• Title/Summary/Keyword: chemical and mineral admixtures

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Role of ingredients for high strength and high performance concrete - A review

  • Parande, A.K.
    • Advances in concrete construction
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    • v.1 no.2
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    • pp.151-162
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    • 2013
  • The performance characteristics of high-strength and high-performance concrete are discussed in this review. Recent developments in the field of high-performance concrete marked a giant step forward in high-tech construction materials with enhanced durability, high compressive strength and high modulus of elasticity particularly for industrial applications. There is a growing awareness that specifications requiring high compressive strength make sense only when there are specific strength design advantages. HPC today employs blended cements that include silica fume, fly ash and ground granulated blast-furnace slag. In typical formulations, these cementitious materials can exceed 25% of the total cement by weight. Silica fume contributes to strength and durability; and fly ash and slag cement to better finish, decreased permeability, and increased resistance to chemical attack. The influences of various mineral admixtures such as fly ash, silica fume, micro silica, slag etc. on the performance of high-strength concrete are discussed.

Chloride Diffusion Coefficient at Reference Time for High Performance Concrete for Bridge Pylons in Marine Environment (해상교량 주탑용 고성능 콘크리트의 기준재령 염소이온 확산계수)

  • Yoon, Chul-Soo;Kim, Ki-Hyun;Yang, Woo-Yong;Cha, Soo-Won
    • Journal of the Korea Concrete Institute
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    • v.24 no.4
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    • pp.435-444
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    • 2012
  • High performance concrete mixes are selected and corresponding test specimens are made for the study of chloride diffusion coefficient at reference time. The concrete mixes were same designs as those used in construction of bridges located in a marine environment. Mix design variables included binder type, water-to-binder ratio, mineral admixtures to total binder weight substitution ratio, fine aggregate source, chemical water reducer admixture type for high strength and high flowability, and target slump or slump flow. The test results showed that the diffusion coefficients at reference time varied significantly according to the type of mineral admixtures and their substitution ratios. A model for diffusion coefficient at reference time considering the type of mineral admixture and the substitution ratio was developed. Diffusion coefficients from the developed model were compared with those from literature review, a previous model, and additional test results. All of the comparisons verified that the developed model can reasonably predict diffusion coefficients and the application of the model to the durability design against chloride penetration is appropriate.

Diverse Application of ECC Designed with Ground Granulated Blast Furnace Slag

  • Kim, Jeong-Su;Kim, Yun-Yong;Kim, Jin-Keun
    • International Journal of Concrete Structures and Materials
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    • v.1 no.1
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    • pp.11-18
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    • 2007
  • In the recent design of high ductile engineered cementitious composites (ECC), optimizing both processing and mechanical properties for specific applications is critical. This study employs a method to develop useful ECC produced with slag particles (slag-ECC) in the field, which possesses different fluid properties to facilitate diverse types of processing (i.e., self-consolidating or spray processing). Control of rheological modulation was regarded as a key factor to allow the performance of the desired processing while retaining the ductile material properties. To control the rheological properties of the composite, the basic slag-ECC composition was initially obtained, determined based on micromechanics and steady-state cracking theory. The stability and consequent viscosity of the suspensions were then mediated by optimizing the dosage of the chemical and mineral admixtures. The rheological properties altered through this approach were revealed to be effective in obtaining ECC-hardened properties, represented by pseudo strain-hardening behavior in uniaxial tension, allowing the readily achievement of the desired function of the fresh ECC.

Time dependent equations for the compressive strength of self-consolidating concrete through statistical optimization

  • Hossain, K.M.A.;Lachemi, M.
    • Computers and Concrete
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    • v.3 no.4
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    • pp.249-260
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    • 2006
  • Self-consolidating concrete (SCC) in the fresh state is known for its excellent deformability, high resistance to segregation, and use, without applying vibration, in congested reinforced concrete structures characterized by difficult casting conditions. Such a concrete can be obtained by incorporating either mineral or chemical admixtures. This paper presents the results of an investigation to asses the applicability of Abram's law in predicting the compressive strength of SCC to any given age. Abram's law is based on the assumption that the strength of concrete with a specific type of aggregate at given age cured at a prescribed temperature depends primarily on the water-to-cement ratio (W/C). It is doubtful that such W/C law is applicable to concrete mixes with mineral or chemical admixtures as is the case for SCC where water to binder ratio (W/B) is used instead of W/C as the basis for mix design. Strength data of various types of SCC mixtures is collected from different sources to check the performance of Abram's law. An attempt has been made to generalize Abram's law by using various optimization methodologies on collected strength data of various SCC mixtures. A set of generalized equations is developed for the prediction of SCC strength at various ages. The performance of generalized equations is found better than original Abram's equations.

Influence of Mineral Admixtures on the Resistance to Sulfuric Acid and Sulfate Attack in Concrete (콘크리트의 황산 및 황산염 침투 저항성에 미치는 광물질 혼화재의 영향)

  • Bae, Su-Ho;Park, Jae-Im;Lee, Kwang-Myong
    • Journal of the Korea Concrete Institute
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    • v.22 no.2
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    • pp.219-228
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    • 2010
  • It has been well known that concrete structures exposed to acid and sulfate environments such as sewer, sewage and wastewater, soil, groundwater, and seawater etc. show significant decrease in their durability due to chemical attack. Such deleterious acid and sulfate attacks lead to expansion and cracking in concrete, and thus, eventually result in damage to concrete matrix by forming expansive hydration products due to the reaction between portland cement hydration products and acid and sulfate ions. Objectives of this experimental research are to investigate the effect of mineral admixtures on the resistance to acid and sulfate attack in concrete and to suggest high-resistance concrete mix against acid and sulfate attack. For this purpose, concretes specimens with three types of cement (ordinary portland cement (OPC), binary blended cement (BBC), and ternary blended cement (TBC) composed of different types and proportions of admixtures) were prepared at water-biner ratios of 32% and 43%. The concrete specimens were immersed in fresh water, 5% sulfuric acid, 10% sodium sulfate, and 10% magnesium sulfate solutions for 28, 56, 91, 182, and 365 days, respectively. To evaluate the resistance to acid and sulfate for concrete specimens, visual appearance changes were observed and compressive strength ratios and mass change ratios were measured. It was observed from the test results that the resistance against sulfuric acid and sodium sulfate solutions of the concretes containing mineral admixtures were much better than that of OPC concrete, but in the case of magnesium sulfate solution the concretes containing mineral admixtures was less resistant than OPC concrete due to formation of magnesium silicate hydrate (M-S-H) which is non-cementitious.

Design and Constructibility of an Engineered Cementitious Composite Produced with Cement-based Mortar Matrix and Synthetic Fibers (시멘트계 모르타르 매트릭스를 활용한 섬유복합재료 ECC(Engineered Cementitious Composite)의 설계와 시공 성능)

  • Kim, Yun-Yong
    • Composites Research
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    • v.20 no.2
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    • pp.21-26
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    • 2007
  • This paper summarizes the design procedure and constructibility of an ECC (Engineered Cementitious Composite), which is a synthetic fiber-reinforced composite produced with the Portland cement-based mortar matrix. This study employs a stepwise method to develop useful ECC in construction field, which possesses different fluid properties to facilitate diverse types of processing (i.e., self-consolidating or spray processing). To control the rheological properties of the composite, the aggregates and reinforcing fibers were initially selected based on micromechanical analysis and steady-state cracking theory. The stability and consequent viscosity of the suspensions were then mediated by optimizing the dosage of the chemical and mineral admixtures. The rheological properties altered through this approach were revealed to be effective in obtaining ECC-hardened properties, represented by pseudo strain-hardening behavior in uniaxial tension, allowing the readily achievement of the desired function of the fresh ECC.

Effective Use of Micro Fines (미분의 효과적인 이용에 관한 연구)

  • 백신원
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.73-78
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    • 2001
  • Portland cement concrete is made with coarse aggregate, fine aggregate, portland cement, water and, in some cases, selected chemical admixtures such as air-entraining agents, water reducer, superplasticizer, and so on, and mineral admixtures such as fly ash, silica fume, slags, etc. Typically, in the concrete, the coarse aggregate and fine aggregate will occupy approximately 80 percent of the total volume of the final mix. Therefore, the coarse and fine aggregates affect to the properties of the portland cement concrete. As the natural sands are drained, it is necessary and economical to utilize crushed sands(manufactured fine aggregate). It is reported that crushed sands differ from natural sands in gradation, particle shape and texture, and the micro fines in the crushed sands affect to the quality of the portland cement concrete. Therefore, the purpose of this paper is to investigate the characteristics of fresh and hardened concrete with high content of micro fines. This study provides firm data for the use of crushed sands with higher micro fines.

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Utilization of waste fine tailing separated coarse materials as cement mineral admixture (입도분급을 실시한 폐광미 미립분의 시멘트 혼화재로의 활용)

  • An, Yang-Jin;Yu, Seung-Wan;Mun, Kyoung-Ju;Park, Won-Chun;Soh, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.297-300
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    • 2004
  • The purpose of this study reutilization of waste fine tailing as admixture for cement. We observe tailing's basic properties such as shape, physical and chemical basic features. Also, various admixtures were made of 2 Types of tailings, OPC, fly-ash and blast furnace slag. The basic properties of the cement mortars incorporation with these admixtures were examined and analyzed under a verity of experimental conditions. This work showed that the tailing separated coarse materials could be effectively utilized as replacement materials of cement without any decrease in the strength if we can control the blaine of materials like OPC, slag and fly ash.

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The Properties of Concrete Compressive Strength used Rice Straw Ash (소성된 볏짚을 혼입한 콘크리트 압축강도 특성)

  • Kim, Young-Soo;Shin, Sang-Yeop;Jeong, Euy-Chang
    • Journal of the Regional Association of Architectural Institute of Korea
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    • v.21 no.5
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    • pp.117-124
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    • 2019
  • When manufacturing concrete, several mineral admixture is added to improve the basic physical property and durability and to make economical concrete. Such mineral admixture includes fly ash, granulated blast furnace slag, silica fume, etc., and not only the studies about mixing these mineral admixtures but also the studies for the development of new materials have been steadily in progress. Recently, some researchers have found, as a part of the development of new materials, the rice straw ash can also be used as a pozzolanic material for concrete considering similar chemical properties of rice straw ash to that of rice husk ash. But there has been insufficient amount of study about it. So, this study was to investigate the possibility as mineral admixture of agriculture by-product, by analyzing properties of concretes using rice straw ash with replacement ratio in comparison with other mineral admixture. In order to measure amount of SiO2 of rice straw ash, XRF(X-ray fluorescence) analysis was tested. For the measure pozzolanic reaction of rice straw ash, pH change and color change was tested according to curing day. Also to evaluate properties of concrete using rice straw ash, slump test, air contents test and compressive strength was tested.

Evaluation of Corrosion Resistance using Electro-chemical Methods for the High-Durability Concrete exposed to Marine Condition (해양환경에 노출된 고내구성 콘크리트의 전기화학적기법을 이용한 부식저항성 평가)

  • Yang, Eun-Ik;Kim, Myung-Yu;Lee, Dong-Gun;Han, Sang-Hun
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.19 no.4
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    • pp.320-328
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    • 2007
  • The durability of marine concrete structures is severely degraded by corrosion due to seawater attack and diffusion of chloride in concrete. The deduction of durability causes high repair cost for maintenance of marine concrete structure. So, the applicability of high-durable materials is investigated to improve the durability in marine concrete structures. For these, the characteristics of corrosion prevention of marine concrete structures mixed with the mineral admixtures(SF, FA and BFS), the modified steel(stainless and coating steel), and corrosion inhibitors are evaluated using electro-chemical methods. As a results of this study, it is quantified for the effect of promotion of durability by high-durability materials in marine concrete structures.