• 제목/요약/키워드: chemical balance study

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Characteristics of Coal Slurry Gasification under Partial Slagging Operating Condition (부분 용융 운전 조건에서 석탄슬러리 가스화 운전 특성)

  • Lee, Jin Wook;Chung, Seok Woo;Lee, Seung Jong;Jung, Woohyun;Byun, Yong Soo;Hwang, Sang Yeon;Jeon, Dong Hwan;Ryu, Sang Oh;Lee, Ji Eun;Jeong, Ki Jin;Kim, Jin Ho;Yun, Yongseung
    • Korean Chemical Engineering Research
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    • v.52 no.5
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    • pp.657-666
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    • 2014
  • Coal gasification technology is considered as next generation clean coal technology even though it uses coal as fuel which releases huge amount of greenhouse gas because it has many advantages for carbon capture. Coal or pet-coke slurry gasification is very attractive technology at present and in the future because of its low construction cost and flexibility of slurry feeding system in spite of lower efficiency compared to dry feeding technology. In this study, we carried out gasification experiment using bituminous coal slurry sample by integrating coal slurry feeding facility and slurry burner into existing dry feeding compact gasifier. Especially, our experiment was conducted under fairly lower operation temperature than that of existing entrained-bed gasifier, resulting in partial slagging operation mode in which only part of ash was converted to slag and the rest of ash was released as fly ash. Carbon conversion rate was calculated from data analysis of collected slag and ash, and then cold gas efficiency, which is the most important indicator of gasifier performance, was estimated by carbon mass balance method. Fairly high performance considering pilot-scale experiment, 98.5% of carbon conversion and 60.4% of cold gas efficiency, was achieved. In addition, soundness of experimental result was verified from the comparison with chemical equilibrium composition and energy balance calculations.

A Study on the Safety Improvement in a Venting System from the HCl Release Accident of a Petrochemical Company (석유화학공장의 염화수소 누출사고를 통한 대기벤트 시스템의 안전성 향상 방안)

  • Ma, Byung-Chol;Lee, Keun-Won;Im, Ji-Pyo;Kim, Young-Chul
    • Journal of the Korean Institute of Gas
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    • v.16 no.4
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    • pp.38-43
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    • 2012
  • The purpose of this study is to carry out the consequence analysis of an accident related to the release of Hydrogen chloride occurred in a petrochemical company in Korea and suggest the measures to prevent similar accidents from happening again. The total amount released through the safety valve of HCl Column was calculated based on the rated capacity of the safety valve, the ideal gas equation and mechanical energy balance, respectively. As a result of the calculation, we found that the amount of HCl released through the safety valve was at least 76.8 kg. Also, we predicted the dispersion concentration at the position of the injured workers(more than 350 m away from the accident location) using simulation programs such as PHAST. The results of ALOHA and K-CARM are 304 ppm and 1,700 ppm respectively. However, PHAST calculation indicated that the concentration is less than l ppm. From these results, we can understand that workers were injured by HCl gas released from the safe valve and the concentration of gas might be less than 1 ppm. Also, it is important for toxic gases such as HCl to be vented safely to the atmosphere after scrubbing.

Receptor Model(CMB) and Source Apportionments of VOCs in Seoul Metropolitan Area (수용모델(CMB)을 이용한 수도권 VOCs의 배출원별 기여율 추정)

  • Han, Jin-Seok;Hong, Y.D.;Shin, S.A.;Lee, S.U.;Lee, S.J.
    • Journal of Environmental Impact Assessment
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    • v.14 no.4
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    • pp.227-235
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    • 2005
  • Source contribution for VOCs collected in Seoul metropolitan area was conducted using PAMs (Photochemical assessment monitoring system) data and CMB(Chemical Mass Balance) model8.0, in order to estimate spatial and temporal variations of VOCs source contribution in that area, and also to compare with corresponding emission inventory. VOCs data used in model calculation were collected at 6 different sites of PAMs(Seokmori, Guwoldong, Simgokdong, Bulgwangdong, Jeongdong and Yangpyeong) and 22 out of 56 VOCs species were analyzed from June 2002 to march 2003 and used for CMB model estimation. The result showed that vehicle exhaust, coating and energy combustion were important sources of VOCs in Seoul metropolitan area, averaging 32.6%, 25.5% and 25.1%, respectively. In this study as well as other references, it was revealed that vehicle exhaust is the main contributor of urban area VOCs, but there is remarkable contrast between emission inventory and model estimation. Vehicle exhaust portion is seriously underestimated while coating is usually overestimated in emission estimates, compared to CMB results. Therefore, it is considered to assert and confirm the uncertainty of emission estimates and clarify the distinction between two other source apportionment methods.

Application of Free Water Surface Constructed Wetland for Treating the Agricultural Runoff (강우시 농업 비점오염원 처리를 위한 FWS 인공습지의 적용성 평가)

  • Kang, Chang-Guk;Lee, So-Young;Maniquiz, Marla C.;Kim, Lee-Hyung
    • Journal of Environmental Impact Assessment
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    • v.19 no.1
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    • pp.83-89
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    • 2010
  • The areas for agricultural purposes in Korea are decreasing every year because of urbanization. However, it is still 17.6% of the total national boundary on 2008. Most of the rice paddy fields are located near the waterbodies which require lots of water during rainy season from May to September. Also lots of nitrate and phosphate chemical fertilizers are spread on the fields every year in order to supply the nutrients for vegetation. The excess nutrients is impairs the water quality of rivers and lakes when it is washed out from the fields. The Korean Ministry of Environment (MOE) adapted the new water quality improvement program, which is the Total Daily Maximum Load, to improve the water quality and to protect the aquaecosystems. The constructed wetland is one of the possible ways to treat the agricultural runoff. The constructed wetland on this study area was constructed by MOE in 2007 to evaluate the application of the constructed wetlands. Plant growth continues to increase during the summer until it reaches its highest biomass of 6,032 g/$m^2$ in August and September. More researches about sedimentation, vegetation, water balance, etc. were performed to evaluate the removal efficiency, to find the removal mechanisms and to make the guidelines for design and maintenance.

Improvement of hot work environment in the curing processes of a tire manufacturing company (타이어 제조공장 가류공정의 온열환경 개선에 관한 연구)

  • Lim, Jung-ho;Kim, Tae-Hyeung
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.21 no.1
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    • pp.1-10
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    • 2011
  • Generally, the tire curing process is the process in which the sulfur is added and subsequently the tire is heated to give the tire elasticity. In this process, all kinds of the chemicals in the tire are emitted with a lot of heat. The chemical fume and heat aggravate the work environment. To solve this problem, 92 local exhaust ventilators and 8 gravity ventilators were used, but not satisfactory yet. Preliminary survey showed that the temperatures in the process were very high: 30.3, 32.9 and $37.2^{\circ}C$ at 2, 4 and 6m above the ground level, respectively in the winter (outside temperature was $2^{\circ}C$). It can be imagined that the process is severely hot in the summer time. The higher temperature distribution in the higher space tells us that the hot plume could not be removed with the existing ventilation systems. Therefore, in this study, some alternative ventilation systems were designed. The partitions were used to contain the hot plume to increase the capture efficiency. The gravity ventilators were newly designed to improve the extraction efficiency of hot fume. To satisfy the balance of pressure in the curing process, some supply air system was introduced by renewing the existing air conditioning system. Many alternative solutions were evaluated by using computational fluid dynamics modelling. The best and applicable solution was selected and the existing ventilation system was modified. After implementing the new ventilation system, the hot environment was much improved. The temperature reduction in the curing process was about $6.4^{\circ}C$.

Study of Synergy Effects of Collaboration in News Program between TV Reporter & Producer - Focusing on KBS 2TV - (방송뉴스제작에 있어서 기자.PD 협업의 시너지효과 탐구 - KBS 2TV <뉴스투데이>를 중심으로 -)

  • Hong, Kyung-Soo
    • The Journal of the Korea Contents Association
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    • v.11 no.4
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    • pp.164-176
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    • 2011
  • To get an implication for desirable direction for Collaboration between Reporter & Producer, I found that had 4 modes of collaboration such as, Producer System, Reporter System, Double Reporting System, Co-Work System, and each was distinguished by field cover, on-mic, editing, writing. Producer system and Reporter system got no chemical synergy because of simple array of single reports due to physical assemble. The achievements of collaboration was birth of new news which had different duration, visual, sound & perspective. It also offered fertile soil for new program and genre literacy of 8 o'clock news. The success factor of collaboration was surprisingly turned out to be personnel rather than system. The balance of reporter & producer was also good factor. But the wall between 2 groups was so high that, after disappearance of extraordinary leader, system began to crumble and at last program was repealed.

Effects of Orally-Administered Bifidobacterium animalis subsp. lactis Strain BB12 on Dextran Sodium Sulfate-Induced Colitis in Mice

  • Chae, Jung Min;Heo, Wan;Cho, Hyung Taek;Lee, Dong Hun;Kim, Jun Ho;Rhee, Min Suk;Park, Tae-Sik;Kim, Yong Ki;Lee, Jin Hyup;Kim, Young Jun
    • Journal of Microbiology and Biotechnology
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    • v.28 no.11
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    • pp.1800-1805
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    • 2018
  • Inflammatory bowel disease, including Crohn's disease and ulcerative colitis (UC), is a chronically relapsing inflammatory disorder of the gastrointestinal tract. Intestinal epithelial cells (IECs) constitute barrier surfaces and play a critical role in maintaining gut health. Dysregulated immune responses and destruction of IECs disrupt intestinal balance. Dextran sodium sulfate (DSS) is the most widely used chemical for inducing colitis in animals, and its treatment induces colonic inflammation, acute diarrhea, and shortening of the intestine, with clinical and histological similarity to human UC. Current treatments for this inflammatory disorder have poor tolerability and insufficient therapeutic efficacy, and thus, alternative therapeutic approaches are required. Recently, dietary supplements with probiotics have emerged as promising interventions by alleviating disturbances in the indigenous microflora in UC. Thus, we hypothesized that the probiotic Bifidobacterium animalis subsp. lactis strain BB12 could protect against the development of colitis in a DSS-induced mouse model of UC. In the present study, oral administration of BB12 markedly ameliorated DSS-induced colitis, accompanied by reduced tumor necrosis factor-${\alpha}$-mediated IEC apoptosis. These findings indicate that the probiotic strain BB12 can alleviate DSS-induced colitis and suggest a novel mechanism of communication between probiotic microorganisms and intestinal epithelia, which increases intestinal cell survival by modulating pro-apoptotic cytokine expression.

Potential Feeding Value of Deoiled Rice Bran by Japanese Quails. 2. Effect on Nutrient Utilization

  • Bhanja, S.K.;Verma, S.V.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.8
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    • pp.1144-1148
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    • 2001
  • The implications of incorporating deoiled rice bran (DORB) in diet on the utilization of certain nutrients had been examined through balance studies made with 6- and 10- week-old Japanese quails. The stuffs evaluated in this study had their origin from two different types of processes- a batch extraction (DORB-B) and another continuous process (DORB-C), and each included at 10, 20 or 30% level in an iso-nitrogenous and iso-caloric diet. On chemical analyses, the DORB-B was found to contain crude protein, 19.0; ether extract, 0.79; total ash, 17.05; Ca, 0.11; P, 1.92; glucose, 2.35 and starch 11.22 g/100 g day matter. Corresponding values for DORB-C were 15.02, 1.56, 13.0, 0.40, 2.76, 2.16 and 19.0, respectively. The data on nutrient balances with quails fed diets containing the two-types of DORB suggested no significant (p>0.05) differences in per cent retention of diet dry matter (DM), organic matter (OM), ether extract (EE), gross energy (GE), nitrogen (N), crude fiber (CF), calcium (Ca) or phosphorus (P) content attributable to the extraction process. The age of the birds also appeared to have no significant (p>0.05) effect on nutrient utilization by them. However, the level of inclusion of DORB had a significant (p<0.05) effect on nutrient utilization by quails in that the retention of dietary N, EE, CF, Ca and P was better at lower than at higher levels. It is concluded that the DORB, irrespective of extraction process, can safely be employed upto 20% level in diet of adult Japanese quails without noticeable interference in utilizing the major dietary nutrients.

The Study of Luppe Smelting with Converting Dust and Slag (제강전로 더스트와 슬래그를 이용한 루페제련에 관한 연구)

  • 황용길;이상화;김재일;김연수
    • Resources Recycling
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    • v.7 no.2
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    • pp.39-45
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    • 1998
  • We smelted thc pellets made by mixing the distilled carbon from wlISte Lires, LD converter dust and slag with reduction process in the revcrberatory furnace. Thc obtained results are as follows 1) The removal mte of zinc appears above 97% after T reducing the pellets at $1300^{\circ}C$ for Ihr and the zinc content in the residue are 0.1~D.2%. 2) Under the mixing condition of 500 g LD dust. 150-200 g LD slag and 30-50 g distilled carbon of waste lires the removal raho of zinc shows above 95%, while t the 50-60% Fe remains in the residue. 3) After smelting at $1350^{\circ}C$ for 3hrs, the recovery ratio of pig iron reduced from lhe p pellets containing 15-20% LD slag and 4.1-7.2% distilled carbon of waste tires appears in the range of 89.3-92%. 4) Tbe c chemical composition of the recovered pig iron is 1.7%C, O.05%P, 0.05%S and balance Fe. 5) Tbe recovered dust from the d dust collcctor alter finishing the reduction rcaction appears as a crude zinc oxide conLaining 60% zinc.

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A Study on Development of Automatic Path Tracking Algorithm for LNG Aluminium Plate and Selection of Process Parameters by Using Artificial Intelligence (LNG 알루미늄 판재 가공용 자동 궤적 추적 알고리즘 개발 및 인공지능을 이용한 공정조건 선정에 관한 연구)

  • 문형순;권봉재;정문영;신상룡
    • Journal of the Korean Society for Precision Engineering
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    • v.15 no.8
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    • pp.17-25
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    • 1998
  • Aluminum alloys have low density, relatively high strength and yield strength, good plasticity, good machinability, and high corrosion and acid resistance. Therefore, they are suitable for large containers for the food, chemical and other industries. Large containers are often bodies of revolution consisting of shell courses, stiffening rings, heads and other elements joined by annular welds. Larger containers have longer welds and require greater leak-tightness and higher weld mechanical properties. The LNG tank consists of aluminum plates with various sizes, so its construction should by divided by several sections. Moreover, each section has its own sub-section consisted of several aluminum plates. To guarantee the quality of huge LNG tank, therefore, the precise control of plate dimension should by urgently needed in conjunction with the appropriate selection of process parameters such as cutting speed, depth of cut, rotational speed and so on. In this paper, a manufacturing system was developed to implement automatic circular tracking in height direction and automatic circular interpolation in depth of cut direction. Also, the neural network based on the backpropagation algorithm was used to predict the cutting quality and motor load related with the life time of the developed system. It was revealed that the manufacturing system and the neural network could be effectively applied to the bevelling process and to predict the quality of machined area and the motor load.

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