilities in Taegu area. Total of 12 public facilities, regulated by the Public Sanitary Law, were selected as sampling sites, which include three underground arcades, one railway and two bus terminals, three general hospitals, and three department stores. In each place, sampling was carried out seasonally during the period of October 1994 to July 1995, and four samples per each site per season were collected both indoors and outdoors simultaneously. After determination of suspended particulate matter (SPM) mass concentrations, the particle samples were divided into two parts for subsequent chemical analysis: one for the analysis of trace elements and the other for water soluble ions. Seasonal levels of SPM appeared to be the highest in spring and the lowest in summer both indoors and outdoors, while locational variations of highest in statioyterminals, and lowest in department stores . SPM concentrations indoors and outdoors did not show any significant differences each other in most places . However, there were significant correlations between indoor and outdoor levels of SPM and other chemical species . These results indicates that indoor SPM levels are likely to be significantly affected by outdoor sources in many places. The most significant source of SPM was estimated to be the resuspension of soil/road dust both indoors and outdoors . The concentrations of toxic heavy metals (Pb, Cd, Cr, Cu) in underground arcades appeared to be very much lower than the established air quality guidelines for underground environments. In addition, it is likely that micro-environmental parameters such as temperature, humidity, and air velocity, play a less significant role than outdoor air quality as a factor affecting the levels of particulate pollutants in indoor environments of public facilities in Taegu area.

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Effect of Organic Selenium (Sel-Plex) on Thermometabolism, Blood Chemical Composition and Weight Gain in Holstein Suckling Calves

  • Ebrahimi, Marzieh;Towhidi, Armin;Nikkhah, Ali
    • Asian-Australasian Journal of Animal Sciences
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    • 제22권7호
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    • pp.984-992
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    • 2009
  • The objective of this study was to determine the effects of milk supplemented with Sel-Plex on thyroid hormones, rectal temperature, plasma glucose and cholesterol concentrations, and body weight in suckling calves. Ten Holstein suckling male calves of approximately 1 month of age were selected and randomly allocated to one of two groups and fed either unsupplemented milk (control) or milk supplemented with 0.3 mg/kg DM Se from Sel-Plex (treated). The animals received treated milk and free choice starter for two months. Dry matter intake for each individual animal was recorded daily throughout the study. The calves were weighed and blood samples were taken weekly. Plasma concentrations of triiodothyronine ($T_{3}$), thyroxin ($T_{4}$) and $T_{3}$-Uptake were determined using radioimmunoassay kits. Plasma cholesterol and glucose concentrations were determined by enzymatic-colorimetric methods. Rectal temperature was recorded at blood sampling time. During the experiment, ambient temperature and relative humidity were recorded at the time of blood sampling and every four hours. Treatment significantly (p<0.01) affected the concentration of $T_{3}$, free $T_{3}$ index ($FT_{3}I$) and ratio of $T_{3}$:$T_{4}$ in plasma. The plasma concentrations of $T_{3}$ in treated calves were 33% higher than in the control. The plasma concentrations of $T_{4}$ (p<0.05), glucose (p<0.01) and cholesterol (p<0.01) were decreased in the treated group. Calves fed Sel-Plex had higher rectal temperature (p<0.01). Plasma free $T_{4}$ index (FT4I) did not differ significantly between the two groups. An increase in body weight was observed (p<0.09) in the treated group. The results indicated that milk fortified with Sel-Plex could increase tissue conversion of $T_{4}$ to $T_{3}$ and therefore improve thermometabolism in suckling calves.