• 환경위생공학
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• 제20권3호
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• pp.17-26
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• 2005

Many researches were focused on the data which obtained from chemical bulk analysis. It is difficult to evaluate source contribution by wet type chemical bulk analysis. In this study, we have reviewed the characterization of individual particle for source identification. We analyzed by SEM/EDX methods. We have obtained average geometric particle diameter measured by optical diameter which were resulted from SEM/EDX image scan, representative physical diameter of individual particle was $3.38\;{\mu}m\;in\;A,\;3.67\;{\mu}m\;in\;B$. In the result of image analysis at each spots particles, both samples non-sphere shapes, C-rich particles. In consequence of chemical analysis of individual particle, each sampling sites some elements.

• 한국가스학회지
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• 제1권1호
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• pp.81-86
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• 1997

본 연구에서는 다양한 위험성 평가 방법중에서 사고의 발생 경위를 연역적으로 추론해 나가는 이상 트리 분석 방법을 이용하여 정상사상을 일으킬 수 있는 시스템 요소들의 파악으로부터 화학공장의 사고 발생 가능성을 산정하였다. Gate-by-gate 방법과 최소 컷 ? 방법을 이용하여 공장내 존재하는 잠재위험에 대하여 정성적 및 정량적 위험성 평가를 수행하였다. 정량적인 위험성 평가 단계에서는 시스템 요소의 고장률 또는 신뢰율 자료로부터 정상사상의 사고 발생 확률 및 빈도를 계산하였다 결론적으로 이상 트리 분석방법을 이용하여 시스템/공정의 사고 발생확률을 논리 방식으로 계산할 수 있었으며, 중요도 분석을 이용하여 정상 사상이 발생하는데 가장 큰 영향을 미치는 손실 경로를 확인하여 보았다.

• Bulletin of the Korean Chemical Society
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• 제14권3호
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• pp.367-370
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• 1993

• 한국환경농학회지
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• 제34권4호
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• pp.294-302
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• 2015

BACKGROUND: Chemical accidents have increased owing to chemical usage, human error and technical failures during the last decades. Many countries have organized supervisory authorities in charge of enforcing related rules and regulations to prevent chemical accidents. A very important part in chemical accidents has been coping with comprehensive first aid tool. Therefore, the present research has provided information with the initial applications concern to the rapid analysis of hazardous material using instruments in vehicle of field mode after chemical accidents. METHODS AND RESULTS: Mobile measurement vehicle was manufactured to obtain information regarding field assessments of chemical accidents. This vehicle was equipped with four instruments including gas chromatography with mass spectrometry (GC/MS), Fourier Transform Infrared Spectroscopy (FT-IR), Ion Chromatography (IC), and UV/Vis spectrometer (UV) to analyses of accident preparedness substances, volatile compounds, and organic gases. Moreover, this work was the first examined the evaluation of applicability for analysis instruments using 20 chemicals in various accident preparedness substances (GC/MS; 6 chemicals, FT-IR; 2 chemicals, IC; 11 chemicals, and UV; 1 chemical) and their calibration curves were obtained with high linearity ( r ² > 0.991). Our results were observed the advantage of the high chromatographic peak capacity, fast analysis, and good sensitivity as well as resolution. CONCLUSION: When chemical accidents are occurred, the posted measurement vehicle may be utilized as tool an effective for qualitative and quantitative information in the scene of an accident owing to the rapid analysis of hazardous material.

• 한국가스학회지
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• 제16권6호
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• pp.41-47
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• 2012

화학공정을 효율적으로 설계 및 관리하기 위한 도면으로 공정흐름도와 공정배관 계장도가 있다. 본 도면들은 공정의 운전조건 및 설비에 대한 정보를 제공하지만 공정이 정상적으로 운전할 신뢰도는 제공하지 못한다. 따라서 본 연구에서는 유향그래프 분석기법을 이용하여 화학공정의 예방점검 정비주기 및 시점을 결정하기 위한 정보를 제공할 수 있는 신뢰도흐름도를 개발하였다. 유향그래프 분석기법은 화학공정이 정상적으로 작동할 가능성을 평가할 수 있는 기법으로써 노드와 아크를 사용하여 화학공정을 유향그래프로 모델화하고, 이 유향그래프를 순차적으로 해석하여 화학공정의 신뢰도를 평가하는 기법이다. 본 연구에서는 운전시간에 따른 화학공정의 신뢰도를 분석하고, 그 결과를 공정배관 계장도에 삽입하여 신뢰도흐름도를 개발하였다. 본 신뢰도흐름도는 화학공정의 기본 도면인 공정흐름도, 공정배관 계장도와 마찬가지로 화학공정의 설계, 예방점검 등 설비관리에 효율적으로 이용될 수 있을 것이다.

• Bulletin of the Korean Chemical Society
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• 제26권3호
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• pp.440-446
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• 2005

A method is described for the determination of dibutyltin (DBT) in sediment by isotope dilution using liquid chromatography inductively-coupled plasma/mass spectrometry (LC-ICP/MS). To achieve the highest accuracy and precision, special attentions are paid in optimization and evaluation of overall processes of the analysis including extraction of analytes, characterization of the standards used for calibration and LC-ICP/MS conditions. An approach for characterization of natural abundance DBT standard has been developed by combining inductively-coupled plasma/optical emission spectrometry (ICP/OES) and LC-ICP/MS for the total Sn assay and the analysis of Sn species present as impurities, respectively. An excellent LC condition for separation of organotin species was found, which is suitable for simultaneous DBT and tributyltin (TBT) analysis as well as impurity analysis of DBT standards. Microwave extraction condition was also optimized for high efficiency while preventing species transformation. The present method determines the amount contents of DBT in sediments with expanded uncertainty of less than 5% and its result shows high degree of equivalence with reference values of an international inter-comparison and a certified reference material (CRM) within stated uncertainties.

• Bulletin of the Korean Chemical Society
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• 제35권1호
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• pp.182-188
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• 2014

Three new transition metal complexes based on Ozagrel $[Cu(Ozagrel)]_n$ (1), $[Zn(Ozagrel)(Cl)]_n$ (2), ${[Mn_2-(Ozagrel)(1,4-ndc)_2]{\cdot}(H_2O)}_n$ (3), (Ozagrel = 3-(4-((1H-imidazol-1-yl)methyl)phenyl)acrylic acid; 1,4-ndc = 1,4-Naphthalenedicarboxylic acid) have been hydrothermally synthesized and characterized by elemental analyse, IR, TG, PXRD, electrochemical analysis and single crystal X-ray diffraction. X-ray structure analysis reveals that 1 and 3 are 3D coordination polymers, while complex 2 is a two-dimensional network polymer, the 2D layers are further packed into 3D supramolecular architectures that are connected through hydrogen bonds. The electrochemistry of 1-3 was studied by cyclic voltammetry in methanol and water using a glassy carbon working electrode. Also, thermal decomposition process and powder X-ray diffraction of complexes were investigated.

• Bulletin of the Korean Chemical Society
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• 제34권8호
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• pp.2375-2380
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• 2013

Two metal-organic frameworks based on the connectivity co-effect between rigid benzenedicarboxylic acid and bridging ligand have been synthesized $[Zn_2(3-NO_2-bdc)_2(4,4'-bpy)_2H_2O]_n$ (1), $[Co(3-NO_2-bdc)(4,4'-bpy)H_2O]_n$ (2) (where $3-NO_2-bdcH_2$ = 3-nitro-1,2-benzenedicarboxylic acid, 4,4'-bpy = 4,4'-bipyridine). The two novel complexes were characterized by IR spectrum, elemental analysis, fluorescent properties, thermogravimetric analysis, single-crystal X-ray diffraction and powder X-ray diffraction (PXRD). X-ray structure analysis reveals that 1 and 2 are two-dimensional (2D) network structures. Complex 1 and complex 2 belong to triclinic crystal with P-1 space group. The luminescence measurements reveal that two complexes exhibit good fluorescent emissions in the solid state at room temperature. Also, thermal decomposition process and powder X-ray diffraction of complexes were investigated.

• 분석과학
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• 제20권5호
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• pp.400-405
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• 2007

액체크로마토그래피/질량분석법(LC/MS) 및 핵자기공명분광분석법 $^1H(NMR)$을 이용하여 화장품에 들어있는 글리세린을 동시 비교분석하였다. 화장품 시료를 물에 용해시키고 수산화나트륨을 첨가하여 시료용액을 강알칼리 상태로 유지시킨 후, 시료용액 중의 글리세린을 benzoyl chloride로 유도체화 반응 시키고 유도체화된 글리세린을 pentane으로 추출하여 LC/MS로 정량분석 하였다. $^1H$ NMR 분석은 시료를 전처리 없이 $D_2O$ 용매에 직접 용해시키고, 글리세린을 ERETIC(Electronic REference To access In vivo Concentrations) 방법을 이용하여 $^1H$ NMR로 직접 정량분석 하였다. LC/MS 및 NMR 분석결과 LC/MS의 검량선은 $0.1-10{\mu}g/mL$ 농도범위에서 $r^2=0.9991$ 이었고 $^1H$ NMR의 검량선은 $25-500{\mu}g/mL$ 농도범위에서 $r^2=1$의 상관계수를 갖는 좋은 직선성을 얻었다.

• 폴리머
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• 제39권3호
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• pp.359-364
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• 2015

A self-oscillating interpenetrating polymer network (IPN) poly(acrylic acid)/poly(ethylene glycol) (PAA/PEG) hydrogel was prepared by using radical polymerization with a two-step method. The IPN hydrogel was characterized by FTIR spectroscopy and morphological analysis. The results indicated that the chains of PEG and PAA twined to form porous structure which is beneficial to water molecules entering inside of the hydrogel. In addition, the pH-responsive behavior, salt sensitivity, swelling/de-swelling oscillatory behaviors and self-oscillation in a closed pH oscillator were also studied. The results showed that the prepared hydrogel exhibited pH-sensitivity, good swelling/de-swelling reversibility and excellent salt sensitivity. The self-oscillating behavior of swelling/de-swelling for the prepared hydrogel was caused by pH alteration coupled with the external media. This study may create a new possibility as biomaterial including new self-walking actuators and other related devices.