• Applied Chemistry for Engineering
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• v.17 no.1
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• pp.12-15
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• 2006

The purpose of this study was to investigate the effect of reaction conditions, solvents, and surfactants on the average size and size distribution of silica particles in preparing silica fine powders by sodium silicate. Silica fine particles were synthesized by varying kinds of solvents and surfactants using the emulsion method. Span 20, Span 40, Span 60, and Span 80 were used as nonionic surfactants, Dispersing solvents were n-Hexane, n-Heptane, iso-Octane, and n-Decane of the alkane group. In these experiments, it was known that the optimum dispersion stirring time to form the emulsion of the constant size was around 6 min. The mean sizes of silica particles, at a variety of the dispersion stirring speeds, decreased as the dispersion stirring speed increased. Also, in the case of the solvents, the size of the formed silica particles decreased when the molecular weight of the solvent increased. Lastly, in the case of the surfactants, the mean size of silica particles increased as the hydrophobic lipophilic balance (HLB) value of the surfactant decreased.

• Transactions on Semiconductor Engineering
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• v.2 no.2
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• pp.1-9
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• 2024

CMP (Chemical Mechanical Polishing) processes have become essential for creating multilayered component structures in semiconductor manufacturing. Typically, the slurry composition in CMP processes involves a balance of three components such as ceria, dispersant, and deionized water. In this study, we conducted research on the stability of ceria slurries using an amphoteric surfactant with controlled concentrations of AMP (2-Amino-2-methyl-1-propanol). The results indicated pH stabilization influenced by carboxylic (-COOH) groups depending on the AMP concentration. Additionally, there was no occurrence of aggregation in the ceria slurry, confirming the absence of dispersion stability issues.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 1992.03a
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• pp.177-200
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• 1992

A thermo-viscoplastic finite element program was developed to analyze the compression molding of SMC process. Deformation of the material was modelled by using the flow-rule. Heat balance during the process was coupled to the deformation. In the cure study, a kinetic model was adopted to describe the cure behavior. The numerical kinetic model was integrated with the thermo-viscoplastic numerical analysis by adding heat generation due to the chemical reaction of the workpiece in the heat transfer analysis. The integrated finite element program can simulate a whole sequential molding process including deformation, heat transfer, and chemical reaction. A practical SMC molding process with T-shaped substructure was simulated. The simulated results showed good agreements with experiments.

• Applied Chemistry for Engineering
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• v.19 no.6
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• pp.600-603
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• 2008

Tire is one of the key components in automobiles. Especially, most vibrations during driving are resulted from the im-balancing of tire-wheel composites. In this study, this problem has been solved by using glass beads as a balancing material. In addition, the glass beads are coated using several materials to reduce the tendency of aggregation of glass beads.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2001.11a
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• pp.47-48
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• 2001

It is well known that atmospheric aerosols play an important role in the radiation balance of the earth and meteorological processes as well as in atmospheric chemistry. Aerosols may origin from both natural and/or anthropogenic sources. Thus, the chemical composition of aerosols can vary considerably. For example, the chemical composition of marine aerosol has been the subject of a considerable number of investigations, including the evaluation of long-range transport of anthropogenic constituents on the chemistry of the remote marine boundary layer. (omitted)

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.179-179
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• 2012

Low pressure radio-frequency glow discharges are investigated using theoretical modeling and various experimental diagnostic methods. In the calculations, global models and transformer models are developed to understand the chemical kinetics as well as the electrical properties such as the effective collision frequency, the heating mechanism and the power transferred to the plasma electrons. In addition, Boltzmann equation solver is used to compensate the effect of the electron energy distribution function (EEDF) shape in the global model, and the general expression of energy balance for non-Maxwellian electrons is developed. In the experiments, a number of traditional plasma diagnostic methods are used to compare with calculated results such as Langmuir probe, optical emission spectroscopy (OES), optical absorption spectroscopy (OAS) and two-photon absorption laser-induced fluorescence (TALIF). These theoretical and experimental methods are applied to understand several interesting phenomena in low pressure ICP discharges. The chemical and physical properties of low pressure ICP discharges are described and the applications of these methods are discussed.

• Journal of the Korean Chemical Society
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• v.13 no.4
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• pp.309-312
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• 1969

A series of metal ion-2, 5-diamine 1, 4-dihydroxybenzene polymers containing copper(II), nickel(II) or cobalt (II) have been prepared. The structure was postulated on the basis of elementary analysis of polymers. It was found that copper polymer is most likely the coordination polymers by X-ray powder pattern studies. The thermal stability of the polymers was also studied by a simple method, utilizing a thermogravimetric balance. The order of thermal stabilities is Cu(II) > Ni(II) > Co(II). The polymers start to decompose at a relatively low temperature.

• Korean Chemical Engineering Research
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• v.49 no.4
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• pp.423-431
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• 2011

Recentincreasing awareness of the environmental damage caused by the $CO_2$ emission of fossil fuelsstimulated the interest in alternative and renewable sources of energy. Fuel cell is a representative example of hydrogen energy utilization. In this study, Molten Carbonate Fuel Cell system is simulated by using $Aspen^{TM}$. Stack model is consisted of equilibrium reaction equations using $ACM^{TM}$(Aspen Custom Modeler). Balance of process of fuel cell system is developed in Aspen $Plus^{TM}$ and simulated at steady-state. Analysis of performance of the system is carried out by using sensitivity analysis tool with main operating parameters such as current density, S/C ratio, and fuel utilization and recycle ratio.In Aspen $Dynamics^{TM}$, dynamics of MCFC system is simulated with PID control loops. From the simulation, we proposed operation range which generated maximum power and efficiency in MCFC power plant.

• Wind and Structures
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• v.37 no.6
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• pp.445-460
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• 2023

Accurate estimation of modal parameters (i.e., natural frequency, damping ratio) of tall buildings is of great importance to their structural design, structural health monitoring, vibration control, and state assessment. Based on the combination of variational mode decomposition, smoothed discrete energy separation algorithm-1, and Half-cycle energy operator (VMD-SH), this paper presents a method for structural modal parameter estimation. The variational mode decomposition is proved to be effective and reliable for decomposing the mixed-signal with low frequencies and damping ratios, and the validity of both smoothed discrete energy separation algorithm-1 and Half-cycle energy operator in the modal identification of a single modal system is verified. By incorporating these techniques, the VMD-SH method is able to accurately identify and extract the various modes present in a signal, providing improved insights into its underlying structure and behavior. Subsequently, a numerical study of a four-story frame structure is conducted using the Newmark-β method, and it is found that the relative errors of natural frequency and damping ratio estimated by the presented method are much smaller than those by traditional methods, validating the effectiveness and accuracy of the combined method for the modal identification of the multi-modal system. Furthermore, the presented method is employed to estimate modal parameters of a full-scale tall building utilizing acceleration responses. The identified results verify the applicability and accuracy of the presented VMD-SH method in field measurements. The study demonstrates the effectiveness and robustness of the proposed VMD-SH method in accurately estimating modal parameters of tall buildings from acceleration response data.

• Korean Chemical Engineering Research
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• v.48 no.5
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• pp.574-582
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• 2010

In this study, the possibility of a quartz crystal micro-balance(QCM) modification of crystallization of L-Penicillamine and D-Penicillamine with a Vapor Diffused Molecular Assembly Technique and its application to the R-(-)-Mandelic acid and S-(+)- Mandelic acid measurement was investigated. The 3-dimensional structures of L-Penicillamine and D-Penicillamine on the surface of QCM were verified to be different from each other through QCM and AFM analyses. The D-Penicillamine modified QCM had specific recognition to the R-(-)-Mandelic acid, but L-Penicillamine modified QCM had no specificity to the R-(-)-Mandelic acid and S-(+)- Mandelic acid. From these results, it was known that the QCM could be modified with various selective meterials via VDMA, and the chiral isomer such as a Mandelic acid isomer could be detected by using a modified QCM.